Physical Sciences and Mathematics Commons^™

Synthesis And Characterization Of Uranyl Dipyrrin Complexes For Environmental Applications, Duer Bolotaulo Bolotaulo

Open Access Theses & Dissertations

Persistent organic pollutants (POPs) are toxic chemicals that adversely affect the health of human populations as well as the environment. The need to develop remediation methods and materials as well as understand the mechanisms in which they can degrade POPs is necessary. Furthermore, heterogeneous phase metal based catalysts in place today do not fully understand the chemistry underlying degradation processes. The proposed research seeks to synthesize and characterize uranyl dipyrrin complexes to assess and understand the reactivity of uranyl dipyrrins with pollutants. Photophysical and electrochemical techniques will be used to characterize and determine the viability of utilizing the uranyl complexes …

Removal Of Endocrine Disrupting Compounds From Water And Wastewater Using Ecofriendly Materials, Alma Lili Loya Posada

Open Access Theses & Dissertations

Endocrine disrupting chemicals (EDCs) are compounds considered pollutants of emerging concern. The United States Environmental Protection Agency (USEPA) defines emerging pollutants as new chemicals without regulatory status and with an impact on the environment and human health that is poorly understood. Bisphenol A (BPA) has been considered an EDC and found to be ubiquitous in the environment because of its presence in a multitude of products including food and beverage packaging, flame retardants, adhesives, building materials, electronic components, and paper coatings Currently, BPA is not regulated by the federal government in the US and waste water treatment plants are not …

Bioavailability Of Metal/Metal Oxide Nanomaterials And Their Effects On The Physiology Of Plants, Nubia Zuverza Mena

Open Access Theses & Dissertations

Nanoparticles (NPs) contained in consumer products will undoubtedly reach the environment. Engineered nanomaterials (ENMs) may cause physiological and biochemical alterations in plants and, therefore, have noteworthy effects on their growth and proliferation. Edible plants are a means through which NPs can reach organisms of higher trophic levels that feed on them. Previous studies have demonstrated that there are strong interactions between NPs and terrestrial plants. This project intends to evaluate the impacts that various commercially available NPs have on plants. Copper (Cu) nanomaterials and conventional Cu compounds were compared in cilantro plants (Chapter 2). In addition, changes in radish sprouts …

Minimizing Environmental Impacts For Hub And Spoke Distribution Network Problems Through The Use Of Multi-Objective Evolutionary Algorithms, Ileana Delgado

Open Access Theses & Dissertations

While transportation is crucial to our economy and our personal lives, as a sector it is also a significant source of greenhouse gas (GHG) emissions. The AASHTO report states, "America's transportation system has served us well, but now faces the challenges of congestion, energy supply, environmental impacts, climate change, and threatens the economic, social, and environmental future of the nation". With respect to the environment, transportation is the most visible aspect of supply chains. Transportation emissions can be reduced by implementing approaches that contribute to GHG emissions reduction, for example, the use of low-carbon fuels, new and improved vehicle technologies, …

Computational Modeling Of A 60kw Oxy-Methane Direct Power Extraction Combustor, Omar Daniel Vidana

Open Access Theses & Dissertations

ANSYS Fluent was used to optimize components of a direct power extraction combustor. This includes the fuel injector, nozzle, and cooling units. Changes in the injector's inlet location impacted pressure and velocity distribution. An angle of 115 degrees with respect to the x-axis was found to increase distribution efficiency. Temperature and velocity data from the combustor and nozzle were calculated using NASA CEA and Fluent. Magnitudes of temperature and velocity for CEA and Fluent matched within 9% and 4%, respectively. For the cooling system it is expected that cavitation will not occur since the saturation temperature of water is not …

Modulation Of The Physiological And Biochemical Effects Of Copper Nanoparticles In Kidney Beans (Phaseouls Vulgaris) Treated By Kinetin, Suzanne Annette Apodaca

Open Access Theses & Dissertations

It is imperative to not only understand the impact of engineered nanomaterials (ENMs) in edible plants, but also the interactions they have with various additives used in agriculture. In this study, kidney bean plants were grown in potting soil treated with nano copper (nCu), bulk copper (bCu), and copper chloride (CuCl2) at concentrations of 0, 50, and 100 mg/kg for 55 and 90 days. At 15 days of growth, 0, 10, and 100 μm of kinetin (KN) were applied to plants. Plant tissue samples were harvested at 55 days and seeds were reaped at 90 days. Physiological and biochemical parameters …

Adaptive Switched Capacitor Voltage Boost For Thermoelectric Generation, Rene A. Brito

Open Access Theses & Dissertations

Thermoelectric generators (TEG) and other forms of energy harvesting often provide voltages that are not directly usable by traditional electronics as levels are too low from the TEG. While increasing the number of thermoelectric elements can ultimately increase the power output, there is a tradeoff between size and power. By implementing charge pumps, a proposed circuit technique is described that can boost the TEG output to levels that can be used for energy harvesting applications. Current voltage boost circuits for TEGs simply boost a voltage by a set amount. The proposed circuit consists of an analog chip, to provide several …

A Novel Approach For Evaluating The Impact Of Fixed Variables On Photovoltaic (Pv) Solar Installations Using Enhanced Meta Data Analysis Among Higher Education Institutions In The United States, Diane N. De Hoyos

Open Access Theses & Dissertations

The global demand for electric energy has continuously increased over the last few decades. Some mature, alternative generation methods are wind, power, photovoltaic panels, biogas and fuel cells. In order to find alternative sources of energy to aid in the reduction of our nation's dependency on non-renewable fuels, energy sources include the use of solar energy panels. The intent of these initiatives is to provide substantial energy savings and reduce dependence on the electrical grid and net metering savings during the peak energy-use hours.

The focus of this study explores and provides a clearer picture of the adoption of solar …

Impacts Of Environmental Changes To The Middle Rio Grande Landscape On Ysleta Del Sur Pueblo's Cultural And Cermonial Sustainability, Andrea L. Everett

Open Access Theses & Dissertations

Given future climate scenarios, this Thesis investigates how plausible climate changes will further impact the Native American community of Ysleta del Sur Pueblo's (Tiguas) cultural continuity and access to riparian ecosystem services along the Rio Grande River (specific to Tigua tradition; riparian vegetation used in ceremony, i.e. Gooding's and Coyote willow). The project aims to (1) describe and understand the relationship between regional climatic changes, anthropogenic changes, and major events in Tigua history, (2) identify rates and patterns of riparian vegetation changes, (3) evaluate impacts on cultural and provisioning ecosystem services relevant to Tigua culture, and relate these to climate …

Evaluating The Effects Of The Phytohormone Indole-3-Acetic Acid In The Response Of Green Pea (Pisum Sativum L.) To Nanoscale Cuo Exposure In Soil, Loren Ochoa

Open Access Theses & Dissertations

The response of plants to copper oxide nanoparticles (nCuO) in presence of the phytohormones such as IAA, is unknown. In this study, green pea (Pisum sativum) plants were cultivated to full maturity in soil amended with nCuO, CuO bulk (bCuO), and CuCl2 at 50 and 100 mg/kg and indole-3-acetic acid (IAA) at 10 and 100 µM. Several analytical techniques were used to evaluate the effects of treatments in the agronomical, physiological, and biochemical effects of treatments. Results showed that only CuCl2 reduced root length and number of leaves. Root copper (Cu) increased in plants exposed to nCuO without IAA; however, …

Application Of Secondary Analyses On Industrial Data Sets, Luis G. Perez

Open Access Theses & Dissertations

Secondary analysis on quantitative data sets is the in-depth analysis of relationships, trends, patterns or behaviors that are not obvious from a superficial examination of data but that can be very germane in the application of that data. The present work presents a framework for investigators to use in applying secondary analysis on big data that correlates to the research topic. The framework can facilitate the illumination of possible data behaviors or patterns that could be useful in arriving at an answer to a question. Behavior of monitored equipment (analyzers, meters, etc.) can easily be depicted and can be used …

Touch And Step Potential Analysis At 23.9kv To 4.16kv & 13.8kv To 4.16kv Distribution Substations With Pad-Mounted Transformers, Floating Grounds, And Other Exposed Ungrounded Metal Bodies Using Winigs, David Guillermo Guzman

Open Access Theses & Dissertations

An electrical substation is composed of various subsystems that allow for the effective and safe operation of the power grid. One of the subsystems integrating a conventional substation is defined as the ground grid system. This system allows for the effective operation of the power grid and all the electrical equipment connected to it by providing a ground potential reference, commonly known as the system ground. In addition, the ground grid system provides safety to the workers and the public transiting inside or living nearby a substation by reducing the step and touch potential (or voltage) levels present during a …

A Decision Making Approach For Selection Of Sustainable Pavements In Texas By Integrating Life Cycle Cost Analysis (Lcca), Life Cycle Assessment (Lca) Of Environmental And Social Impacts, Sundeep Inti

Open Access Theses & Dissertations

A sustainable pavement can be defined as the one that minimally impacts future economic opportunities, social conditions, human health, and the environment and still fulfills the engineering objectives. Although a pavement as outlined above is not yet entirely feasible, continual effort from every stakeholder with a vision of achieving sustainable development is essential for the future of society. In this study, one such effort was initiated by proposing a framework for selection of pavement design based on sustainable development.

The concept of sustainability is widely believed to be founded on three criteria: economic, environmental, and social standards. Since the purpose …

Environmental Dynamics: A Compendium Of Rhetorical Application, Annalisa Perez

Open Access Theses & Dissertations

Technology, albeit exceedingly useful, has exponentially exacerbated the communications dilemma between the technical and the non-technical. Additionally, based on a current new understanding of the term environmental, it can no longer be fully defined by terms such as air, water, waste, or purification. Rather, the meaning of environmental has been globally transformed in several ways. The term environmental is encompassing an expansion of understanding and is further defined with words such as essence, perception, rapport and multi-dimensional spaces. This work, Environmental Dynamics: A Compendium of Rhetorical Application (EDC), provides a framework where communication can be enhanced in areas where communication …

Fabrication And Testing Of Cfrp Composites With Embedded Piezoelectric Particles For Temperature Sensing And Energy Harvesting, Emilio Tarango Valles

Open Access Theses & Dissertations

As a part of this world's continuous evolution and technological advancements, smart materials and functional composites have become an attractive topic. In many cases, these new functional composites are replacing the traditional engineering material due to their customizable mechanical properties. This Thesis analyzes and demonstrates the signal response, sensing capabilities and structural properties from Carbon/Glass Fiber Reinforced Plastic Composites (CFRP) with embedded Lead Zirconate Titanate Particles (PZT). The added PZT particles function as actuators, giving the composites a functionality. The PZT quantity inside each composite was variated to study better and characterize the mechanical and electrical properties; the variations were …

Reliable And Secure Scada Framework For Residential Microgrid Communications, Goutham Krishna Chalamasetty

Open Access Theses & Dissertations

Cyber security is one of the major needs for electric power industry like many other industries and organizations. The advancements in technology provide numerous benefits to power industry as well as benefits cyber attackers to perform different cyber-attacks on the industry. Power system is a complex physical entity that deals with power generation, distribution, and transmission. In general, no individual or company or an organization can bear a one hour power cut, which shows the need for reliability in electric power industry.

In order to develop a reliable and secure Supervisory Control and Data Acquisition (SCADA) communication network, this Thesis …

Spatiotemporal Variability Of Plant Phenology In Drylands: A Case Study From The Northern Chihuahuan Desert, Naomi Robin Luna

Open Access Theses & Dissertations

With global change, which includes climate change, there is a sense of urgency to understand how shifts in climate will affect ecosystems. Although several studies have improved understanding of how and why some ecosystems respond, most studies have not explored simultaneous responses of different land cover types throughout a given region. Dryland ecosystems, such as the Chihuahuan Desert, appear to respond to climate variability and currently make up about 40% of global land surface area. It is expected that drylands will expand to cover 60% of land surface area on earth by mid-century making this ecosystem more critical to global …

An Effective And Optimal Quality Control Approach For Green Energy Manufacturing Using Design Of Experiments Framework And Evolutionary Algorithm, Juan Alejandro Saavedra

Open Access Theses & Dissertations

Quality Control (QC) and Quality Assurance (QA) strategies vary significantly across industries in the manufacturing sector depending on the product being built. Such strategies range from simple statistical analysis and process controls, decision-making process of reworking, repairing, or scraping defective product. This study proposes an optimal QC methodology in order to include rework stations during the manufacturing process by identifying the amount and location of these workstations. The factors that are considered to optimize these stations are cost, cycle time, reworkability and rework benefit. The goal is to minimize the cost and cycle time of the process, but increase the …

Predicting The Water Quality Of Shallow Arctic Ponds Using Remote Sensing, Gabriela Tarin

Open Access Theses & Dissertations

Barrow, Alaska is in a region dominated by Arctic tundra of which a substantial part is covered by lakes and ponds. Despite their dominance in the landscape, freshwater ecosystems in the Arctic have been insufficiently studied. It is clear that furthering understanding of how Arctic water bodies are responding to warming will depend on the analysis of changes in the concentration of organic and inorganic constituents in the water; however, scientists are faced with the task of sampling many remote sites in a relatively hostile environment. Thus, the exploration and incorporation of remote methods for monitoring changes in water quality. …

Study Of No2 Photolysis Rate Coefficients For The Paso Del Norte Region, Pema Wangchuk

Open Access Theses & Dissertations

The photolysis of nitrogen dioxide is one of the most influential chemical processes in the formation of photochemical air pollution. In this study, we compared simulated and measured nitrogen dioxide photolysis rate coefficients (J_(NO_2 )) for the Paso Del Norte (PdN) region. The Tropospheric Ultraviolet-Visible (TUV) radiation transfer model was used to calculate J_(NO_2 ) values. The measurements of hemi-spherically integrated, spectrally resolved solar photon flux between the wavelengths 400 and 700 nm were used to obtain the photolysis rate coefficients for ã??NOã??_2. Results are presented for a selected episode on July, 2015. The work investigated the use of measured …

Effects Of Citric Acid Coated And Uncoated Cerium Oxide Nanoparticles In Tomato (Solanum Lycopersicum) Plants, Ana Cecilia Barrios

Open Access Theses & Dissertations

This research was performed to examine the physiological and biochemical effects of bare (nCeO2) and citric acid coated (nCeO2+CA) cerium oxide nanoparticles in tomato (Solanum lycopersicum). Plants were germinated and grown to full maturity in soil amended with 0-500 mg/kg and periodically analyzed using ICP-OES/MS and other spectroscopic and biochemical techniques. Although Ce in tissues increased as the external nCeO2 increased, there were no visible signs of toxicity. In mature plants, nCeO2 induced developmental changes and altered nutritional quality (essential elements) in fruits. On the other hand, nCeO2+CA affected fruit carbohydrate composition (sugars and starch). This study gives insights on …

Sedimentologic And Stratigraphic Analysis Of Synrift Siliciclastic Fluvial And Lacustrine Strata In The Lower Cretaceous Upper Yucca Formation, Indio Mountains, West Texas, Matthew Robert Fox

Open Access Theses & Dissertations

Outcrops of the upper Yucca Formation in the Indio Mountains near Van Horn, Texas provide temporal, tectonic, and climatic similarities to Lower Cretaceous, synrift, greenhouse pre-salt lacustrine strata along in the subsurface of the South Atlantic margin. These "pre-salt" strata hold prolific petroleum reservoirs but despite extensive seismic studies performed for regional scale hydrocarbon exploration in these lacustrine reservoirs, sedimentologic and stratigraphic analyses have rarely been published. The Upper Yucca Formation in the Indio Mountains contain lacustrine reservoir analogs that intertongue with fluvial and deltaic sandstones. Near Squaw Canyon, fluvial-deltaic sandstones are reduced in abundance to lacustrine carbonates by nearly …