Benthic Foraminifera As Tools Of Paleoceanography: Three Case Studies From The Late Cretaceous Of The North Pacific Ocean And Western Interior Seaway, And The Miocene-Pleistocene Of The Ross Sea, Antarctica, Serena N. Dameron

Doctoral Dissertations

This dissertation is a widespread compilation of research covering vastly different times and locations. Despite these differences, the use of foraminifera helps to unravel their geologic history, revealing the paleoenvironmental, paleoclimatic, and paleoceanographic conditions of each location. What unites each study is how water mass, food supply and oxygen concentration play a critical role on the microfossil assemblage. This dissertation is broken up into three unique chapters. Chapter 1 reexamines some old ideas of how benthic foraminifera can be used as water mass indicators. A 13-myr record from Shatsky Rise in the paleo-central Pacific Ocean contains several instances water mass …

Improving The Hydrological Analysis Of Groundwater Flow Paths By Integrating Geochemical And Physical Characteristics Of A Highly Fractured Aquifer System To Create Sustainable Use Of Groundwater In A Climate With Projected Drying Trends., Marsha K. Allen

Doctoral Dissertations

Improving the hydrological analysis of groundwater flow paths by integrating geochemical and physical characteristics of a highly fractured aquifer system to create sustainable use of groundwater in a climate with projected drying trends. Precipitation over Caribbean islands has decreased steadily since the 1950's, which has led to severe drought conditions. The most recent Pan-Caribbean Drought occurred from 2013 to 2016. Climate models predict that drying trends are expected to continue and become more severe over time as precipitation decreases and temperatures rise. In addition, evaporation rates on these islands are expected to increase by ~15-17%, contributing to the drought. Though …

Fundamental Controls On The Water Cycle In Arid Environments: A Mechanistic Framework For Spatiotemporal Connectivity Between Hydroclimate And Groundwaters In The Dry Andes, Brendan J. Moran

Doctoral Dissertations

There remain many persistent uncertainties regarding fundamental aspects of natural water cycles in arid mountainous regions, the Dry Andes of South America represents one of the most extreme examples of these environments on the Planet. Deep water tables (>100 meters), long groundwater transit times and distances (>100 years, 10-100 kilometers), limited and infrequent rainfall, remote and difficult to access terrain, and complex salar/evaporite hydrogeology common in these environments make reliable monitoring of these hydrological systems particularly difficult. As a result, major gaps remain in our understanding of critical aspects of the water cycle such as recharge and evaporation …

Algorithm Performance On The Estimation Of Cdom And Doc In The North Slopes Of Alaska, Monica Weisenbach

Masters Theses

Use of satellite imagery makes environmental monitoring easy and convenient with little of the logistics involved in planning sampling campaigns. Colored dissolved organic matter (CDOM) is an important component to track as a proxy for the large pool of dissolved organic carbon (DOC). In a world contending with the looming issue of global climate change, the ability to investigate the carbon cycle of inland to coastal environments allows for examination of the magnitude of carbon flowing through the system and potential changes over years. The Arctic region is a critical area for climate change impacts but is a difficult landscape …

Investigating Gallium Inclusion In Aluminum And Iron Oxyhydroxides, Corey A. Palmer

Masters Theses

Because Ga shares many physicochemical properties with Al and Fe, Ga may be able to incorporate into Al and Fe oxy-hydroxides. Understanding how Ga incorporates into these oxy-hydroxides may be crucial for finding Ga-rich bauxite deposits. In order to find the difference in Ga inclusion rates into oxy-hydroxides, as well as understand the mechanisms for this Ga inclusion, Al and Fe oxy-hydroxides were synthesized in the lab with Ga additions of 2 mol % Ga and 20 mol % Ga for a low-Ga and high-Ga treatment, respectively, along with a no added Ga control. X-Ray diffraction analyses confirmed the formation …

Crustal Evolution Of The New England Appalachians: The Rise And Fall Of A Long-Lived Orogenic Plateau, Ian Hillenbrand

Masters Theses

The rise and demise of mountain belts, caused by growth, modification, or removal of the continental lithosphere are fundamental processes that influence almost all Earth systems. Understanding the nature, timing, and significance of active processes in the creation and evolution of modern mountain belts is challenged by a lack of middle crustal and lower crustal exposures. Analogues can be found in ancient orogens, whose deeply eroded roots offer a window into deeper processes, yet this record is complicated by overprinting events and complex deformational histories. Research presented herein constrains the tectonic history of multistage Appalachian Orogen, type locality of the …

Magnetite Mineralization Of The Hammondville Pluton: Poly-Phase Kiruna Type Iocg Magnetite-Apatite Deposits In The Lyon Mountain Granite, Phillip Geer

Masters Theses

Recent mapping of the Eagle Lake Quadrangle, NY, coupled with whole-rock geochemistry and microscopy has offered insight into the petrogenesis of the magnetite-apatite deposits of the Hammondville mining district in the eastern Adirondack Mountains. This study provides insight into the magmatic history of the ca. 1060-1050 Ma Lyon Mountain Granite (Hammondville Pluton) which is intimately related to, and hosts the deposits in this area. Magnetite seams are commonly surrounded by well layered magnetite gneiss, which typically parallel the seams, although in some outcrops appear to be slightly truncated by them. Mineralization is generally concordant with the weak layering found throughout …

Seeing Through The Ottawan Overprint, Adirondack Mtns., Ny: Integrating Microstructural Analysis, Geothermobarometry, And In-Situ Monazite Petrochronology, Justin Mistikawy

Masters Theses

Integrating field observation with petrochronology is critical for understanding the tectonometamorphic evolution of the North American Grenville Province. Despite methodological advances in geothermobarometry and geochronology, incorporating these data into larger models of the Adirondack Mountains remains particularly challenging due to the presence of multiple generations of deformation, primarily related to the ca. 1190 – 1140 Ma Shawinigan and ca. 1090 – 1020 Ma Ottawan Orogenies (McLelland et al.,2013). The Rock and Bear Ponds area is a dome of tight-to-isoclinally folded metapelites in structural contact with orthogneiss. Fold generations are orthogonal and partitioned such that the northern area is dominated by …

Petrogenesis Of Basaltic Lavas In Iceland And The Springerville Volcanic Field, U.S.A.: The Influence Of Tectonic Setting, Depth Of Melting And Volatiles, Marissa Mnich

Doctoral Dissertations

Icelandic basalts were long thought to be low in water (e.g. Gunnarsson et al., 1998), but more recent studies suggest that hotspots, like the Iceland mantle plume, may be a source of hydrous basaltic melts (Nichols et al., 2002). To explore a possible link between location, volatile concentration and resulting petrogenetic implications, samples were collected from eleven volcanic centers throughout Iceland. Water concentrations were measured in melt inclusions and phenocrysts using Fourier transform infrared (FTIR) spectroscopy. Results for a subset of samples indicate variable water in melt inclusions ranging from approximately 50 ppm to over 3000 ppm. Samples from southwestern …

Middle To Late Pleistocene Paleoenvironmental Reconstructions From Lake El'gygytgyn, Arctic Russia, Mary Helen Habicht

Doctoral Dissertations

Climate change is a major issue challenging the world today. Our global society faces rising temperatures, variable weather patterns, and rising sea level among other associated issues. Our action (or inaction) to address current changes will have serious ramifications for life on our planet in the coming centuries and millennia. In order to provide context for these present and future changes, we can utilize the paleo record to understand the natural variability of Earth’s climate system. One region of the world is changing more rapidly than the global average. Over recent decades, the Arctic has experienced warmer temperatures, reduced sea …

Spatial And Temporal Mapping Of Distributed Precipitation, Surface And Groundwater Stable Isotopes Enables Insights Into Hydrologic Processes Operating At A Catchment Scale, Alison Cole

Masters Theses

Isotopic analyses of d¹⁸O and d²H of water through the hydrologic cycle have allowed hydrologists to make better interpretations related to climate and relationships between precipitation, surface water, and groundwater. In this study 394 precipitation samples 1917 surface water samples and 1405 groundwater samples across Massachusetts was used to create an isoscape for each respective water. All samples have been collected by volunteers throughout Massachusetts. A state meteoric water line: d²H = 7.7*d¹⁸O + 9.8, surface water line: d²H = 5.7*d¹⁸O – 4.2, and groundwater line: d^{2 …}

Sorption Temperature And And The Stability Of Iron-Bound Soil Organic Matter, Michael L. Nguyen

Doctoral Dissertations

The preservation of soil organic matter (SOM) is an important control on the global cycling of carbon. Long-term preservation of SOM has important implications on soil fertility and climate regulation. Minerals, such as iron oxides, can react with SOM and serve as a preservation mechanism for SOM. Globally, iron oxide-SOM interactions form a “rusty carbon sink” which protects up to 22% of organic carbon in marine sediments. Climate changes, such as warming, may alter the size or efficacy of the “rusty carbon sink.” The effects of temperature, SOM composition, and mineral particle size on the formation and stability of iron …

Root-Driven Weathering Impacts On Mineral-Organic Associations Over Pedogenic Time Scales, Mariela Garcia Arredondo

Masters Theses

Plant roots are critical weathering agents in deep soils, yet the impact of resulting mineral transformations on the vast deep soil carbon (C) reservoir are largely unknown. Root-driven weathering of primary minerals may cause the formation of reactive secondary minerals, which protect mineral-organic associations (MOAs) for centuries or millennia. Conversely, root-driven weathering may also transform secondary minerals, potentially enhancing the bioavailability of C previously protected in MOAs. Here we examined the impact of root-driven weathering on MOAs and their capacity to store C over pedogenic time scales. I compared soil that experienced root-driven weathering, resulting in the formation of discrete …

Mid-Pliocene To Early Pleistocene Sea Surface And Land Temperature History Of Nw Australia Based On Organic Geochemical Proxies From Site U1463, Rebecca Smith

Masters Theses

Ocean gateways facilitate water circulation between ocean basins, and therefore directly impact thermohaline circulation and global climate. In order to better predict the effects of future climate change, it is critical to constrain past changes in ocean gateway behavior, and corresponding changes in thermohaline circulation, particularly during analogue periods for modern climate change. The Indonesian Throughflow (ITF) is a primary ocean gateway and vital component of the global conveyor that transports water from the Pacific Ocean into the Indian Ocean, however due to a lack of long and continuous sedimentary records from locations under its influence, changes in ITF behavior …

Estimation Of Cdom In Inland Waters Via Water Bio-Optical Properties Using A Remote Sensing Approach, Jiwei Li

Doctoral Dissertations

Monitoring of Colored dissolved organic matter (CDOM) in inland waters provides important information for tracing carbon cycle at the land-water interface and studying aquatic ecosystem. Remote sensing estimation of CDOM in the inland waters offers an alternative approach to field samplings in examining CDOM spatial-temporal dynamics. However, CDOM retrieval is a challenge due to the lack of algorithm for resolving bottom effect in shallow inland waters. Moreover, an effective approach based on multi-spectral, high spatial resolution and global coverage satellite images is in urgent need. To resolve these challenges, shallow water bio-optical properties (SBOP) algorithm was developed to overcome bottom …

Arctic And North Atlantic Paleo-Environmental Reconstructions From Lake Sediments, Gregory A. De Wet

Doctoral Dissertations

ABSTRACT

Petrogenesis And Concentric Zonation Of The Belchertown Intrusive Complex, West-Central Massachusetts, Karen June Van Wagner

Masters Theses

The Belchertown Intrusive Complex is a ~164 km2 Devonian pluton that intruded Paleozoic metasedimentary and metavolcanic rocks in west-central Massachusetts. Intrusion of the pluton was synchronous with Acadian deformation (Ashwal, 1974). The complex is concentrically zoned, with a core of orthopyroxene-biotite monzodiorite, a middle zone of clinopyroxene-hornblende-biotite granodiorite, and an outermost zone of hornblende-biotite granodiorite. Zoning from a more to less hydrous mineral suite from the outside to the inside of the pluton led Ashwal (1974) to suggest that metamorphic hydration most strongly affected the outermost zones of the complex. Basaltic inclusions occur most commonly near the edges of …

Metamorphic And Structural Control Of Magnetism Within The Lower Continental Crust, Northern Saskatchewan, Canada, Jeffrey R. Webber

Doctoral Dissertations

The linking of geophysical information to tectonometamorphic processes holds great potential for the surveying of vast remote areas of the planet and may allow for the transcendence of observational scales. Investigations concerning magnetic properties of the lower continental crust can reveal an incredible wealth of information concerning the conditions of metamorphism, regional extent of deformation, and controls on the magnetic architecture of the lithosphere. This dissertation presents three contributions aimed at the integration of petrology, structural geology, and rock magnetism in order to investigate the magnetic nature of the lower continental crust, constrain tectonometamorphic processes at the regional scale in …

Geochemical Attributes Of Hydraulically Active Fractures And Their Influence On Groundwater Quality, Amy L. Hudson

Doctoral Dissertations

This study utilized discrete interval diffusion sampling of a fractured bedrock well completed in schist to investigate if a natural weathering signal can be used to identify hydraulically active fractures. The open borehole well MFS-1, is the focus of the study, which is in close proximity to the recharge zone making it ideal for testing the hypotheses of this study. The hydraulically active fractures of Well MFS-1 were identified, and the dominant mixing force of the water column of the well was determined to be thermal convection in the upper portion of the well and upward gradients. The isotopic data …

Micropaleontology And Isotope Stratigraphy Of The Upper Aptian To Lower Cenomanian (~114-98 Ma) In Odp Site 763, Exmouth Plateau, Nw Australia, Ali Alibrahim

Masters Theses

The biostratigraphy and isotope stratigraphy of the upper Aptian to lower Cenomanian interval including oceanic anoxic events OAE1b, 1c and 1d are investigated in ODP Site 763, drilled on the Exmouth Plateau offshore northwest Australia. Benthic foraminifera suggest that Site 763 was situated in outer neritic to upper bathyal water depths (~150-600 m). OAEs of the Atlantic basin and Tethys are typically associated with organic carbon-rich black shales and δ¹³C excursions. However, OAEs at this high latitude site correlate with ocean acidification and/or pyrite formation under anoxic conditions rather than black shales. Ocean acidification maybe responsible for sporadic …

Sources Of Water And Solutes To The Salar De Atacama, Chile: A Coupled Hydrologic, Geochemical, And Groundwater Modeling Study, Lilly G. Corenthal

Masters Theses

Focused groundwater discharge in endorheic basins provides opportunities to investigate mechanisms for closing hydrologic budgets in arid regions. The Salar de Atacama (SdA), a closed basin in northern Chile, has accumulated over 1800 km³ of halite and a lithium-rich brine since the late Miocene primarily through evapotranspiration of groundwater. The hydrologic balance of SdA and sources of water and solutes required to explain this deposit are not well constrained. An adapted chloride mass balance method drawing on a database of over 200 water sample sites is applied to a remotely-sensed precipitation dataset to estimate spatially-distributed modern groundwater recharge. Comparing …

A High-Resolution Paleoenvironmental And Paleoclimatic History Of Extreme Events On The Laminated Sediment Record From Basin Pond, Fayette, Maine, U.S.A., Daniel R. Miller

Masters Theses

Future impacts from climate change can be better understood by placing modern climate trends into perspective through extension of the short instrumental records of climate variability. This is especially true for extreme climatic events, such as extreme precipitation and wildfires, as the period of instrumental records provides only a few examples and these have likely have been influenced by anthropogenic warming. Multi-parameter records showing the past range of climate variability can be obtained from lakes. Lakes are particularly good recorders of climate variability because sediment from the surrounding environment accumulates in lakes, making them sensitive recorders of climate variability and …

Oceanographic Controls On The Expression Of Cretaceous Oceanic Anoxic Events In The Western Interior Sea, Christopher M. Lowery

Doctoral Dissertations

The Cretaceous Period (145-66 Ma) was a time of elevated global temperatures superimposed on fluctuating climate regimes and repeated biotic turnover. It recorded several major perturbations of the carbon cycle, characterized by widespread deposition of organic-rich black shale and benthic and photic zone dysoxia to euxinia, termed oceanic anoxic events (OAEs). The Cenomanian-Turonian OAE2 and the enigmatic Coniacian-Santonian OAE3 are well-preserved in the Western Interior Sea (WIS) of North America. The expression of these OAEs in the WIS differs both from each other and from contemporaneous open-ocean sections. Despite decades of research, questions remain about the role of oceanographic parameters …

Dissolution, Ocean Acidification And Biotic Extinctions Prior To The Cretaceous/Paleogene (K/Pg) Boundary In The Tropical Pacific, Serena Dameron

Masters Theses

The several million years preceding the Cretaceous/Paleogene (K/Pg) boundary has been the focus of many studies. Changes in ocean circulation and sea level, extinctions, and major volcanic events have all been documented for this interval. Important research questions these changes raise include the climate dynamics during the warm, but not hot, time after the decay of the Late Cretaceous greenhouse interval and the stability of ecosystems prior to the mass extinctions at the end-Cretaceous.

I document several biotic perturbations as well as changes in ocean circulation during the Maastrichtian stage of the latest Cretaceous that question whether the biosphere was …

Sedimentological, Geochemical And Isotopic Evidence For The Establishment Of Modern Circulation Through The Bering Strait And Depositional Environment History Of The Bering And Chukchi Seas During The Last Deglaciation, Ben M. Pelto

Masters Theses

Sea level regression during the Last Glacial Maximum exposed the Bering Land Bridge, and cut off the connection between the North Pacific and Arctic Ocean, ending the exchange of North Pacific Water through the Bering Strait. Exchange of North Pacific Water comprises a major portion of fresh water input to the Arctic Ocean, and is of vital importance to North Atlantic Deep Water formation, a vital component of Atlantic Meridional Overturning Circulation. Bering Strait throughflow thus plays an integral role in global climate stability. A suite of four cores was selected, three in the Bering Sea and one in the …

Locating Cryptotephra In Sediments Using Fluid Imaging Technology, Robert D'Anjou, Nicholas L. Balascio, Raymond S. Bradley

Raymond S Bradley

We report a new approach to locate and quantify cryptotephra in sedimentary archives using a continuously-imaging Flow Cytometer and Microscope (FlowCAM_). The FlowCAM rapidly photographs particles flowing in suspension past a microscope lens and performs semi-automated analysis of particle images. It has had primarily biological applications, although the potential sedimentological applications are numerous. Here we test the ability of this instrument to image irregularly shaped, vesicular glass shards and to screen sediment samples for the presence of cryptotephra. First, reference samples of basalt and rhyolite tephra (sieved <63>microns) were analyzed with the FlowCAM, demonstrating the ability of the instrument to …

Geochemistry And Inorganic Carbon Transport Of A Glacial Till Drumlin At A Road Salt Facility, Houbao Li

Open Access Dissertations

Investigations were conducted at a salt/premix storage facility lying on top of a glacial drumlin near the coastline in eastern Massachusetts, to characterize salt contaminated groundwater. Groundwater hydrogeochemical variations at different depths were determined based on ten years of monthly or quarterly water quality data from 54 monitoring wells. Groundwater was grouped in three water categories – shallow, middle and deep. Hydrogeochemical characterization indicates that the dominant water types are Na-Cl, Na-Ca-Cl and Ca-HCO3 from the shallow to deep water group. Rock weathering is the dominant hydrogeochemical process for deep water group, whereas salt water percolation and cation exchange control …

Holocene Paleo-Environmental Variability Reconstructed From A Lake Sediment Record From Southeast Greenland, Gregory A. De Wet

Masters Theses 1911 - February 2014

Arctic climate variability over the Holocene has been both extensive and, at times, abrupt. Current understanding of these changes is still quite limited with few high-resolution paleoclimate records available for this period. In order to place observed and predicted 21^st century climate change in perspective, reliable and highly resolved paleo-reconstructions of Arctic climate are essential. Using an 8.5 m sediment core from Nanerersarpik Lake, this project will characterize climate changes during the Holocene, including the deglacial transition, the rapid changes that are known to have occurred around 8,200 years ago, the transition from Holocene thermal maximum (HTM) to the …

7700 Years Of Holocene Climatic Variability In Sermilik Valley, Southeast Greenland Inferred From Lake Sediments, Samuel H. Davin

Masters Theses 1911 - February 2014

During the latter half of the 20^th century until present day there has been an unprecedented rise in global annual mean temperatures accompanied by rising sea levels and a decrease in Northern Hemisphere snow cover, which if it continues will lead to widespread disruption of climate patterns, ecosystems, and present-day landscapes. It is therefore of critical importance to establish an expanded network of paleoclimate records across the globe in order to better assesses how the global climate system has changed in the past, that we may create a metric by which to address modern change. Herein is presented a7,700 …

Reading Landscape: Mid-Century Modernism And The Landscape Idea, Jeffrey David Blankenship

Open Access Dissertations

This dissertation traces the recovery of the landscape idea during the middle decades of the 20th century by a group of public intellectuals, scholars and designers responding to the everyday realities of the modern American built environment. That recovery served as a corrective to modernism's construction of landscape as either abstract utopian space or retrogressive historical tableau. The primary catalyst for this renewed interest in landscape as a representation of human cultures and their complex relationship with the natural world was the essayist and critic John Brinckerhoff Jackson (1909-1996) and his magazine Landscape. During the years of Jackson's editorship (1951-1968), …