Physical Sciences and Mathematics Commons^™

Reductive Dehalogenation Of Chlorinated Aromatic And Aliphatic Hydrocarbons Under Anaerobic Conditions, Monica Turner Togna

Dissertations

The process of reductive dehalogenation involves the removal of a halogen substituent from a molecule with the concurrent addition of electrons to the molecule, resulting in a more reduced and often less toxic product. Anaerobic bacteria have the potential to utilize hazardous chlorinated aromatic and aliphatic hydrocarbons as electron acceptors in metabolic reductive dehalogenation processes.

In experiments performed with chlorinated aromatic compounds a highly enriched anaerobic culture stoichiometrically converted 2,4,6-trichlorophenol (2,4,6-TCP) to 4-monochlorophenol. Dehalogenation occurred only in alkaline media (pH 8-9) at concentrations of 2,4,6-TCP up to 1 mM. Data indicated that the dehalogenating organism did not fit into any …

Scaling Up Of Water-Based Organic Reactions, Chen Gu

Dissertations

Three water-based organic reactions, Diels-Alder, epoxidation of olefins, and free-radical bromination have been investigated as an approach to pollution prevention. The first two systems were scaled-up by at least a factor of 20. These reactions are of special interest to the pharmaceutical and speciality chemical industries. The photo-induced free-radical bromination of alkanes with bromine in water was studied in a two-phase system. Experimental results show that all reactions have advantages resulting from being conducted in water, such as reaction rate acceleration, reaction selectivity increase, and the absorption of water-soluble gas byproduct by solvent water.

The effects of stirring rates, temperature, …

Effect Of Vitamin Supplementation On Biodegradation Of Aliphatic Hydrocarbons And Diesel Fuel, Susmita Guptapal

Dissertations

Bioremediation of hazardous wastes is proven to be environmentally benign and most cost effective technology when proper conditions are provided. However, commercialization of this method still requires comprehensive research to enhance the degradation rate to make the technology more acceptable for implementation. In this research a unique approach to increase the rate of biodegradation by vitamins supplementation was studied.

Five vitamins, niacin, biotin, folic acid, thiamin and pantothenic acid were selected for the present study. Different short chain (C₈ and C₉), and long chain (C₁₆ and C₁₇) aliphatic hydrocarbons and diesel fuel (a mixture …

Factors That Influence Changes In Temporal And Spatial Accumulation Of Debris On An Estuarine Shoreline, Cliftwood Beach, New Jersey, Usa, Laura Pace

Theses

A field investigation was conducted on an estuarine shoreline in Raritan Bay, New Jersey to identify the temporal and spatial distribution changes in accumulation of marine debris, and the factors that influence these changes. Methodology consists of 12-monthly collections of debris and profile data, and collection of local climatological and tide data. Debris was classified by type, length, weight, fragmentation, and probable function and weathering noted for each collected item. Wind roses were constructed to determine dominant wind speed and direction and wind characteristics for time intervals between field sampling.

Plastics are the primary component of debris; glass and styrofoam …

Continuous Monitoring Of Volatile Organic Compounds Using Microtrap Based Gas Chromatographic Systems, Yonghua Xu

Dissertations

Continuous analysis allows a representative portion of a sample to flow continuously through an analytical instrument, which gives analytical information with little or no delay in time. A microtrap is a small diameter tube packed with adsorbents in series. When a gaseous sample containing volatile organic compounds (VOCs) flows through the microtrap, the VOCs can be trapped selectively by adsorbents. Then a pulse of electrical current is applied to the microtrap. This rapid heating results in a desorption that can act as a sharp injection for GC separation. Thus the microtrapped sample is the total amount of VOC present in …

Stratospheric Ozone Layer Depletion : A Computer Aided Case Study, James M. Lipuma

Theses

In industries today, there is a desire to stop pollution before it starts, through the process of pollution prevention. Unfortunately, many university level students are not exposed to the thinking process involved in environmental problem solving early enough in their academic career, if they are exposed to it at all. The goal of this thesis is to develop and to evaluate an interdisciplinary case-study about the depletion of the stratospheric ozone layer by chlorofluorocarbons (CFCs). This case-study will be used to teach first year chemistry students about environmental problem solving. The case study was assembled from existing literature according to …

Pollution Prevention In The New Jersey Chemical Industry : Motivations And Barriers To Commitment, Judith A. Thornton

Theses

This study of the New Jersey Chemical Industry identifies the primary elements that lead to or inhibit company commitments to pollution prevention. A direct measure of facility pollution prevention commitment is developed that takes into account: organizational support attributes, past reductions achievements, current methods implementation, process reduction goals, and special environmental initiatives. The "P2 Commitment Index" allows for categorization of facilities so that the needs and interests of varying groups may be differentiated.

Higher level commitments are associated with: establishment of company pollution prevention policy, setting of prioritized facility goals, and measurement and reporting on pollution prevention progress. Facilities at …

Oxidation Of Isobutane And Isobutene Reaction Pathways And Detailed Mechanism, Chiung-Ju Chen

Theses

A reaction mechanism consisting of 248 elementary reactions and 138 species has been developed to model experimental systems - decomposition of 2,2,3,3 tetramethylbutane in the presence of oxygen and oxidation of isobutene. This elementary reaction mechanism based on two important reaction systems: tert-butyl radical with O₂ and allylic isobutenyl radical with O₂, plus their subsystems, such as isobutene + HO₂, isobutene + OH and allylic isobuteny1hydroxy + O₂. Thermochernical kinetic parameters are developed for each elementary reaction and a chemical activation kinetic analysis using quantum RiceRamsperger-Kassel (QRRK) theory for k(E) and modified strong …

The Effects Of Chromated Copper-Arsenate (Cca) Pressure-Treated Wood On Local Sediments And Benthos In A Freshwater Lake, William A. Romeo

Theses

This study looked at the sediment and benthic organism effects of exposure to a Chromated Copper-Arsenate (CCA) treated wood bulkhead in a lake environment with respect to 1) the leaching and accumulation of chromium, copper and arsenic in the nearby sediments, 2) accumulation of these metals in local benthic organisms and 3) the effects of these metals on the local benthic community structure. Sediment samples, taken at regular distances away from a CCA bulkhead and three reference areas in a freshwater lake in Wayne, NJ, were sieved to remove the fine particle fraction (<70µm) which was then analyzed for the metals of concern. Benthic organisms were sampled at the same locations, enumerated, identified, dried and also analyzed for the metals in question. Analysis of sediment metal concentrations revealed high levels of copper at all sampling locations. This was attributed to the annual addition and accumulation Of CuS0₄ added to the lake. There …