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Physical Sciences and Mathematics Commons

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Environmental Sciences

1994

Theses and Dissertations

Trichloroethylene--Environmental aspects

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Full-Text Articles in Physical Sciences and Mathematics

Experiment Using Infrared Spectroscopy To Study The Effect Of Soil Characteristics Upon The Rate Of Trichloroethylene Desorption, Benjamin T. Kindt Sep 1994

Experiment Using Infrared Spectroscopy To Study The Effect Of Soil Characteristics Upon The Rate Of Trichloroethylene Desorption, Benjamin T. Kindt

Theses and Dissertations

This research investigated the influence of soil characteristics on the desorption of trichloroethylene (TCE). TCE is one of the most common contaminants at Superfund sites. Unfortunately, extraction of TCE from contaminated soils has been hindered by its slow and poorly understood desorption from soil particles. The rate and progress of desorption of TCE from seven types of soil with varying particle diameters and elemental compositions was measured using optical absorption techniques. Fitting the data to the Langmuir Isotherm functional form predicted in the literature yielded parameters for the desorption rate and total amount desorption each soil type. These parameters were …


Use Of Infrared Spectrometry To Determine The Effect Of Temperature On The Description Rates Of Trichloroethylene From Plastic Clay 98b, Abdellatif Fares Aug 1994

Use Of Infrared Spectrometry To Determine The Effect Of Temperature On The Description Rates Of Trichloroethylene From Plastic Clay 98b, Abdellatif Fares

Theses and Dissertations

This thesis investigated the influence of temperature on the desorption rated of trichloroethylene (TCE) from plastic clay. It was expected that an increase in temperature will cause an increase in both the desorption rates of TCE and in the desorbed quantity. Previous studies on other chemicals indicated a faster decrease in the remaining sorbed concentration with an increase in temperature. This research made use of the infrared optical absorption technique. IR spectroscopy was used to measure the concentration of the vapor TCE that desorbed from the soil. The soil was exposed to liquid TCE for 2 days then placed inside …