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Articles 1 - 9 of 9

Full-Text Articles in Physical Sciences and Mathematics

Evaluating The Hazardous Materials (Hazmat) Pharmacy Among Air Force Majcoms Using Waste Reductions And Activity Indicators, W. Edward Iseman Jr. Dec 1996

Evaluating The Hazardous Materials (Hazmat) Pharmacy Among Air Force Majcoms Using Waste Reductions And Activity Indicators, W. Edward Iseman Jr.

Theses and Dissertations

The Hazardous Materials (HazMat) Pharmacy has been designed as an environmentally friendly vehicle to handle, store, dispense, track, recycle, and dispose of hazardous materials in the Air Force. This thesis effort proposed a method in which valuable feedback for the pharmacy can be obtained. Because it is still in the early stages of implementation, there has been little feedback on the pharmacy. An activity index that uses a variable most closely associated with the generation of hazardous waste in a MAJCOM is proposed. Using an aircraft maintenance related variable, like maximum take-off weight, the fluctuations in mission over time can …


Surfactant Enhanced Microbial Degradation Of Jp-8 Contaminated Soil, John D. Thomas Dec 1996

Surfactant Enhanced Microbial Degradation Of Jp-8 Contaminated Soil, John D. Thomas

Theses and Dissertations

This research effort used an automated respirometer to evaluate the enhancement of JP-8 fuel biodegradation, from surfactant addition. Two nonionic surfactants, Novell 1412-7 and Alfonic 810-4.5 were chosen for addition to contaminated JP-8, microcosms at three levels of treatment. The three levels of treatment included sub-CMC, CMC, and supra-CMC concentrations for each surfactant. The Novell II, nonionic surfactant, exhibited inhibitory characteristics, and was eliminated from the study. The focus of the study was to determine if JP-8 was actually degraded, and if enhancement of JP-8 biodegradation would be achieved from surfactant addition. The respirometer was found to be repeatable within …


Laser-Induced Breakdown Spectroscopy On Solution Samples Using Surface Excitation, Leonard M. Berman Dec 1996

Laser-Induced Breakdown Spectroscopy On Solution Samples Using Surface Excitation, Leonard M. Berman

Theses and Dissertations

Laser-induced breakdown spectroscopy (LIBS) is a spectroscopic technique where output from a pulsed laser is focused onto a target in order to create an intense plasma. The optical emission is characteristic of the elements in the focal volume and can be used for elemental analysis. Research on the detection of nickel in solution in addition to solvent detection of CCl4, CHCl3, C2Cl4, and C2HCl3 has been performed. Breakdown was formed at the sample surface via a Q-switched Nd:YAG laser. Initially, operation of the laser was at 1064 nm/repetition rate of 5 Hz. Experiments …


Local Effects Of Solid Rocket Motor Exhaust On Stratospheric Ozone Concentrations, Brian K. George Dec 1996

Local Effects Of Solid Rocket Motor Exhaust On Stratospheric Ozone Concentrations, Brian K. George

Theses and Dissertations

Solid Rocket Motors (SRMs) power the initial flight of the Space Shuttle and Titan IV rocket. During those first two minutes after liftoff, the exhaust plumes from these motors emit large quantities of chlorine compounds and alumina particles into the atmosphere. For years scientists have argued that such a large chlorine input, injected directly into the stratosphere, would photochemically react with the surrounding air to cause significant ozone depletion. To answer the question of whether SRM exhaust causes a significant ozone depletion, Version 7 data from the Total Ozone Mapping Spectrometer (TOMS) instrument was analyzed for the 30 days prior …


Mass Transport Of Volatile Organic Compounds Between The Saturated And Vadose Zones, Monte S. Harner Dec 1996

Mass Transport Of Volatile Organic Compounds Between The Saturated And Vadose Zones, Monte S. Harner

Theses and Dissertations

Volatile organic compounds (VOCs) dissolved in the saturated zone are transported into the vadose zone primarily by gaseous phase diffusion. If the saturated zone is remediated, VOCs present in the vadose zone may become a secondary source of contamination for the groundwater. The amount of VOCs that remain in the vadose zone is dependent on site hydrology, soil properties, and the chemical properties of the contaminants. The purpose of this study was to determine what conditions caused VOC concentrations in the vadose zone to significantly recontaminate the saturated zone. A one-dimensional numerical model was developed to investigate the transport of …


The Biodegradation Characteristics Of Proposed Fuel Systems Icing Inhibitors (Fsii), Charles E. Meshako Dec 1996

The Biodegradation Characteristics Of Proposed Fuel Systems Icing Inhibitors (Fsii), Charles E. Meshako

Theses and Dissertations

The biodegradation characteristics of three fuel system icing ihhibitors (FSII) were evaluated. FSII are jet fuel additives that partition into water readily and are present in the water drained from storage tank bottoms in concentrations approaching 40%. These concentrations raise concerns as to the disposal and handling of these wastes. The current FSII, DiEGME was evaluated along with two new candidates, dipropylene glycol and glycerol formal. DiEGME appeared to be moderately but not completely biodegradable. It is likely that much of it would be removed in a wastewater treatment plant. Dipropylene glycol only showed signs of degradation after more than …


An Activity Driver Based Analysis Of Hazardous Materials Usage At Wright-Patterson Afb, Charles D. Perham Dec 1996

An Activity Driver Based Analysis Of Hazardous Materials Usage At Wright-Patterson Afb, Charles D. Perham

Theses and Dissertations

As the Air Force has progressed and succeeded in the realm of pollution prevention, the opportunities for further progress have become more challenging. With the 'low-hanging fruit' now gone from the pollution prevention tree, new methods to identify opportunities must be adopted. This research effort applied a subset of activity based costing, activity driver analysis, to reveal pollution prevention opportunities in regards to hazardous materials usage. A sample of base organizations (civil engineering and aircraft maintenance), and a sample of the hazardous chemicals (Class C or most hazardous) used by those organizations were investigated to determine the drivers behind usage.


Modeling Marine Exposure To Polychlorinated Biphenyls From Sunken Ships, Charles N. Wendt Dec 1996

Modeling Marine Exposure To Polychlorinated Biphenyls From Sunken Ships, Charles N. Wendt

Theses and Dissertations

In the past, the U.S. Navy has routinely conducted SINKing EXercises (SINKEX) for training, weapon effectiveness tests, and economic disposal of aging assets. Recent concern over polychlorinated biphenyl (PCB) chemicals aboard such target vessels has resulted in a suspension of SINKEX. The U.S. Navy has approximately 200 vessels currently requiring such disposal. Environmental legislation and health concerns preclude selling such vessels to foreign governments or scrapping. This work attempted to model the fate and transport of these PCBs by examining their transport to coastal water and their accumulation in the marine food chain. The model includes biodegradation, upwelling, partitioning of …


An Exploration Of Environmental Technology Transition From The Laboratory To The Field, Michael A. Greiner Sep 1996

An Exploration Of Environmental Technology Transition From The Laboratory To The Field, Michael A. Greiner

Theses and Dissertations

Environmental policy, social factors, individual behavior, and environmental technologies are key factors in improving the current condition of the environment. The Department of Defense (DoD) is not immune to these aspects, as its actions have and will continue to impact the environment in which they conduct operations. The objective of this research is to analyze the environmental technology aspect of improving environmental conditions. Of particular interest, what barriers and bridges are encountered when an Air Force laboratory transitions environmental technologies to an end-user: operational field organization or major weapon system. The research employs a case study methodology to analyze five …