Physical Sciences and Mathematics Commons^™

Antibiotics And Antibiotic-Resistant Bacteria In Coastal Plain Streams, Jason Duff

Electronic Theses and Dissertations

Streams across the United States and globally are influenced by environmental contamination, including antibiotics, which enter streams due to widespread use and multiple pathways into the environment. Antibiotics are also likely to enter streams in mixture with other contaminants that alter the effects on aquatic organisms. Furthermore, antibiotic-resistant bacteria enter streams through similar pathways as antibiotics with implications for natural microbial communities. Therefore, understanding the presence and effects of antibiotic-contaminant mixtures and antibiotic-resistant bacteria in streams is important for resource management.

Chapter one describes an experiment that tested the hypothesis that the antibiotic tetracycline (TC) alone influences phytoplankton communities differently …

A Quantum Astrochemical Perspective On The C-C3h Radical With Application To The Interstellar Medium, Matthew Bassett

Electronic Theses and Dissertations

The interstellar medium (ISM) has been an area of focus for astrochemists and quantum chemists for many years, with particular interest in the presence of interstellar molecules and the resulting chemical processes. The c-C3H radical has been detected in the ISM near the dark molecular cloud TMC-1. With the application of ab initio computational methods using coupled-cluster theory at the singles, doubles, and perturbative triples [CCSD(T)] level, highly accurate quartic force fields (QFFs) are constructed to define the electronic wavefunction for the inter nuclear Hamiltonian. The QFF is used to predict the equilibrium geometry and produce vibrational frequencies, rotational constants, …