Physical Sciences and Mathematics Commons^™

The Impact Of Nanomaterial Functionalization And Core Chemical Composition On Toxicity To Daphnia Magna, Jared S. Bozich

Theses and Dissertations

Nanomaterials (NMs) are being developed for a variety of industrial, biomedical, and environmental applications. Initially these materials consisted of simple metal oxides or carbon based NMs. More recently NMs have become increasingly complex consisting of multiple transition metals and surfaces functionalized with polymers, surfactants and ligands that have the ability to alter their physiochemical properties and enhance performance. As manufactured NM production increases, so does the concern about their release into the environment and potentially harmful effects. The focus of toxicology has largely been on first generation materials and we have comparatively less information about the potential impacts of complex …

A Multi-Faceted Biogeochemical Approach To Analyzing Hypoxia In Green Bay, Lake Michigan, Shelby Labuhn

Theses and Dissertations

Green Bay, Lake Michigan is a large freshwater estuary that has experienced seasonal hypoxia for decades. Hypoxia, or dissolved oxygen concentrations less than 2 mg L-1, is a problem in coastal ecosystems around the world because it has a negative impact on ecosystem health by decreasing biodiversity and fisheries. In order to create adequate management policies for hypoxia, it is important to understand the sources and sinks of oxygen within Green Bay. This study utilizes a number of traditional and novel field methods to measure the production and respiration of oxygen within lower Green Bay, defined as south of Chambers …

Determining The Impacts Of Environmental Contaminants To Zebra Mussels Using Genetic Biomarkers, Nicklaus James Neureuther

Theses and Dissertations

ABSTRACT

DETERMINING THE IMPACTS OF ENVIRONMENTAL CONTAMINANTS TO ZEBRA MUSSELS USING GENETIC BIOMARKERS

by

Nicklaus James Neureuther

The University of Wisconsin-Milwaukee, 2016

Under the Supervision of Professor Rebecca Klaper, PhD

Persistent legacy contaminants and emerging chemicals of concern continue to be a threat to the function and health in the Great Lakes Areas of Concern (AOCs). While chemical monitoring programs traditionally sample water and sediment, these studies can only provide information of the type and level of contamination within an (AOC). This being said, information on the biological impacts to the biota are needed to measure impairments of chemical exposure, …

Identifying With “The Native” In Anglo-American Environmental Writing: A Rhetorical Study, Alexis Piper

Theses and Dissertations

ABSTRACT

IDENTIFYING WITH “THE NATIVE”

IN ANGLO-AMERICAN ENVIRONMENTAL WRITING:

A RHETORICAL STUDY

by

Alexis F. Piper

The University of Wisconsin-Milwaukee, 2016

Under the Supervision of Professor Anne Wysocki

In an effort to contribute to rhetorical theories of “identification” this dissertation examines Anglo nature writing written for Anglo audiences in the United States over several centuries. In my conclusion, I suggest approaches current nature writers might use to offer audiences ways of engaging with Indigenous peoples and Native conceptions of environment that are more ethical, appropriate, and effective than approaches used in previous centuries. I maintain that such approaches could potentially …

Bringing The Outside In: Examining The Impacts That Climate, Exchange, And Identity Processes Have On Organizationally-Beneficial Employee Green Behavior, Sashi C. Sekhar

Theses and Dissertations

My dissertation contributes to growing practitioner and researcher interest in the corporate social responsibility topic of employee green behavior, a key strategic input to organizational environmental sustainability efforts. While it has been recognized that employee behavior can significantly impact sustainability efforts (Daily, Bishop, and Govindarajulu, 2009; Ones and Dilchert, 2012), the psychological mechanisms through which this occurs and the precise nature of these behaviors have not been rigorously examined. To address the gaps, my research investigates the interrelationship between organizational and individual factors in motivating organizational citizenship behavior directed toward the natural environment (OCB-E). The model, which derives from social …

Chemical Forms Of Nitrogen In Runoff From Diverse Florida Watersheds, Jessica Emily Voelker

Theses and Dissertations

Watershed use along the Indian River Lagoon (IRL) on the central east coast of Florida has changed drastically during the past century, bringing with it declining water quality, eutrophication, hypoxia and fish kills. The decline of the lagoon has been directly linked to nutrient overloading; however, the sources and chemical forms of nutrients to the IRL are still not well constrained. This study was designed to determine how watershed land use impacts concentrations and fluxes of the various forms of dissolved nitrogen to the IRL. Five tributaries to the IRL were sampled monthly from July 2015 – September 2016. Storm …

Corrosion Of Aluminum Current Collector In Cost Effective Rechargeable Lithium-Ion Batteries, Shengyi Li

Theses and Dissertations

Rechargeable lithium ion batteries (LIB) have been widely used as commercial energy storage systems for portable equipment, electronic devices and high power applications (e.g. electronic vehicles). One issue with the commercialized LIB is that expensive, highly toxic and flammable organic solvents are used in the electrolyte and the fabrication process of electrodes. The toxic organic based solvents increase the production cost and lead to significant safety concerns in the event of a battery overcharge or short circuit. The recent development of “green manufacturing” technology allows manufacturers to replace the organic solvents used in the cathode coating process by aqueous based …

Eco Ephemeral: Works By Thomas Ferrella & Artists’ Books From Special Collections, Uw-Milwaukee Libraries, Pamela Caserta Hugdahl

Theses and Dissertations

This thesis essay and accompanying exhibition approach environmental concerns through an art historical perspective by considering works of art by Thomas Ferrella, M.D. and artists’ books from Special Collections at UW-Milwaukee Libraries. The exhibition evades conventional boundaries of galleries in order to present artists’ books in their intended manner and to display Ferrella’s outdoor installations in context with UWM’s award-winning sustainability initiatives. The results exemplify how we shape earth and in turn how our actions upon earth impact us, emphasizing human interdependence on fragile ecosystems. Ferrella’s artworks and medical expertise in combination with the content in the artists’ books and …

Simulation Of Value Stream Mapping And Discrete Optimization Of Energy Consumption In Modular Construction, Md Mukul Chowdhury

Theses and Dissertations

With the increased practice of modularization and prefabrication, the construction industry gained the benefits of quality management, improved completion time, reduced site disruption and vehicular traffic, and improved overall safety and security. Whereas industrialized construction methods, such as modular and manufactured buildings, have evolved over decades, core techniques used in prefabrication plants vary only slightly from those employed in traditional site-built construction. With a focus on energy and cost efficient modular construction, this research presents the development of a simulation, measurement and optimization system for energy consumption in the manufacturing process of modular construction. The system is based on Lean …

Takeover On The Tallgrass Prairie: How Lespedeza Cuneata Establishes Dominance, Morgan Rae Walder

Theses and Dissertations

Invasion ecology aims to study mechanisms by which invasive species are able to enter, establish, and spread within an ecosystem. This study analyzed Darwin’s naturalization and the biotic resistance hypotheses as the most likely explanations for invasion by an exotic legume, Lespedeza cuneata, into a tallgrass prairie. Darwin’s naturalization hypothesis posits that exotic species are less able to establish in communities that have related species, because similarity in morphology and function promotes intense competition for resources. The biotic resistance hypothesis states that competitors, herbivores, and pathogens already present in the community limit the colonization, naturalization, and persistence of invaders, therefore …

A Gis Analysis Of Land Cover Effects On Water Systems: Nutrients And Algae In Stormwater Ponds, Nicole Lee Kappel

Theses and Dissertations

Anthropogenic land conversion is occurring rapidly and has the potential to impact our water quality. This study aims to explore the effect of watershed land characteristics on water quality within stormwater ponds (SWPs). Rapid land conversion is known to affect water quality of receiving water bodies, however not much is known about the effect of urbanization on SWPs. Geographic informational systems (GIS) was used to determine areas of land that drain into ponds. Water samples were collected and analyzed for total phosphorous, dissolved reactive phosphorous, nitrate, and ammonia. Algal pigment and percent cover measurements were taken in the field and …

An Integrated Environmental Analysis Framework For Multi-Functional Urban Food Production Utilizing Nutrient Recycling From Organic Waste Streams, William Kort

Theses and Dissertations

Increasing enthusiasm for local food, including urban agriculture, has piqued research interest in the tenets underlying perceived benefits of localizing food production. This study develops and demonstrates the application of a comprehensive framework for the life cycle environmental assessment of the utilization of urban organic wastes in urban agriculture, specifically fruit and vegetable production. Results indicate that this full “urban nutrient cycle” may have significant environmental benefits in terms of land area requirements, water use, wastewater generation, nutrient recovery, environmental contamination and green infrastructure potential, compared to more conventional methods of waste processing and food production. Urban intensive food production …

Rational Design Of Cathode Materials For High Performance Lithium-Sulfur Batteries, Xi Chen

Theses and Dissertations

Sulfur, one of most promising cathode candidates for next-generation lithium ion batteries, shows a limited cycling performance due to its shuttling effect, low conductivity, self-discharge and volume expansion during lithiation and delithiation process. According to the operation principles, failure mechanism, and recent progress on lithium-sulfur batteries, here we developed several scalable and rational synthesis methods for high performance cathode materials. We dissolved commercial sulfur to anhydrous ethylenediamine (EDA) to form an EDA-S precursor, and then we reduced the sulfur particles size at conductive carbon black substrate. The 70% theoretical capacity of sulfur cathode battery was obtained. We also melted commercial …

Addressing Instability Issues In Microgrids Caused By Constant Power Loads Using Energy Storage Systems, Eklas Hossain

Theses and Dissertations

Renewable energy sources, the most reasonable fuel-shift taken over the naturally limited conventional fuels, necessarily deal with the self-functional microgrid system rather than the traditional grid distribution system. The study shows that the microgrid system, a comparatively low-powered system, experiences the challenge of instability due to the constant power load (CPL) from many electronic devices such as inverter-based systems. In this dissertation, as a methodical approach to mitigate the instability complication, AC microgrid stability is thoroughly investigated for each and every considerable parameter of the system. Furthermore, a specific loading limit is depicted by evaluating the stability margin from the …

Transient Control Of Synchronous Machine Active And Reactive Power In Micro-Grid Power Systems, Luke Gerard Weber

Theses and Dissertations

There are two main topics associated with this dissertation. The first is to investigate

phase–to–neutral fault current magnitude occurring in generators with multiple zero–sequence

current sources. The second is to design, model, and tune a linear control system for oper-

ating a micro–grid in the event of a separation from the electric power system.

In the former case, detailed generator, AC8B excitation system, and four–wire electric

power system models are constructed. Where available, manufacturers data is used to

validate the generator and exciter models. A gain–delay with frequency droop control

is used to model an internal combustion engine and governor. …

Assessing The Remanufacturability Of Office Furiniture: A Multi-Criteria Decision Making Approach, Po-Hsun Chen

Theses and Dissertations

While the average life cycle of consumer goods is continuously decreasing, the amount of used product at their end-of-life (EOL) is accumulating fast at and at the same pace. Most EOL products end up in landfills, and many of which are not biodegradable. These two challenges have necessitated renewed global interest in product EOL management strategies by manufacturers, third party companies, consumers and governments. Remanufacturing is one of the EOL strategies which is highly environmental-friendly. Additionally, remanufacturing is seen as one of the highly profitable re-use business strategies. The selling price of remanufactured products is usually about 50—80% of a …

Modelling Of Dreissenid Mussel Impacts On Lake Michigan, Chunqi Shen

Theses and Dissertations

Invasive dreissenid mussel appear to have profoundly altered Great Lakes food webs and nutrient cycles during the past several decades. Recent declines of phytoplankton were supposed to be highly related with the increase of mussel population. These phytoplankton declines were further found to be coincident with declines in the abundance of planktivorous fish. In addition, the resurgence of Cladophora in Great lakes was estimated to be associated with the high density colonization of mussels. More light is available at lake bottom due to the mussels’ graze effect. The mussels further promote Cladophora growth by fertilizing it with nutrient-rich excrement. And …

South Padre Island Beach Management: Assessment Of Dune Restoration, Shelby Rose Bessette

Theses and Dissertations

Dune restoration is a common method of increasing coastal resilience. A dune restoration program was initiated by the City of South Padre Island, TX in 2010 consisting primarily of plantings of Sea Oats, Uniola paniculata, and Bitter Panicum, Panicum amarum and has continued approximately annually thereafter. These restoration efforts were evaluated in this study by comparing dune ecological structure and function among reference sites and restoration plots ranging in age from 2 to 5 years. Plant and animal communities were examined using a combination of quadrat sampling, funnel traps, pit-falls and sweep nets. Soil organic content and soil electric …

North American Butterfly Association Counts At Congaree National Park: A Case Study For Connecting Citizen Science To Management, Austin Clarridge

Theses and Dissertations

Citizen science is becoming an ever more popular way for scientists and resource managers to deal with needs for large temporal and spatial scale datasets. It provides a free or low cost means for collection of extensive amounts of data across time and space while acting as a public education and outreach tool, empowering communities to be involved in the management decisions being made in their back yard. Though large, well-known citizen science programs such as the Christmas Bird Counts are being used extensively for peer reviewed literature and management decisions, there are numerous smaller, local counts that have the …

A Comparison Of Framing In Two Environmental Conflicts, Alexander M. Iannone

Theses and Dissertations

Frames can be perspectives about people, objects, events, or settings that guide action based on past experiences and values. Conflicts are created by different stakeholders “holding conflicting frames.” Researchers in the past have used framing analysis to try and better understand environmental conflicts that tend to perpetuate for extended periods of time. A set of researchers have relied on specific framing categories and typologies as a framework for analysis. They have found that the strong presence or lack thereof certain frames can tell us a lot about conflict dynamics and shed light into the undercurrents driving the complexity of the …

Variation In Restaurant Sanitary Scores In New York City, Kyle Gregory

Theses and Dissertations

The purpose of this study was to determine whether restaurants that are homogenous in nature would exhibit substantially different hygiene scores based on the underlying consumer learning behaviors present in the neighborhoods in which the restaurants are located.

A New Paradigm Of Maximizing The Wind And Solar Penetration– A Economical Assessment, Yuming Chen

Theses and Dissertations

Wind and solar energies are the most potential and widely-used renewable energies. But in most cases these energies cannot be maximized because of transmission line capacity and their remote location. Therefore, this thesis proposes a new paradigm which using battery transportation and logistics instead of transmission line, to maximize wind and solar energies. The main focus of this work is to investigate the economical feasibilities of this new paradigm.

In the first part, different models and application are presented. The purpose is finding an appropriate model which can make full use of existing grid resources such as transmission line and …

Applying The Water Governance Framework On Rural Water Development Projects In Guatemala, Muhanad M. Alkharaz

Theses and Dissertations

According to the Organization for Economic Cooperation and Development (OECD), ‘Water crisis is mainly a governance crisis’, (OECD, 2013). Many water experts, as individuals, organizations and even governmental bodies have developed water governance frameworks to overcome water challenges on local, national, and international levels such as Integrated Water Resource Management. In rural areas, especially in developing countries, access to safe drinking water is a daily challenge due to a variety of political, economic, and social constraints. For in-stance, some developing countries have a strong centralized governance system. Due to lack of capacity and resources, central governments are incapable of providing …

The Effects Of Geomagnetic Disturbances On Electrical Power Systems, Benjamin J. Hynes

Theses and Dissertations

Solar storms that generate coronal mass ejections are a cause for concern due to the damage that they cause in high voltage power grids. Geomagnetically induced currents can be introduced onto the grid and cause many adverse effects. The vulnerability of the bulk electric power systems to such events has increased during the past few decades because the power system transmission lines have become more interconnected and have increased in length. Real and reactive power flows, voltage fluctuations, frequency shifts, undesired relay operations, higher order harmonic currents, undesired damage to assets and failure of assets are all possible outcomes from …

High Capacity Wells And Baseflow Decline In The Wolf River Basin, Northeastern Wisconsin, Susan A. Borchardt

Theses and Dissertations

The baseflow of the Wolf River (drainage area of 1 200 km2) in northeastern Wisconsin has declined by over 30% during the last thirty years, whereas climatic, land cover, and soil characteristics of the basin have remained unchanged. Because groundwater basins do not always coincide with surface water basins, estimating groundwater discharge to streams using variables only pertinent to the surface water basin can be ineffective. The purpose of this study is to explain the decline in the baseflow of the Wolf River by developing a multiple regression model. To take into account variables pertaining to the groundwater basin, withdrawal …

Effects Of Drift, Selection And Gene Flow On Immune Genes In Prairie Grouse, Zachary Bateson

Theses and Dissertations

Fragmentation of natural habitats is related to population decline in many species. The resulting small and isolated populations are expected to lose genetic variation at a rapid rate, which reduces the ability to adapt to environmental change. One concern is that small populations are more susceptible to emerging pathogens due to the loss of variation at immune genes. My dissertation examined the relative effects of gene flow, genetic drift and selection on immune genes in prairie-chickens (Tympanuchus cupido), a species that has undergone drastic population declines across their range. In the first chapter, I examined how artificial gene flow through …

Influence Of Permeate From Domestic Reverse Osmosis Filters On Lead Corrosion And Leaching From Plastic Pipes, Jyotsna Shrestha

Theses and Dissertations

Reverse Osmosis filters are gaining popularity nowadays, in domestic water supply system, to meet the increasing demand of pure and improved drinking water. There are various types of domestic RO filters with varying sizes, capacities, and treatment stages available. However, there exist a few concerns regarding the RO treatment system. One of the major issues in the quality and distribution of drinking water is the corrosive water that the RO system produces. Therefore, this research herein tends to focus on the corrosive effect of the permeate water on lead metal, as lead is considered a serious problematic drinking water contaminant. …

Design And Optimization Of Hybrid Energy Storage For Photovoltaic Power Fluctuation Smoothing Based On Frequency Analysis, Ruirui Yang

Theses and Dissertations

A proper design of energy storage system (ESS) can effectively smooth the photovoltaic (PV) output power fluctuation, lower the cost, and improve the power quality and stability.

According to the response characteristics of different energy storage equipment, an optimal hybrid EES sizing method is proposed based on frequency analysis. A hybrid ESS including lead-acid battery, lithium battery and electric double-layer capacitor (EDLC) is selected to smooth out PV power fluctuation and meet both power and energy requirement of the power grid. Fast Fourier Transform (FFT) method is applied for analyzing the spectrum of unwanted PV fluctuation. From the FFT analysis, …

A Simulation-Based Analysis Of Chemical And Radiological Hazard Zones Adapted To Physical Boundaries, Mickie J. Sundheim

Theses and Dissertations

In the United States, industrial and terrorist use of chemical, biological, radiological, and nuclear (CBRN) materials pose a risk to public safety. During the initial phase of typical CBRN incidents, emergency responders establish hazard zones based on standard distances from published guidelines and recommendations. This research investigates how standard hazard zones change in a real world environment that accounts for physical boundaries. Using a python simulation in ArcGIS®, new hazard zones were created by expanding standard hazard zones to follow nearby roads, railroads, and rivers. The new and standard zones were compared by calculating the population and area affected by …

Removal Of Perfluorooctanoic Acid From Water Using Primitive, Conventional And Novel Carbonaceous Sorbent Materials, Christopher K. Brown

Theses and Dissertations

Polyfluoroalkyl Substances (PFAS), like perfluorooctanoic acid, have been used for the last 50 years in a wide variety of industrial processes and consumer-based products, including polymer additives, lubricants, fire retardants and suppressants, pesticides, and surfactants (Buck et al. 2015). The Department of Defense (DoD) has used PFAS-based Aqueous Film Forming Foam (AFFF) at fire training facilities and aircraft hangars. AFFF has contaminated approximately 600 sites classified as fire training facilities with PFAS (Huang, 2013).

This study focused on testing the most likely carbonaceous adsorbent compounds to remediate PFAS-contaminated sites on Air Force installations. Batch tests were performed to determine the …