Physical Sciences and Mathematics Commons^™

Analysis Of C2 And C3 Hydrocarbons In Ambient Air. Section I ; Identification And Quantification Of Volatile Organics Emitted From A Landfill. Section Ii, Tsong-Sheng Chang

Theses

SECTION I

A method was developed to analyze Acetylene, Ethylene, Ethane, Propylene and Propane levels in the ambient air. Chlorinated compounds within the operation retention time, Methyl chloride, Methylene chloride and Vinyl chloride, were monitored also.

Four sampling sites are located at Carteret, Elizabeth, Newark and Montville in New Jersey. Samples were taken during the summer of 1988. Two sample duration periods utilizing 12 and 6 liter stainless steel canisters were set up to take 24 hour air samples and instantaneous air samples (5 minutes collection period).

The average levels of Acetylene, Ethylene, Ethane, Propylene and Propane at the four …

Thermal Decomposition Of Dichloromethane/1,1,1-Trichloroethane Mixture In An Atmosphere Of Hydrogen, Yang Soo Won

Theses

The thermal decomposition of a dichloromethane/1 , 1 , 1-trichloroethane mixture diluted in hydrogen was conducted in tubular flow reactors at 1 atmosphere total pressure. The thermal degradation of each species was analyzed systematically over temperature ranges from 475 - 810 °C, residence times of 0.05 - 2.0 seconds and three different surface to volume ratio flow reactors.

It was found that the conversions of each species in the mixture were a function of both temperature and residence time. Complete decay occurs at about 810 °C for dichloromethane and around 570 °C for 1,1,1-trichloroethane at 1 second residence time. The …

A Study Of Human Exposure To Benzo(A)Pyrene (Bap) Through Different Pathways. Part A ; Assessment Of Benzo(A)Pyrene (Bap) Exposure Through Urine Analysis With The Hydriodic Acid Reduction Reaction. Part B, Shao-Keng Liang

Theses

PART A: An investigation of total human exposure to an environmental pollutant is described. The study is being conducted in a community impacted by a foundry suspected to be a dominant local source of benzo(a)pyrene (BaP). The research aims to assess the relative contributions of indoor and outdoor sources and to measure BaP in media including indoor air, outdoor air, food and water.

PART B: A method for biological monitoring of exposure to benzo(a)pyrene, a representative polycyclic aromatic hydrocarbon (PAH), has been developed. The analytical procedure includes extraction of PAH and PAH metabolites from urine using commercial cartridges containing c …

A New Hazardous Waste Treatment Technology Utilizing Low Power Density Microwave Energy, Gabriele Else Windgasse

Theses

Two major applications of a new hazardous waste treatment technology using low power density microwave energy have been characterized: 1) Desorption of organic materials such as: trichloro-ethylene, para-xylene, naphthalene and gasoline hydrocarbons from substrates such as: sand and granulated activated carbon was achieved by microwave induced steam distillation and the application of a new phenomenon: arcing between GAC particles when they are exposed to microwave radiation. All contaminants could be removed to 100% (non-detectable with GC and GC-MS). 2) Decomposition of organic contaminants such as: trichloro-ethylene and trichloro-ethane in arcing/heating GAC beds. A new fluidized bed reactor ("RDW-reactor", after Ray, …

Adsorption And Kinetics Of Adsorption By Flyash In Solution, Murthy K. Jogimahanti

Theses

The phenomena of adsorption is extremely important in water/wastewater treatment process. A process which uses flyash as the sorbent for removing organic compounds from aqueous solutions has been investigated. Also, the rate at which this process occurs, i.e., the kinetics of adsorption, has been studied. Single solute systems were examined and the samples were analyzed using a Flame Ionization Detector Gas Chromatograph. The potentialities of adsorption on flyash as a method of renovation of water have not been realized fully, because little knowledge is available regarding the effective application of the method for this purpose.

Flyash has been known to …

Use Of Recirculation Reactor To Study Biodegradation Of Aroclor 1242, A Polychlorinated Biphenyl, Babu S. Sanji

Theses

The performance of immobilized microorganisms in the detoxification of hazardous waste was investigated using a recirculation flow reactor, run in a batch mode. A mixed microbial population from a wastewater treatment plant was immobilized in calcium alginate gel. The bio-oxidation ability of these microbes towards a model toxin Aroclor 1242 (R) (PCB 1242) was studied.

A non-ionic surfactant (Triton X-405 (R)) was used as a medium in the enhancement of the solubility of Aroclor 1242 in aqueous phase.

Dissolved oxygen concentration was monitored using a flow Clark-type dissolved oxygen probe. Oxygen consumption was compared to the biodegradation of Aroclor 1242. …

Pentachlorophenol And Oxygen Consumption Of Immobilized Mixed Bacterial Culture, Tesfamariam Stephanos Tsadwa

Theses

This study was undertaken to investigate the effects of Pentachlorophenol (PCP) concentration on oxygen consumption of immobilized microbial cells. The microbial population, from a municipal wastewater treatment plant, was immobilized in calcium alginate gel. The following studies have also been conducted in this project:

1. Comparison of the effect of PCP concentration on oxygen uptake between immobilized and free cells.
2. Comparison of the effects of PCP concentration on oxygen uptake between acclimated and an unacclimated bacterial beads.

Dissolved oxygen concentration was monitored using a flow Clark-type oxygen probe, in a micro-assay bioreactor. It was found that PCP concentrations higher than 2000ppm …

Preconcentration And Direct Flame Ionization Method For Measurement Of Non-Methane Organic Compounds In Ambient Air And Statistical Analysis Of Experimental Data, Lianyi Zuo

Theses

A fast and reliable method for the determination of non-methane organic compounds (NMOC) in ambient air has been developed. Samples are collected in SUMMA polished stainless steel canisters using a sampling system with a critical orifice as flowrate controller. Analysis of NMOC in the atmosphere via a canister is carried out by cryogenic preconcentration and a direct flame ionization detection method (PDFID). This system is sensitive and provides accurate measurement of ambient NMOC concentration even if the concentration is as low as 0.1 ppm carbon. The performance of the method was characterized using 19 pairs of canister samples and tested …

Microbial Phenol Degradation Utilizing A Complete-Mix Biological Reactor : The Effects Of Dissolved Oxygen Content, Keith Kollar

Theses

Experiments were conducted using phenol as a sole carbon source in a series of completely mixed biological reactors with solids recycle (CMBR). The reactor working volume was 4 liters, and solids were recycled from 3 liter clarifiers. Dissolved oxygen concentration (DO) was varied in order to determine the impact of this important variable on system operability.

Phenol was removed at better than 99 percent efficiency during most of the runs. Filamentous growth was not observed during any run. However, bulking did occur at higher DO levels, which was the result of microbial slime production.

Comparative Adsorption Studies On Clay Soils, Prasanna R. Mysore

Theses

An investigation has been made to study clay as sorbent in the treatment of the hazardous contaminants of potential sludge leachate emanating from industrial landfills.

Experimentally was studied six highly toxic and hazardous chemicals, which include: phenol, aniline, cyclohexanol, cyclohexanone, cresol and monochlorophenol. Vermiculate, Kaolinite, Attacote and Hectorite clays were studied as the sorbent material. Removal of organic pollutants were measured using a total organic carbon analyzer (TOC).

Results indicate that these clays can be used for some treatment of the above mentioned organic compounds. The study shows that removal of organic pollutants by clay depends on several factors, such …