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Articles 1 - 30 of 46
Full-Text Articles in Physical Sciences and Mathematics
Molecular Insights Into The Redox Of Atmospheric Mercury Through Laser Spectroscopy, Rongrong Wu Cohen
Molecular Insights Into The Redox Of Atmospheric Mercury Through Laser Spectroscopy, Rongrong Wu Cohen
Theses and Dissertations
The widespread pollution of mercury motivates research into its atmospheric chemistry and transport. Gaseous elemental mercury (Hg(0)) dominates mercury emission to the atmosphere, but the rate of its oxidation to mercury compound (Hg(II)) plays a significant role in controlling where and when mercury deposits to ecosystems. Atomic bromine is regarded as the main oxidant for Hg(0) oxidation, known to initiate the oxidation via a two-step process in the atmosphere – formation of BrHg (R1) and subsequent reactions of BrHg with abundant free radicals Y, i.e., NO2, HOO, etc. (R2), where the reaction of BrHg +Y could also lead to the …
Towards Structured Planning And Learning At The State Fisheries Agency Scale, Caleb A. Aldridge
Towards Structured Planning And Learning At The State Fisheries Agency Scale, Caleb A. Aldridge
Theses and Dissertations
Inland recreational fisheries has grown philosophically and scientifically to consider economic and sociopolitical aspects (non-biological) in addition to the biological. However, integrating biological and non-biological aspects of inland fisheries has been challenging. Thus, an opportunity exists to develop approaches and tools which operationalize planning and decision-making processes which include biological and non-biological aspects of a fishery. This dissertation expands the idea that a core set of goals and objectives is shared among and within inland fisheries agencies; that many routine operations of inland fisheries managers can be regimented or standardized; and the novel concept that current information and operations can …
Common Ground Over Common Water: Defining The Public Interest In The Milwaukee Watershed, Thomas Anthony Gentine
Common Ground Over Common Water: Defining The Public Interest In The Milwaukee Watershed, Thomas Anthony Gentine
Theses and Dissertations
My dissertation examines government and nongovernment entities’ attempts to restore and protect the use and health of the Milwaukee River and its watershed from 1960 to 2000. Under Mayor Henry Maier’s leadership, Milwaukee worked to reclaim the urban riverway to stimulate economic growth. However, state and federal representatives, after the passage of the 1965 Water Quality Act, demanded that the city government prioritize updating the combined storm and sewer system to lessen pollution in the Milwaukee River. At the same time, other groups worked to save rural areas from unplanned development and further degradation of the waterway. Influential groups included …
Dynamic Soil Properties In The Lower Rio Grande Valley: Carbon And Nitrogen Responses To Different Tillage Practices, Luzyannet Ballesteros Gonzalez
Dynamic Soil Properties In The Lower Rio Grande Valley: Carbon And Nitrogen Responses To Different Tillage Practices, Luzyannet Ballesteros Gonzalez
Theses and Dissertations
There has been increased attention in utilizing agriculture for carbon sequestration. Soil carbon and nitrogen are two dynamic soil properties (DSPs) that are indicators of soil health and function and have overlapping cycles. These soil properties change frequently as a result of environmental conditions and agricultural management practices. This study focuses on the impact of tillage practices in unirrigated agricultural fields in Hidalgo and Willacy counties located in South Texas on Hidalgo Sandy Clay Loam; With a particular focus on Soil Total Carbon (TC), Soil Inorganic Carbon (SIC), Permanganate Oxidizable Carbon (POXC), Carbon and Nitrogen ratio (C:N), Soil Organic Matter …
Conjunctive Management For Groundwater-Surface Water Resources: Numerical Modeling And Potential Assessment Of Managed Aquifer Recharge (Mar) At Lower Rio Grande Valley In South Texas, Dwight Zedric Q. Capus
Conjunctive Management For Groundwater-Surface Water Resources: Numerical Modeling And Potential Assessment Of Managed Aquifer Recharge (Mar) At Lower Rio Grande Valley In South Texas, Dwight Zedric Q. Capus
Theses and Dissertations
Texas is well known to frequent floods and droughts, and yet has mounting concerns in very imbalanced water availability and water demands from growth in population and economical activities. Capturing and storing water is essential to long-term and climate-smart management of the “already-scarce” water resources. This study aimed to apply numerical modeling to evaluate potentials and impacts of Managed Aquifer Recharge (MAR) to regional groundwater systems in the Lower Rio Grande Valley. Using Visual MODFLOW Flex 3D package, different scenarios were simulated for groundwater flow patterns and storage capacities. Water injections tested ranged between 7.30x105 ft3 to 3.65x109 ft3 , …
South Texas Wildlife Activity Across A Fragmented Landscape And Road Mitigation Corridor, Caitlin K. Brett
South Texas Wildlife Activity Across A Fragmented Landscape And Road Mitigation Corridor, Caitlin K. Brett
Theses and Dissertations
Wildlife crossing structures (WCS) and roadside fencing are commonly installed to mitigate habitat fragmentation, wildlife road mortalities, and other negative effects that roads can have on the surrounding landscape. Eight such WCS were constructed below Farm-to-Market (FM)106 in Cameron County, Texas, across a 16 km corridor transecting the Laguna Atascosa National Wildlife Refuge. These WCS, paired with adjacent roadside fencing, were intended to prevent road mortalities of the endangered ocelot (Leopardus pardalis) and to mitigate the barrier effect of FM106 on this and other meso-mammal species. This study will analyze camera trap data from roadside and habitat reference …
Investigating The Relationship Between Dissolved Oxygen And Nitrate Concentration As A Proxy For Marine Ecosystem Health, Natalia M. Moore
Investigating The Relationship Between Dissolved Oxygen And Nitrate Concentration As A Proxy For Marine Ecosystem Health, Natalia M. Moore
Theses and Dissertations
Coastal environments such as seagrass meadows span a wide range of spatial scales and can experience disturbances that cause rapid shifts to ecosystem dynamics. Increased pressure to the coastal zone has highlighted the need for constant, real-time monitoring to monitor current ecosystem status. A custom, low cost, high resolution, in situ sensor network was designed and tested in the Lower Laguna Madre, Texas to characterize primary productivity in seagrass meadows through gradient patterns of dissolved oxygen concentration, with the purpose of determining whether seagrass or phytoplankton were the more dominant primary producer. There was a distinct vertical and horizontal gradient …
Influence Of Pretreatments On Physiological Status And Post-Planting Survival Of Thornforest Seedlings In A Restoration Context, Douglas E. Mainhart
Influence Of Pretreatments On Physiological Status And Post-Planting Survival Of Thornforest Seedlings In A Restoration Context, Douglas E. Mainhart
Theses and Dissertations
Semi-arid ecosystems across the globe have faced land conversion posing a threat to the important ecosystem services they provide. Revegetation-centered restoration efforts in arid regions have low success due to limited water availability and higher temperatures. Typically, practitioners utilize methods that modify field conditions around seedlings to mitigate these stressors. I evaluated the efficacy of in-nursery treatments to improve plant water status. Three pretreatments were applied: elevated CO2, drought hardening, and an antitranspirant foliar spray. My goal was to understand how these pretreatments would impact survival and growth in the field and what physiological traits they altered. Elevated CO2 and …
Incorporating Native Plants In Insectary Strips To Promote Insect Diversity And Below-Ground Beneficial Microbes In South Texas, Lindsey N. Richards
Incorporating Native Plants In Insectary Strips To Promote Insect Diversity And Below-Ground Beneficial Microbes In South Texas, Lindsey N. Richards
Theses and Dissertations
Farm edges are generally the most undisturbed areas in a farm with diverse vegetation and can enhance agrobiodiversity and provide crucial food and shelter for wildlife, insects, and soil biota. Planting native wildflowers with the ability to reseed and withstand local climatic conditions for semi-permanent vegetation around farm edges or in between crops has potential to biologically control pests. To test this, we ran a two-year study and installed three different flowering insectary strips on a certified organic vegetable farm in South Texas during the winter season. The treatments were: 1) a commercially sourced 17-species native wildflower seed mix; 2) …
Weather Parameters Influencing The Incidence Of Citrus Canker Caused By Aw Strain In The Rio Grande Valley, Amit Sharma
Weather Parameters Influencing The Incidence Of Citrus Canker Caused By Aw Strain In The Rio Grande Valley, Amit Sharma
Theses and Dissertations
Citrus canker caused by bacterium Xanthomonas citri subsp. citri (Xcc) seriously affects the citrus industry by making the fruit unmarketable due to unsightly lesions on the fruit. Canker caused by Aw strain of Xcc was reported in the citrus trees located in the residential areas of the Rio Grande Valley (RGV). Canker severity differs amongst cultivars/varieties, and it is influenced by prevailing environmental conditions. Multiple regression modeling of the disease incidence with the environmental variables such as temperature, humidity, windspeed, wind gust, and rainfall was performed to understand the environmental conditions that are favorable for spread of citrus …
Urban Flooding Accelerates The Affordable Housing Shortage: A Case Study In Columbia, South Carolina, Mary Hannah Lindsay
Urban Flooding Accelerates The Affordable Housing Shortage: A Case Study In Columbia, South Carolina, Mary Hannah Lindsay
Theses and Dissertations
The state of South Carolina stands at the corner where climate change and the housing crisis meet. The affordable housing stock across South Carolina continues to deplete as its major cities experience urban flooding events due to outdated and weakened infrastructure, compounded by an intensification of storm systems brought on by a changing climate. Lower income communities are forced to accept lesser living conditions and less resilient housing options because these options are more affordable. Renters are often met with more challenges when navigating disaster recovery compared to homeowners. Using a case study established in Columbia, South Carolina of the …
Improvement Value Of Forest Resources By Use Of Cottonseed Protein Meal As A Bio-Based Wood Adhesive For Hardwood Plywood Products, Edward David Entsminger
Improvement Value Of Forest Resources By Use Of Cottonseed Protein Meal As A Bio-Based Wood Adhesive For Hardwood Plywood Products, Edward David Entsminger
Theses and Dissertations
Literature shows that production of cottonseed adhesives is feasible to develop an environmentally friendly and competitive bio-based wood adhesive. Defatted cottonseed and water-washed cottonseed meals were prepared from glandless cottonseed and were used in adhesive formulations to produce three-ply yellow poplar (Liriodendron tulipifera) plywood panels as the first objective. These two cottonseed meals were compared with the properties of plywood panels made with an adhesive formulated from a commercial soybean meal, as a control. Adhesive resins were prepared from each protein meal with sodium metabisulfite (Na2S2O5) and one of two polyamido-amine-epichlorohydrin (PAE) wet strength agents, and the plywood panels were …
Defining Viable Solar Resource Locations In The Southeast United States Using The Satellite-Based Glass Product, Jolie Kavanagh
Defining Viable Solar Resource Locations In The Southeast United States Using The Satellite-Based Glass Product, Jolie Kavanagh
Theses and Dissertations
This research uses satellite data and the moment statistics to determine if solar farms can be placed in the Southeast US. From 2001-2019, the data are analyzed in reference to the Southwest US, where solar farms are located. The clean energy need is becoming more common; therefore, more locations than arid environments must be observed. The Southeast US is the main location of interest due to the warm, moist environment throughout the year. This research uses the Global Land Surface Satellite (GLASS) photosynthetically active radiation product (PAR) to determine viable locations for solar panels. A probability density function (PDF) along …
Determining The Effects Of Elevated Carbon Dioxide On Soil Acidification, Cation Depletion, And Soil Inorganic Carbon And Mapping Soil Carbons Using Artificial Intelligence, Jannatul Ferdush
Theses and Dissertations
Soil carbon is the largest sink and source of the global carbon cycle and is disturbed by several natural, anthropogenic, and environmental factors. The global increase of atmospheric CO2 affects soil carbon cycling through varied biogeochemical processes. The first chapter is a compilation of current information on potential factors triggering soil acidification and weathering mechanisms under elevated CO2 and their consequences on soil inorganic carbon (SIC) pool and quality. Soil water content and precipitation were critical factors influencing elevated CO2 effects on the SIC pool. The second chapter examines a detailed column experiment in which six soils …
Fish Community Analysis Using Multidirectional Rov Video Surveys In The Northwestern Gulf Of Mexico, Keegan J. Angerer
Fish Community Analysis Using Multidirectional Rov Video Surveys In The Northwestern Gulf Of Mexico, Keegan J. Angerer
Theses and Dissertations
In this study, ROV surveys with multidirectional video were used to analyze the fish communities associated with artificial reef patches in the Rio Grande Valley artificial reef 13.7 km off the coast of South Padre Island, TX. Nine configurations of reef patches consisting of varying combinations and densities of concrete pyramid and low-profile modules were surveyed. The highest species diversity was found at patches with large deployments of both pyramids and low-profile modules. Total Red Snapper Lutjanus campechanus abundance did not differ between configurations, but the highest abundances of juvenile Red Snapper were found at configurations with one pyramid and …
Tree Ring Reconstructions Of Streamflow For The Lower Rio Grande Valley Of Texas, Adedolapo Mutiyat Adeyanju
Tree Ring Reconstructions Of Streamflow For The Lower Rio Grande Valley Of Texas, Adedolapo Mutiyat Adeyanju
Theses and Dissertations
The Rio Grande River is a major water source for people living within the USA-Mexico border. The Rio Grande River has its headwaters in the San Juan Mountains in Colorado and the Sierra Madre Occidental in Mexico before flowing into Texas through El-Paso. The water supply issues facing the Lower Rio Grande Basin (LRGB) are extremely complex from international restrictions to severe climate change. The river shares its flow between the U.S.A and Mexico based on the provisions of the 1944 treaty between the U.S.A and Mexico. The LRGB flow is regulated by releases from Falcon and Amistad Reservoirs managed …
Quantifying And Predicting Drought Performance In Woody Semi-Arid Seedlings In South Texas: Implications For Enhancing Drought Resilience In Restoration, Zarek Contreras
Quantifying And Predicting Drought Performance In Woody Semi-Arid Seedlings In South Texas: Implications For Enhancing Drought Resilience In Restoration, Zarek Contreras
Theses and Dissertations
Increasingly frequent and severe droughts in the Lower Rio Grande Valley National Wildlife Refuge have been observed to cause large variation in species-specific mortality patterns in young seedlings, spanning 6 – 43 % mortality within the first year. To understand the underlying mechanisms behind this, we subjected seedlings of five woody semi-arid species (Celtis pallida, Forestiera angustifolia, Sideroxylon celastrinum, Phaulothalmnus spinescens, and Zanthoxylum fagara) to a point-of-no-return drought experiment in order to (1) identify potential metrics capable of predicting species wilting and mortality responses, and (2) to understand the underlying mechanisms that correspond to species drought performance …
Red Drum (Sciaenops Ocellatus) Trophic Web Reconstruction Using Stable Isotopes In Two Systems In The Northwestern Gulf Of Mexico, Elizabeth Mogus Garcia
Red Drum (Sciaenops Ocellatus) Trophic Web Reconstruction Using Stable Isotopes In Two Systems In The Northwestern Gulf Of Mexico, Elizabeth Mogus Garcia
Theses and Dissertations
Estuaries act as nurseries for many important fishes, including predators like Red Drum (Sciaenops ocellatus). Using gut content and stable isotope analyses to better understand juvenile S. ocellatus’ diet and role within the trophic web, a full year of data was collected on a quarterly basis to illustrate a change in diet based on resource availability at two study sites and for two non-overlapping S. ocellatus sizes. Panopeidae and Penaeidae were the most abundant prey items found in S. ocellatus stomachs for both sizes, sites, and four quarters representing over 50% of the diet. Stable isotope analyses …
Assessing Intra-Urban Particulate Matter (Pm2.5) Concentrations At The Lower Rio Grande Valley (Rgv), South Texas, Usa, Using Low-Cost Sensors, Esmeralda Mendez
Assessing Intra-Urban Particulate Matter (Pm2.5) Concentrations At The Lower Rio Grande Valley (Rgv), South Texas, Usa, Using Low-Cost Sensors, Esmeralda Mendez
Theses and Dissertations
Rapid technological developments of novel low-cost air quality sensors enable long-term ambient monitoring in neighborhood areas. In this study, spatial and temporal trends are analyzed by localized level monitoring with low-cost sensors (TSI BlueSky Air Quality Monitor). Eleven low-cost sensors were deployed across the Lower Rio Grande Valley, South Texas region: Brownsville, Edinburg, Weslaco, and Port Isabel. 24-hour PM2.5 concentrations are correlated with PM2.5 from existing Texas Commission on Environmental Quality (TCEQ) Continuous Ambient Monitoring Stations (CAMSs) to express temporal and spatial heterogeneity from March 01, 2021, to March 31, 2022. Results indicated the deployed low-cost sensors as a better …
Network Analysis Of Scientific Research In The Gulf Of Mexico, Juliet S. Vallejo
Network Analysis Of Scientific Research In The Gulf Of Mexico, Juliet S. Vallejo
Theses and Dissertations
The Gulf of Mexico ecosystem represents a significant management challenge in its 3,423-mile coastline and transnational regulatory setting, along five states from the United States, six states from Mexico, and Cuba which borders the southeastern quadrant. Providing various resources to the regional economies, the continued success of these resources depends on the collaboration among transnational participants in bringing together complementary skills and multidisciplinary approaches to producing, circulating, and utilizing scientific knowledge. Using bibliometric analysis of Gulf of Mexico-related published research over 18 years from 2000 to 2018 allows for identifying organizations, their connections, and trends in the production of scientific …
Growth And Reproduction In Gulf Of Mexico Black Corals (Antipatharians) In Field And Laboratory Studies, Victoria E. Salinas
Growth And Reproduction In Gulf Of Mexico Black Corals (Antipatharians) In Field And Laboratory Studies, Victoria E. Salinas
Theses and Dissertations
Black corals provide an important ecosystem of marine life and are found throughout all the oceans of the world at depths between 2 and 8,600 m. However, little is understood about their life history and the factors that control the distribution of black corals, particularly in the Gulf of Mexico (GoM). Given the impacts of the Deepwater Horizon oil spill on soft corals (e.g., black corals and octocorals) in the GoM, studies of their growth and reproductive biology in both natural and aquaculture environments are crucial for restoration efforts. The objectives of this study were to examine reproductive processes, compare …
Understanding The Spatio-Temporal Evolution Of Surface Heat Flux In The Tropics From Observations And Models, Xin Zhou
Theses and Dissertations
An important component of the earth’s surface energy budget is the surface heat flux that allows the exchange of mass and energy between the ocean and the atmosphere and thereby influences oceanic and atmospheric circulations. For better prediction of weather and climate, numerical models must be able to capture the mean and variability of surface heat flux since surface heat flux directly feeds into model simulation of convection and precipitation. In this study, we explore the spatial and temporal variations of different surface heat flux components over the tropical oceans using observations and atmospheric global climate models (AGCMs). We confine …
Effects Of Nutrient Enrichment On Mangrove And Saltmarsh Habitats, Elena A. Flores
Effects Of Nutrient Enrichment On Mangrove And Saltmarsh Habitats, Elena A. Flores
Theses and Dissertations
Nutrient over-enrichment is a global threat to coastal and marine environments. Yet, system-specific attributes of estuarine and coastal ecosystems may result in large differences in their sensitivity and susceptibility to such threat. In tropical latitudes, plant species adapted to low-nutrient habitats generally have nutrient-conservation mechanisms that acquire, use, and internally recycle nutrients efficiently. Thus, a major challenge for managers and decision makers is to develop a predictive and holistic understanding of how nutrient loading alters ecosystem functions and therefore ecosystem services. The objective of the present research is to document short and long-term effects of persistent nutrient …
Analyzing The Impact Of Governance Strategies On Trust And Risk In The Salish Sea Transboundary Fishery Context, Evelyn Roozee
Analyzing The Impact Of Governance Strategies On Trust And Risk In The Salish Sea Transboundary Fishery Context, Evelyn Roozee
Theses and Dissertations
The Salish Sea is the site of a transboundary fishery whose coastal jurisdiction includes British Columbia, Washington State, the two federal governments, and many Indigenous tribes with sovereign rights. Fishery management becomes increasingly complex when transboundary cooperation is needed. Furthermore, while the Salish Sea region has attempted to facilitate better transboundary collaborative governance, these have generally failed to institutionalize the principles of adaptive management. This research seeks to assess current trust and risk perceptions and analyze the effects of control mechanisms used in the transboundary fishery management network. The data consists of a survey measuring collaborative precursors, barriers, and outcomes …
Use Of Consumer Grade Small Unmanned Aerial Systems (Suas) For Mapping Storm Damage In Forested Environments, James Dewey Cox
Use Of Consumer Grade Small Unmanned Aerial Systems (Suas) For Mapping Storm Damage In Forested Environments, James Dewey Cox
Theses and Dissertations
Storm damages to forested environments pose significant challenges to landowners, land managers, and conservationists alike. Damage scope and scale assessments can be difficult, costly, and time consuming with conventional pedestrian survey techniques. Consumer grade sUAS technology offers an efficient, cost-effective way to accurately assess storm damage in small to moderate sized survey areas (less than 10 km²). Data were collected over a 0.195 km² area of damaged timber within the Kisatchie National Forest in Central Louisiana using a DJI Mavic 2 Pro drone. Collected imagery was processed into an orthomosaic using Agisoft Metashape Professional with a resulting ground sampling distance …
Exploring The Impact Of End-User Engagement On The Diffusion And Adoption Of A Climate Resilience Tool In The Gulf Of Mexico, Renee C. Collini
Exploring The Impact Of End-User Engagement On The Diffusion And Adoption Of A Climate Resilience Tool In The Gulf Of Mexico, Renee C. Collini
Theses and Dissertations
Climate change-related hazards negatively impact ecosystems, economies, and quality of life. Significant resources have been invested in data collection and research with the goal of enhanced understanding and capacity to predict future conditions in order to mitigate or adapt to intensifying hazard risk. The expansive production of climate science has generated a necessary complimentary enterprise dedicated to enhancing decision-makers’ understanding of and access to climate science as it is essential for future societal and ecological well-being. Though the aim of these many tools is to support resilient decision-making in the face of climate change, professionals report an underutilization of climate …
Cover Crops And Irrigation Impacts On Corn And Soybean Production In The Mid-Southern Usa, Dillon Aaron Russell
Cover Crops And Irrigation Impacts On Corn And Soybean Production In The Mid-Southern Usa, Dillon Aaron Russell
Theses and Dissertations
Reducing groundwater withdrawals from the Mississippi River Valley Alluvial Aquifer is imperative to sustain future irrigated cropping systems in the mid-southern USA. This research was conducted to determine the impacts of cover crops and irrigation sensor thresholds on corn (Zea mays L.) and soybean (Glycine max L.) production, water productivity, irrigation water use efficiency, and soil physical properties in the Mississippi Delta. The cover crop treatments included cereal rye (Secale cereale L.), hairy vetch (Vicia villosa R.), wheat (Triticum aestivum L.)-radish (Raphanus sativus L.)-turnip (Brassica rapa L.) mix, and no cover crop. The irrigation thresholds included -40 kPa, -90 kPa, …
Evaluating Soil Health Changes Following Cover Crop And No-Till Integration Into A Soybean (Glycine Max) Cropping System In The Mississippi Alluvial Valley, Alexandra Gwin Firth
Evaluating Soil Health Changes Following Cover Crop And No-Till Integration Into A Soybean (Glycine Max) Cropping System In The Mississippi Alluvial Valley, Alexandra Gwin Firth
Theses and Dissertations
The transition of natural landscapes to intensive agricultural uses has resulted in severe loss of soil organic carbon (SOC), increased CO₂ emissions, river depletion, and groundwater overdraft. Despite negative documented effects of agricultural land use (i.e., soil erosion, nutrient runoff) on critical natural resources (i.e., water, soil), food production must increase to meet the demands of a rising human population. Given the environmental and agricultural productivity concerns of intensely managed soils, it is critical to implement conservation practices that mitigate the negative effects of crop production and enhance environmental integrity. In the Mississippi Alluvial Valley (MAV) region of Mississippi, USA, …
Quantifying The Economic Impact Of Conservation Policy Changes Utilizing Precision Agriculture Tools, Kyle Stanley Watkins
Quantifying The Economic Impact Of Conservation Policy Changes Utilizing Precision Agriculture Tools, Kyle Stanley Watkins
Theses and Dissertations
The United States Farm Bill is a multi-billion-dollar federal legislation reenacted every five years to provide funding towards crop protection, nutrition, environmental protection, and other important focuses. The largest conservation program within the Farm Bill is the Conservation Reserve Program, which encompasses many conservation practices such as CP-33: habitat buffers for upland birds. Conservation implementation through the Farm Bill relies on voluntary producer enrollment in exchange for a rental fee to not farm enrolled land for a set time. I used yield data collected across six years from 36 agricultural fields in Humphreys and Holmes counties, Mississippi, USA, and a …
Photocatalytic Degradation Of Organic Contaminants By Titania Particles Produced By Flame Spray Pyrolysis, Noah Babik
Photocatalytic Degradation Of Organic Contaminants By Titania Particles Produced By Flame Spray Pyrolysis, Noah Babik
Theses and Dissertations
Advanced oxidation of organic pollutants with TiO2 photocatalysts is limited due to the wide bandgap of TiO2, 3.2 eV, which requires ultraviolet (UV) radiation. When nanosized TiO2 is modified by carbon doping, charge recombination is inhibited and the bandgap is narrowed, allowing for efficient photodegradation under visible light. Here, we propose a flame spray pyrolysis (FSP) technique to create TiO2. The facile process of FSP has been successful in preparing highly crystalline TiO2 nanoparticles. Using the same procedure to deposit TiO2 onto biochar, the photocatalyst was doped by the carbonaceous material. The morphology, crystalline and electronic structure of the FSP …