Physical Sciences and Mathematics Commons^™

Modeling Study On The Neopentyl+ O2 Reaction System And Experimental And Modeling Study On Mtbe Pyrolysis And Oxidation, Ru Wei

Dissertations

A modeling study on neopentyl radical + O₂ reaction system is conducted in this study. Thermodynamic parameters on all species and important transition states are calculated. A thermochemical kinetic analysis is performed.

Thermodynamic parameters are estimated using group additivity with HBI groups. Transition state energies are evaluated from experimental and theoretical data in the literature, combined with elementary reaction modeling to account for temperature effects. Transition state structures, vibration frequencies and entropies are determined from semi-empirical calculations, MOPAC PM3. Kinetics are analyzed with quantum RRK theory for k(E) coupled with modified strong collision analysis of Gilbert et al for …

Removal And Recovery Of Vocs And Oils From Surfactant-Flushed Recovered Water By Membrane Permeation, Ashish Nagnath Saraf

Theses

Surfactant-enhanced subsurface remediation appears to be capable of removing efficiently contaminants from the source area as well as the concentrated plume. Initial research was conducted on separate removal of trichloroethylene (TCE) and an oil. It was found that oil permeation and modified pervaporation are effective techniques of removing oil and TCE respectively from the simulated feed. It was found that the oil permeation technique can effectively remove 98-99% of oil from an oil-in-water emulsion. The subsurface-entrapped organic pollutants often have high boiling components along with the VOCs. A combined permeation technique is applied here to simultaneously remove TCE and n-dodecane …

An Investigation Of The Oxygraphic Response Of Stressed Bovine Blood, Cristin Mckenna

Dissertations

Oxygraphic profiles of stressed bovine blood in a temperature controlled 2 ml reactor vessel provide the basis for an investigation of blood's response to various conditions. This response is broken down into an initial response (within 3 seconds), the response over 1 hour and the response over 24 hours. Fast-assay runs which investigate the initial response display a dose-response relationship when chemically stressed by phenol. Phenol concentrations in the 1,000 ppm range indicate a decrease in dissolved oxygen (DO) and higher phenol concentrations of over 20,000 an increase in DO. In addition to phenol concentration, other factors investigated with respect …

Sampling And Analysis Of Trace Level Volatile Organic Compounds From Air Via Membrane Permeation, Naihong Zhu

Dissertations

The objective of this study is to develop air sampling techniques using membrane permeation. Two novel techniques for sampling and analysis of trace level VOCs from air via membrane permeation are presented:

1. selective concentration of VOCs into a canister using a membrane permeator;
2. on-line membrane extraction for direct introduction of VOCs from air emissions into a gas chromatograph.

In the membrane permeator-canister sampling system (MPCS), the air sample containing trace level VOCs as well as some interferences such as moisture are passed through the membrane module. Polydimethyl siloxane membrane used in this research is highly permeable to organic compounds, but …

Development Of Methods For Field Determination Of Chromium (Vi) In Water And Groundwater, David John Chesbro

Theses

In this study, methods for the determination of chromium (VI) in fresh water at low ppb levels for the use under field conditions were developed. The plan was to devise a simple and inexpensive on-site field method which would be useable by people who are not professional chemists. An investigation was carried out to develop a preconcentration and determination procedure for the analysis of chromium (VI) using anion-exchange membranes and/or resins. The chromium (VI) would be sorbed to the solid support and then treated with 1 ,5-diphenylcarabzide, a specific colorimetric reagent for chromium (VI), which forms a red complex upon …

Assessment Of Potential Operating Benefits Incurred By Implementing Iso 14001 : Five Case Studies From The New Jersey Chemical Industry, Stefanie Gitter

Theses

Environmental management is an important aspect of strategic planning and competitiveness for many businesses. Environmental management systems (EMS) are operating policies that are established to help a company measure progress towards goals set forth in a strategic environmental plan. A growing number of EMS models are being used by countries and industry groups, so the International Standards Organization (ISO) developed one model to prevent duplicate efforts which can result when companies try to meet the import requirements of different countries.

The ISO-EMS model is a series of standards, and ISO 14001 is the first to be published. Companies will be …

Oxidative Response Of Immobilized Bovine Blood To The Model Pollutant Phenol, Michael George Nickey

Theses

The primary purpose of this work is to determine if bovine blood can be studied in an immobilized cell bioreactor to determine if a phenol induced oxygen releasing optimum exists. This method of study has the potential to be used to determine what effects xenobiotics have on the oxidative activities of blood.

Three blood fractions containing approximately 21, 44, and 70% red blood cells (RBCs) were immobilized and placed in a recirculating bioreactor. These fractions were exposed injections of 0 ml, 3 ml, or 10 ml amounts of 2000 ppm phenol. The most active fraction was the 21% red cell …

Size-Frequency Distribution Of Palaemonetes Pugio In Two New Jersey Estuaries And Predator-Prey Interactions With Fundulus Heterocolitus, Celine Santiago

Theses

Predation by Fundulus heteroclitus is known to be an important factor regulating the abundance and size distribution of Palaemonetes pugio in the salt marsh habitat.

A preliminary study showed that P. pugio from a polluted estuary, Piles Creek, were relatively larger than those found in a more pristine estuary, Little Sheepshead Creek. Possible causes could be differences in competition, inherent environmental components, reproductive effort, or predation. To investigate the differences in size frequency, data on relative abundances of both species and size frequency distribution of P. pugio were collected for comparison from the two estuaries.

It was determined that P. …