Physical Sciences and Mathematics Commons^™

Struktura Emisji Związków Fluoru Z Hutnictwa Żelaza Na Przykładzie Huty Katowice, Marian Mazur, Robert Oleniacz, Marek Bogacki

Robert Oleniacz

As recently as a dozen or so years ago ferrous metallurgy was known as one of the biggest source of fluorine compound emissions to the atmosphere. Nevertheless production technology and raw material changes occurring in this industry cause continuous decreasing of their participation in the total fluorine emission. On the ground of investigations that have been carried out in the Katowice Steelworks (Poland) in the last few years, participation of particular technological processing in the water-soluble fluorine compound emissions (which are regarded as toxic) were presented in the paper, as well as a position of fuel combustion process (that take …

Emisja Związków Fluoru Z Hutnictwa Żelaza, Marian Mazur, Marek Bogacki, Robert Oleniacz

Robert Oleniacz

The article presents the results of the last few years of comprehensive researches related to the emission of fluorine compounds from iron metallurgy in Poland. Determined of the levels of flue-gas concentrations and air emissions for fluorine in the form of gaseous and solid compounds, including water-soluble compounds (considered to be toxic). The study also made it possible to analyze of raw materials used in these processes taking into account fluorine content and its impact on the amount of fluorine compounds emitted to the air.

English title: Emissions of fluorine compounds with iron metallurgy.

Analiza Źródeł Emisji Związków Fluoru Z Procesów Hutnictwa Żelaza, Marian Mazur, Robert Oleniacz, Marek Bogacki

Robert Oleniacz

The paper presents the results of many years of complex research issues related to the emission of fluorine compounds of iron and steel processes. They allowed to examine these processes used in raw materials in terms of the fluorine content and their impact on the amount of emissions of fluorine compounds to the air. Were determined by measuring the levels of concentration in flue gases and stack emissions of fluorine in the form of gaseous and solid compounds, including water-soluble components (considered to be toxic).

English title: Analysis of emission sources of fluorine compounds from the processes of ferrous metallurgy.

Emisja Związków Fluoru Z Procesów Hutnictwa Żelaza, Marian Mazur, Marek Bogacki, Robert Oleniacz

Robert Oleniacz

The paper presents the results of a comprehensive study of issues related to emissions of fluorine compounds from ferrous metallurgy processes carried out over the last few years. As part of this study raw materials used in these processes were analyzed in terms of fluorine content and its impact on the amount of air emissions of fluorine compounds. Also determined by measuring the concentration levels and emissions of fluorine in the gaseous and solid phase, including water-soluble compounds (considered to be toxic).

English title: Emissions of fluorine compounds from the processes of ferrous metallurgy.

Chemistry Of Pentafluorothio (Sf5) Alkyl Derivatives, Rolf Walter Winter

Dissertations and Theses

Part I describes the preparation of a number of useful intermediates from the sultone F₅SCHCF₂OSO₂ (1). These intermediates include the following: the ketene F₅SC(SO₂)=C=O (21), the unique sultone F₄S=CCF₂OSO₂ (23), and various ionic intermediates of the form Y⁺ [F₅SC(SO₂F) COX]^-. These intermediates play an important role in providing new pathways for preparing fluorosulfonic acid precursors. Fluorosulfonic acids are excellent candidates to improve the efficiency of environmentally safe fuel cells. It was possible to obtain new derivatives of 1 by …

Fluorinated [Beta]-Sultones As Precursors To Fluorinated Sulfonic Acids, And New Fluorosulfonyl Containing Monomers/Polymers, Javid Mohtasham

Dissertations and Theses

Sulfur trioxide (SO₃) adds to fluoroolefins of the form RCF=CF₂, (where R = F, SF₅, CF₃, CF₃OCF₂, CF₂=CF(CF₂)₂, CF₃(CF₂)₃O, CF₃O(CF₂)₂OCF₂, or CH₂ClCHClCH₂), yielding the fluorinated [beta]-sultones, RCFCF₂OSO₂. In the case of CF₃(CF₂)₃OCF=CF₂, a reverse addition occurs, giving the sultone, CF₃(CF₂)₃CF₂2OCFCF₂SO₂O. The fluoro [beta]-sultones are capable of undergoing different reactions, such as rearrangement, hydrolysis, esterification, and polymerization. These reactions, will result in the formation of compounds containing the fluorosulfonyl grouping (SO₂F); it is this group that yields the corresponding sulfonic acid upon base/acid treatment.

The addition of sodium bisulfite to CF₃CF= CF₂ and CF₃(CF₂)₄CF=CF₂ in the presence of (C₆H₅CO)₂O₂ and Na₂B₄O₇·10H₂O …