Physical Sciences and Mathematics Commons^™

Cavity Ring-Down Spectroscopic Study Of Gas-Phase Photolysis Of Unsaturated Dicarbonyls And Aromatic Aldehydes, And Surface Photolysis Of Acetaldehyde, Bin Xiang

Legacy Theses & Dissertations (2009 - 2024)

Photochemical smog is a phenomenon associated with pollution in urban atmospheres arising from the photochemical oxidation of volatile organic compounds (VOCs) in the presence of nitrogen oxides. The oxidation process can lead to ozone and secondary air pollutants including particle formation which reduce visibility. The term "photochemical smog" is used to describe this pollutant mixture. The further degradation of secondary air pollutants could also have an impact on the atmospheric oxidation capacity. However, the atmospheric degradation mechanisms of the secondary pollutants are still not fully understood. In this dissertation, cavity ring-down spectroscopy combined with laser photolysis and Fourier transform infrared …