Physical Sciences and Mathematics Commons^™

Bioremediation Of Petroleum Hydrocarbons In Coastal Sediments, Charbel Abou Khalil

Dissertations

The biodegradation of dispersed crude oil in the ocean is relatively rapid (a half-life of a few weeks). However, it is often much slower on shorelines, usually attributed to low moisture content, nutrient limitation, and higher oil concentrations in beaches than in dispersed plumes. Another factor may be the increased salinity of the upper intertidal and supratidal zones since these parts of the beach are potentially subject to prolonged evaporation and only intermittent inundation. Therefore, two laboratory experiments are conducted to investigate whether such an increase in porewater salinity results in additional inhibitory effects on oil biodegradation in seashores.

In …

Combustion Soot Nanoparticles: Mechanism Of Restructuring And Mechanical Properties, Ali Hasani

Dissertations

Soot, a product of incomplete combustion of fossil fuels, is a global warming agent. The effect of soot particles on climate depends on their morphology. Freshly released soot particles are fractal lacey aggregates, but they often appear collapsed in atmospheric samples collected away from emission sources. A body of work has concluded that the collapse is caused by liquid shells when they form by vapor condensation around soot aggregates. However, some recent studies argue that soot remains fractal even when engulfed by the shells, collapsing only when the shells evaporate. To reconcile this disagreement, the effects of the condensation and …

Assessing The Health Effects Of Climate Change, Social Vulnerability, And Environmental Justice In Camden County, New Jersey, Daniil Ivanov

Theses

Climate change negatively impacts health, while socially vulnerable and overburdened communities disproportionately experience climate change and negative health determinants. Camden County is used as a case study for analyzing environment, socioeconomics, and health. Environmental variables—PM2.5 and land cover of impervious surfaces, floodplains, and forests—were compared to the CDC Social Vulnerability Index (SVI) at the census tract level, finding significant correlations between land cover, air quality, and the SVI. The overburdened communities defined by the NJ Environmental Justice Law experienced a significantly higher incidence of emergency department visitation for respiratory, circulatory, and mental illnesses than non-overburdened communities. Health outcomes were compared …

Planning Methodology For Alternative Intersection Design And Selection, Liran Chen

Dissertations

The recent publication of the 6th Edition of the Highway Capacity Manual included a chapter on Ramp Terminals and Alternative Intersections that introduces various alternative intersection designs and assesses the performance of Median U-turn, Restricted crossing U-turn and Displaced left-turn intersections. Missing from the literature is an alternative intersection selection tool for identifying whether an alternative intersection would be successful under local conditions. With limited information of organized alternative intersection research, most planners must rely heavily on their personal judgement while selecting the most suitable intersection designs. As appealing as alternative intersections are, there is no comprehensive methodology for planners …

Atmospheric Mercury Chemistry: Detection, Kinetics, And Mechanism, Na Mao

Dissertations

The presence of mercury in the environment is of global concern due to its toxicity. The atmosphere is an important transient reservoir for mercury released by human activities and natural sources. The knowledge of atmospheric mercury chemistry is critical for understanding the global biogeochemical cycle. In the atmosphere, mercury primarily exists in three forms: gaseous elemental mercury (GEM), gaseous oxidized mercury (GOM), and particulate-bound mercury (PBM). Over the last decade, the existing knowledge of mercury cycle has dramatically changed: (1) There has been increasing evidence that current detection methods do not accurately quantify gaseous oxidized mercury and a technique which …

Reactive Iron Mineral Coatings In Redox Transition Zones Of A Site With Historical Contamination: Abiotic Attenuation, Xin Yin

Dissertations

Reactive iron mineral coatings are found throughout reduction-oxidation (redox) transition zones and play a significant role in contaminant transformation processes. In this study, an 18.3-meter core is collected, subsampled, and preserved under anoxic conditions to maintain its original redox state. Screening analyses are conducted at sampling increments of 5.08 cm in depth for the following: elemental concentrations with X-ray fluorescence (XRF), sediment pH, sediment oxidation-reduction potential (ORP), total volatile organic carbon (TVOC) in the sample headspace, and abundant bacteria (16S rRNA sequencing). Using the Fe and S gradients correlated with microbial data, five RTZs are delineated. To characterize iron mineral …

Safe Yield Comparisons For The 1960’S And 2000’S Drought In The Passaic River Basin, Stephanie R. Santos

Dissertations

The Passaic River Basin is a complex system of rivers, tributaries, reservoirs, and some of the largest water purveyors in the State of New Jersey. Located in the northeastern part of the State, it drains approximately 800 square miles of water that is used for distribution to the five major purveyors: North Jersey District Water Supply Commission, Passaic Valley Water Commission, Jersey City, Newark, and New Jersey American Water. These purveyors operate under a safe yield, which is defined by the New Jersey Department of Environmental Protection (NJDEP) as the amount of water that should be continuously available should the …

Optimizing Work Zone Schedules Considering Traffic Diversion With Artificial Bee Colony Algorithm, Celina Semaan

Dissertations

Highway maintenance activities often decrease roadway capacity and intrude traffic movements. The need to finish the project on time and under a specific budget while minimizing the traffic congestion and complying with the emission standards requires an appropriate work zone schedule optimization. The objective of this research is to improve the efficiency of work zone activities and minimize the total project cost including maintenance, user, and emission cost.

While previous studies investigated the work zone optimization problem, they did not consider the implementation of emission standards nor applied a green diversion strategy. This dissertation analyzes the optimization of work zone …

Development Of Novel Membranes For Nanocarbon Enhanced Separation With Application In Biofuels And Solvent Recover, Oindrila Gupta

Dissertations

Pharmaceutical industries historically have had one of the highest amounts of solvent waste generated per unit of drug manufactured. Energy requirements and carbon footprint of current solvent recycling processes tend to be quite high, and the incineration of the solvents for waste disposal produces toxic air emissions. Also, rapidly increasing demand for energy and strict regulation on engine pollutant emissions have necessitated the use of alcohol as carbon-neutral fuels. Thermal distillation is one of the most common methods for the separation of alcohol-water mixtures. However, its application is limited due to energy requirements and high operating costs, and heating to …

1,4-Dioxane Biodegradation In Propanotrophs: Molecular Foundations And Implications For Environmental Remediation, Li Fei

Dissertations

1,4-Dioxane (dioxane) has emerged with an escalating concern given its human carcinogenicity and widespread occurrence in groundwater. Bioremediation is promising as an effective and cost-efficient treatment alternative for in situ or ex situ cleanup of dioxane and co-existing pollutants in the field. Soluble di-iron monooxygenases (SDIMOs) are reputed for their essential roles in initiating the cleavage of dioxane and other pollutants. In this doctoral dissertation, molecular foundations for SDIMOs-mediated dioxane biodegradation are untangled to promote the development and implication of site-specific bioremediation and natural attenuation strategies. This dissertation focused on propanotrophic bacteria given their pivotal roles in dioxane metabolism and …

Compound Flooding In Coastal Areas Emanating From Inland And Offshore Events, Hamed Behzad Koochaksaraii

Dissertations

The vulnerability of urban populations to natural hazards and climate change is a major theme in many reports on coastal cities with flooding ranking highly among the climate change concerns. Flooding could occur as a result of runoff for inland rainfall that accumulates at the mouth of the estuary to the sea or it could occur due to a storm surge emanating from the ocean. The techniques for modeling the flooding from these events are very different, as they were developed in different scientific fields: hydrology and hydraulic engineering for inland rainfall versus coastal oceanography and coastal engineering for offshore …

Nanocarbon Modification Of Membranes For Enhanced Water Desalination And Water Treatment, Worawit Intrchom

Dissertations

Water scarcity is foreseen to be one of the great global issues in the coming decades. The challenges are not only in providing water supply to cope with the growing public demand, but recovering clean water to natural resources. Clean water supply, from brackish and seawater is attractive. Membrane distillation (MD) is an emerging thermal membrane-based process that has been used for desalination and other pollutant separations from water. MD can be operated at low temperature, so low-grade energy sources are a good alternative heat source for MD. High salt rejection and low membrane fouling also make MD interesting for …

Numerical And Analytical Methods To Predict Behavior Of Reinforced Ductile Concrete Composites, Mandeep Pokhrel

Dissertations

Structural components constructed with ductile concrete composites, such as high-performance fiber-reinforced cementitious composites (HPFRCC), are known to perform exceptionally well under extreme mechanical and environmental loading conditions compared to traditional concrete. HPFRCC flexural components exhibit enhanced performance in terms of displacement ductility, energy dissipation capacity, and damage tolerance capacity. However, recent research suggests that the flexural behavior of reinforced HPFRCCs in terms of crack progression, reinforcement plasticity, and failure mechanism is significantly different than conventional reinforced concrete. Specifically, the failure mode of flexural members is found to be predominantly through the fracture of longitudinal reinforcement rather than compression crushing of …

Reduction In Salt Deposition On Carbon Nano-Tube Immobilized Membrane During Desalination Via Membrane Distillation, Madihah Saud Humoud

Dissertations

As water scarcity increases globally under the stresses of increasing demand, aquifer depletion, and climate change, the market for efficient desalination technologies has grown rapidly to fill the void. One such developing technology, membrane distillation (MD), has found much interest in the scientific community. MD has also been powered by solar energy and waste heat resources because it can be operated at relatively low temperatures. Recent studies indicate that MD could potentially achieve the efficiencies of state-of-the-art mature thermal desalination technologies, although additional engineering and scientific challenges must first be overcome.

MD can be used to treat high salinity water …

Dental Professionals Occupational Noise Exposure And Its Auditory And Non-Auditory Effects, Alexis Frees

Theses

The purpose of this study was to assess noise exposure and its auditory and non-auditory effects on workers in five clinical departments in the School of Dental Medicine at Rutgers Biomedical Health Sciences Campus in Newark, New Jersey. The study included environmental noise level measurement, dental instrument sound level measurement, personal noise dosimetry and a questionnaire survey to assess non-auditory effects. Octave band analysis of environmental noise levels showed that they are slightly above the standard noise criteria for clinics, and measurements from six dental instruments confirm that they contribute higher sound pressure levels at the frequencies of 1000, 2000, …

Engineering Of Escherichia Coli 2-Oxoglutarate Dehydrogenase Complex With Mechanistic And Synthetic Goals, Joydeep Chakraborty

Dissertations

The Escherichia coli 2-oxoglutarate dehydrogenase complex (OGDHc) compromises multiple copies of three enzymes - 2-oxoglutarate dehydrogenase (E1o), dihydrolipoyl succinyltransferase (E2o), and dihydrolipoyl dehydrogenase (E3). OGDHc is found in the Krebs cycle and catalyzes the formation of the all-important succinyl-Coenzyme A (succinyl-CoA). OGDHc was engineered to understand the catalytic mechanism and optimized for chemical synthetic goals.

Succinyl-CoA formation takes place within the catalytic domain of E2o via a transesterification reaction. The succinyl group from the thiol ester of S8-succinyldihydrolipoyl-E2o is transferred to the thiol group of CoA. Mechanistic studies were designed to investigate enzymatic transthioesterification. His375 and Asp374 was shown to …

Fouling And Aging In Membrane Filtration : Hybrid Afm-Based Characterization, Modelling And Reactive Membrane Design, Wanyi Fu

Dissertations

Membrane filtration has been extensively used in water and wastewater treatment, desalination, dairy making, and biomass/water separation. However, membrane fouling, aging and insufficient removal efficiency for dissolved organic matters remain major challenges for wider industrial applications. In order to tackle these challenges, this doctoral dissertation investigates mechanisms of membrane fouling and development of antifouling membrane filtration technologies. Specifically, four major research areas are explored: (i) nanoscale physicochemical characterization of the chemically modified polymeric membranes; (ii) quantitative modelling between membrane properties and membrane fouling and defouling kinetics; (iii) development of quantitative structure-activity relationships for membranes that undergo thermal and chemical aging …

Methods To Improve The Remediation Of Polycyclic Aromatic Hydrocarbons (Pahs) In Aerobic And Anaerobic Environments, Brian Wartell

Dissertations

Oil spills occur regularly in terrestrial environments and crude oil can contain many compounds that are highly resistant to degradation. Among these compounds are high levels of polycyclic aromatic hydrocarbons (PAHs) which are not only toxic but can also be carcinogenic and/or mutagenic. The first chapter of this dissertation includes an extensive review chapter on the variables affecting the anaerobic degradation of hydrocarbons, with a particular focus on PAHs. Electron acceptors, electron donors, temperature, salinity, pH all play key roles in determining the possibility effective of effective degradation occurring. Thus, by addressing solutions, such as biostimulation, improving environmental variables for …

Kinetic Study Of Free Radical-Radical Reactions Of Combustion Importance At Elevated Pressures, Chao Yan

Dissertations

Combustion mechanisms consist of hundreds elementary reactions of free radicals and stable molecules. Radical-radical elementary reactions play important roles due to the high concentration in which free radicals are accumulated in combustion systems. Radical-radical reactions are typically multi-channel. Some of the channels might be of chain propagation or even chain branching nature, while other channels might be of chain termination nature. The relative importance of different channels is pressure dependent. Compared to radical-molecule reactions, radical-radical reactions are much less studied. This is due to the difficulties of well characterized quantitative production of radical species as well as due to the …

Public Perceptions Of The Functions Of Natural And Engineered Infrastructure In Coastal Hazards Mitigation: The Cases Of Two Communities In The Raritan Bayshore, New Jersey, Jaime D. Ewalt Gray

Dissertations

Emerging United States (U.S.) federal policies call for more comprehensive integration of both engineered and natural infrastructure in mitigating coastal hazards. For such policies to be effectively implemented, the mitigation functions of and relationship between natural infrastructure and engineered infrastructure must be understood and their integrated use accepted by affected actors, especially residents living in at-risk coastal communities. Little is known about public perceptions of the functions of engineered and natural infrastructure in coastal hazard mitigation and the interactions between these two types of infrastructure. This study analyzes perceptions based on semi-structured interviews of 14 residents in Laurence Harbor, Middlesex …

Novel Membrane Structures For Air And Water Purification, Smruti Ragunath

Dissertations

Membrane separations have undergone rapid developments in recent years. The key component in the process is the membrane itself which acts as a selective barrier regulating transport of components between the two sections. The main advantage of membrane separation process in comparison to other unit operations is its unique separation principle, ease of operation, lower energy requirement, and can be easily coupled with other downstream processes. Different membrane based applications include filtration, osmosis, dialysis, gas separation, pervaporation, membrane extraction and membrane distillation (MD). The membranes can be fabricated by a variety of processes such as phase inversion, sol-gel, track etching, …

Effects Of Human Development On Aeolian Sediment Transport Rates Within An Adjacent Undeveloped Backshore Enclave, Kayla L. Kaplan

Theses

Sandy backshore enclaves are created where shorefront buildings are lost during high magnitude storms. Subsequent foredune growth in these enclaves is critical to providing protection to landward development. Conditions for foredune growth and sediment flux within an enclave can be influenced by the presence of adjacent buildings. The objectives of this research are to assess the following questions: what is the nature of sediment flux on a beach within an enclave, what are the potential constraints to transport on a beach within an enclave and, are natural processes alone able to sustain a foredune in an enclave. A field investigation …

Thermochemistry And Kinetics: Hydrogen Atom Addition Reactions With Alkenes, Oxidation Of Cyclopentadienone, Trifluoroethene And Transport Properties, Suriyakit Yommee

Dissertations

Thermochemical and transport properties and reaction kinetic parameters are important to understand and to model atmospheric chemistry, combustion and other thermal systems. These processes are all important to the environment. Thermochemical properties kinetic parameters and models for several atmospheric and combustion related chemical systems are determined using computational chemistry coupled with fundamentals of thermodynamics and statistical mechanics. Transport properties of hydrocarbon and oxygenated hydrocarbons which are important to the calculation of fluid dynamics of gas phase flow reactions and mixing needed for evaluation in the combustion and thermal (flow) fluid dynamic modeling. Transport properties of radicals cannot be measured so …

The Experience Of Reducing Environmental Risks In An Environmental Justice Community, Gabriela Dory

Dissertations

Research on Environmental Justice (EJ) communities has focused on quantitative assessment of environmental hazards and general physical health problems. Little is known about how individuals living in EJ communities perceive their environmental risks and how they reduce environmental risks. The purpose of the study is to explore and describe the perceived environmental risks and the experience of reducing environmental risk among individuals living in an EJ community.

A qualitative and longitudinal design with a descriptive phenomenological method is used to recruit 23 participants living in a known EJ community in the urban area of New Jersey. A total of 43 …

The Winds Of Change: The Political Ecology Of Renewable Energy Transition In Vermont, Jill Mcnulty Clegg

Theses

This research presents a case study of renewable energy transition (RET) in Vermont, illustrated by a recently completed commercial wind project in the Lowell Mountains. Preliminary analysis maps out the current political landscape of Vermont’s RET – its stakeholders, political climate, and important policy advances. Subsequent analysis focuses on the relationship between RET and the unique aspects of Vermont’s institutions, culture, and communities. Important elements of this analysis include the ways that community groups form a vital link between citizens and the State, the unique opportunities and challenges presented by Vermont’s pastoral land perception and activist heritage, and the way …

Innovations In State-Level Solar Energy Policy : Motivating Community Investment In Resiliency, Sarah Katheryn Gentile

Theses

Community-level resilience in the face of climate change is critical for New Jersey. Through a review of current literature, evidence is provided that a majority of work being done with respect to climate-change planning is taking place at the local level. On the basis of case-study analyses, three community renewable energy projects are examined as well as two policy tools that are helping to facilitate development of local capacity to generate renewable energy. The best elements of these initiatives are extracted and form the basis of a policy discussion intended to encourage local level generation of renewable energy, thereby increasing …

Thermochemistry Reaction Paths And Oxidation Kinetics On Ketonyl And Aldehydic Nitrogen Oxides, Propene And Isooctane: A Theoretical Study, Suarwee Snitsiriwat

Dissertations

Thermochemical properties for several atmospheric and combustion related species are determined using computational chemical methods coupled with fundamentals of thermodynamics and statistical mechanics. Enthalpies of formation (ΔH_f°₂₉₈) are determined using isodesmic reaction analysis at the CBS-QB3 composite and the B3LYP density functional methods. Entropies (S°₂₉₈) and heat capacities (Cp°(T)) are determined using geometric parameters and vibration frequencies; internal rotor contributions are included in S and Cp(T) values in place of torsion frequencies. Kinetic parameters are calculated versus pressure and temperature for the chemical activated …

New Economy : Assessment Of The Institutionalization Of An Emerging Paradigm And Academic Field Through Inquiry Into Prominent Boundary Organizations, Jeanine Cava Rodgers

Theses

It is increasingly acknowledged that in order to reach global and regional sustai nabi l ity goals, economic growth and consumption levels in wealthy developed nations will need to stabilize or reverse. Organizations and projects of a wide variety have emerged and expanded to take on this challenge, and shape the so-called, "new economy". The purpose of this research is to gain a clearer picture of the impacts of efforts to develop a shared new-economy knowledge framework on the broader sustai nabi l ity conversation, and to assess the intellectual institutionalization of same. This thesis focuses in on the influence …

Transport Of Terrigenous Sediment And Horseshoe Crab Eggs In The Swash Zone Of An Estuarine Foreshore In Delaware Bay, New Jersey, Usa, Sherestha Saini

Dissertations

Identification of processes responsible for egg exhumation and transport in the swash zone is paramount to conservation of species that use the intertidal foreshore. One example where the understanding of these processes is critical to egg exhumation, transport and deposition is in Delaware Bay, USA. Beaches in Delaware Bay provide foraging grounds to many shorebird species that migrate thousands of miles from Central and South America to feed on nutrient rich horseshoe crab eggs during their peak spawning season. Eggs laid at depth by horseshoe crabs are exhumed and transported by bioturbation, wave and swash processes and made available to …

Dispersibility Of And Adsorption On Functionalized Carbon Nanotubes, Susana Addo Ntim

Dissertations

As the applications of carbon nanotubes (CNTs) proliferate, mass production and widespread use of these nanocarbons will continue to rise. While raw, unrefined, and hydrophobic carbon nanotubes tend to settle out of aqueous media/environments, water dispersible, functionalized CNTs (F-CNTs) will contaminate water resources and will also be highly bioavailable on exposure. Therefore, there is a need to develop an understanding of the fate of F-CNTs in aqueous media.

The colloidal behavior of aqueous dispersions of F-CNTs formed via carboxylation and polymer wrapping with polyvinyl pyrrolidone (PVP) is investigated. The presence of polymer on the nanotube surface provides steric stabilization, and …