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Full-Text Articles in Physical Sciences and Mathematics

Labile Dissolved Nickel (Ni) Concentrations In The North Pacific, Calyn M. Crawford Oct 2023

Labile Dissolved Nickel (Ni) Concentrations In The North Pacific, Calyn M. Crawford

USF Tampa Graduate Theses and Dissertations

Nickel (Ni) is an important micronutrient for phytoplankton and bacteria that serves as a required co-factor in several metalloenzymes. Despite these known biological uses, total dissolved Ni concentrations remain elevated in global surface waters, in contrast to the surface depletion commonly observed for macronutrients and other nutrient-type trace elements. A prevailing hypothesis for the muted depletion of dissolved Ni concentrations in surface waters is that dissolved Ni in seawater is not in a bioavailable form. The chemical lability of Ni in seawater provides insight into Ni speciation and bioavailability, but few measurements have been made in the open ocean to …


Investigating The Role Of Plant Traits And Interactions In Emergent Wetland Nutrient Removal, Andrew Ryan Sample Aug 2023

Investigating The Role Of Plant Traits And Interactions In Emergent Wetland Nutrient Removal, Andrew Ryan Sample

Theses and Dissertations

Increasing wetland restoration in the Lower Mississippi Alluvial Valley has been identified as a method to reduce nutrient loading in the Gulf of Mexico. Wetlands have historically been used to treat water through processes facilitated by wetland plants, and relatively few species and plant traits have been identified as important in carrying out these processes. This study focuses on some of those species and traits and aims to identify species differences and plant traits that may be important for wetland nutrient mitigation. Chapter I provides background information on nutrient pollution, wetland biogeochemical mechanisms for nutrient sequestration, and the focal species …


Nutrient Dynamics Of Freshwater Estuarine Sediments Disturbed By Dredging, Ryan Allan John Roekle Aug 2023

Nutrient Dynamics Of Freshwater Estuarine Sediments Disturbed By Dredging, Ryan Allan John Roekle

Theses and Dissertations

This study examined the nutrient environment of sediments in the Milwaukee River estuary and the dynamics of those nutrients during simulated disturbance experiments within the context of large-scale dredging remediation. Surface sediments were collected from throughout the Milwaukee estuary (including river, harbor, and nearshore stations) by PONAR, centrifuged to separate porewater (interstitial water) from solid material, and filtered to further isolate and stabilize dissolved material. Porewaters were analyzed for dissolved nutrients including ammoniacal nitrogen (AN), nitrate, nitrite, and soluble reactive phosphorus (SRP). Surface sediment porewaters within the estuary were often highly enriched in AN and SRP, which were often 10-2000x …


Getting The Dirt On Phosphorus Pollution In Mountain Lakes: Are Rising Soil Temperatures Contributing To Eutrophication In Mountain Watersheds?, Gordon O. Gianniny May 2023

Getting The Dirt On Phosphorus Pollution In Mountain Lakes: Are Rising Soil Temperatures Contributing To Eutrophication In Mountain Watersheds?, Gordon O. Gianniny

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Mountain watersheds provide a critical supply of clean water to millions of people around the world. In recent years, evidence of a concerning trend has emerged in these watersheds: rising phosphorus (P) concentrations. P often acts as the limiting nutrient in mountain lake ecosystems, so increasing P availability in mountain lakes and streams has the potential to drastically increase algal growth in these systems. In extreme cases, increasing mountain lake P concentrations may even cause harmful algal blooms that degrade downstream water quality. While the implications of rising P concentrations in mountain lakes are serious, the cause driving this widespread …


Contrasting Seasonal Cycling Of Arsenic In A Series Of Subarctic Shield Lakes With Different Morphometric Properties, Jeremy Harbinson Jan 2023

Contrasting Seasonal Cycling Of Arsenic In A Series Of Subarctic Shield Lakes With Different Morphometric Properties, Jeremy Harbinson

Theses and Dissertations (Comprehensive)

The subarctic shield near Yellowknife, Northwest Territories (NWT), is populated with thousands of small lakes (<1.5 km2) and several large lakes. Historic mining activities in the region have left a legacy of environmental impacts and widespread arsenic (As) contamination in both aquatic and terrestrial environments. In particular, several small subarctic lakes near Yellowknife have been previously documented to be contaminated with high levels of As. Subarctic lakes are characterized by seasonal ice-cover that can persist for more than half of the year, yet little is known about the under-ice spatial and seasonal dynamics of As cycling. The objective of …