Physical Sciences and Mathematics Commons^™

A Point Model Of Aquifer Cleanup With A Distribution Of First-Order Rate Parameters, Jon E. Hodge

Theses and Dissertations

Many try modeling groundwater contaminant transport to predict it. Is this possible with rate-limited processes, and under what conditions? On occasion, cleanups go slower than predicted (tailing) and hazardous concentrations reappear after cleanup is thought complete (rebound). Rate-limited transport is blamed by many. When immobile water is present, diffusion from varied sizes and shapes of immobile regions can cause varied rate limitations (due to varied diffusion path lengths). Although known, most modelers represent these varied rate-limiting processes with a single 'representative' rate-parameter. This can yield poor predictions for long-term experiments, and the parameter is generally time and pump-rate dependent. This …