Physical Sciences and Mathematics Commons^™

Enhanced Electrochemical Performance Of Li-Ion Battery Cathodes By Atomic Layer Deposition, Yan Gao

Doctoral Dissertations

”Li-ion battery now plays an irreplaceable role in supplying green and convenient energy. In this work, atomic layer deposition (ALD) was used to modify Li-ion battery cathode particles for performance enhancement.

An ultrathin and conductive CeO₂ ALD film was deposited on Li-rich layered cathode particles, of which the specific capacity and cyclic stability were significantly improved. On the same cathode particles, FeO_x ALD and post-annealing resulted in a stable and conductive surface spinel phase to improve the performance.

Synergetic TiN coating and Ti doping were performed on a LiFePO₄ (LFP) cathode and extended its cycle life. The …

Seismic Behavior Of Composite Bridge Columns, Mohanad M. Abdulazeez

Doctoral Dissertations

“This study investigates experimentally and numerically the seismic behavior of large-scale hollow-core fiber-reinforced polymer-concrete-steel (HC-FCS) innovative bridge columns as a sustainable approach to endure and rapidly recover from natural disasters such as earthquakes. The HC-FCS column consisted of a concrete shell sandwiched between an outer fiber-reinforced polymer (GFRP) tube and an inner steel tube to provided continuous confinement for the concrete shell along with the height of the column. The columns have a slender inner steel tube with diameter-to-thickness (D_s/t_s) ratios ranged between 85 to 254. Each steel tube was embedded into the footing, while the …

Minimizing The Detrimental Effects Of Hydro-Peaking On Riverbank Instability: The Lower Osage River Case, Wesam Sameer Mohammed-Ali

Doctoral Dissertations

"The fluctuation of water level downstream from dams due to hydropower flow releases negatively affects the riverbank stability. Therefore, this research aims to examine the feasibility of using an optimization technique to mitigate the riverbank instability resulting from the outflow variation of hydropower plants. The effects of the water releases from the Bagnell Dam were investigated by computing a series of safety factors for 78 cross sections along the 81-mile stretch of the lower Osage River in relation to outflow events by using the integrated BSTEM model incorporated into the HEC-RAS model. The 1-D sediment transport and unsteady flow in …

Development Of Tools For Water Management In The Hatra Watershed (Northwestern Iraq) Using Satellite Technologies, Majid S. Mohamod

Doctoral Dissertations

“All around the world the demand for water is increasing, especially in arid and semi-arid regions, including Iraq which subject to continuous desertification that is worsening, more importantly the Jezira region in northwestern Iraq. Thus, it’s crucial to have a better strategy for water management. One of these strategies is to promote groundwater recharge for restoring the aquifer depletion. The successful groundwater recharge is limited by some potential data such as the annual water budge and precipitation measurements. The atomospheric and hydrological observations are limited by sparse population which tends to be less in arid and semi-arid regions. Therefore, an …

Mass Spectrometry Analysis Of Contaminants Of Emerging Concern: Nanoparticles, Algal Toxins, And Cyanotoxins In Natural Waters And Their Potential Health Impacts, Ariel R. Donovan

Doctoral Dissertations

“The analysis of contaminants of emerging concern is critical to protecting environmental health. In the presented dissertation, two groups of contaminants of emerging concern were assessed using mass spectrometry methods: nanoparticles and algal and cyanotoxins.

Analysis of metal oxide nanoparticles in environmental matrices has been a challenging issue, as most traditional methods require complicated sample preparation methods or that can alter or destroy the nanoparticles in the system. Single particle inductively coupled plasma mass spectrometry (SP-ICP-MS) methods were used to detect metal oxide nanoparticles in surface waters and their removal through drinking water treatment simulations while retaining all information regarding …

Integrated Study On The Applicability Of Co₂-Eor In Unconventional Liquids Rich Reservoirs, Dheiaa Khafief Khashan Alfarge

Doctoral Dissertations

"Unconventional Liquids Rich Reservoirs (ULR) such as Bakken, Niobrara, and Eagle Ford have become the main target for oil and gas investors as conventional formations started to deplete and diminish in number. These unconventional plays have a huge oil reserve; however, the predicted primary oil recovery is still low as an average of 7.5 %. Unconventional Improved Oil Recovery (UIOR) techniques are still a new concept in the oil industry because there is no commercial project for any IOR technique so far. Injecting carbon dioxide (CO₂) might be the most potential strategy to improve oil recovery in such complex plays. …

Functionalized Nanoporous Carbon Scaffolds For Hydrogen Storage Applications, Christopher L. Carr

Doctoral Dissertations

"Recent efforts have demonstrated confinement in porous scaffolds at the nanoscale can alter the hydrogen sorption properties of metal hydrides, though not to an extent feasible for use in onboard hydrogen storage applications, proposing the need for a method allowing further modifications. The work presented here explores how the functionalization of nanoporous carbon scaffold surfaces with heteroatoms can modify the hydrogen sorption properties of confined metal hydrides in relation to non-functionalized scaffolds (FS). Investigations of nanoconfined LiBH₄ and NaAlH₄ indicate functionalizing the carbon scaffold surface with nitrogen can shift the activation energy of hydrogen desorption in excess of …

Environmental Hazard Identification, Assessment And Control For A Sustainable Maritime Transportation System, Lizzette Marie Pérez Lespier

Doctoral Dissertations

"A demand exists to contribute towards the widening awareness of the need for sustainable maritime development and for coordinated maritime policies worldwide. Maritime shipping is considered the most eco-efficient mean of transportation and yet, is responsible for negative environmental impacts.

This dissertation focuses on developing data-driven decision support tools to evaluate the sustainable performance of MTS by focusing on the elements of the MTS that place stress on the environment. The first research contribution is a System Dynamics simulation model that examines the MTS resiliency after an extreme event and determines the sequence needed to restore the ocean-going port to …

Modeling Dynamic Community Acceptance Of Mining Using Agent-Based Modeling, Mark Kofi Boateng

Doctoral Dissertations

"This research attempts to provide fundamental understanding into the relationship between perceived sustainability of mineral projects and community acceptance. The main objective is to apply agent-based modeling (ABM) and discrete choice modeling to understand changes in community acceptance over time due to changes in community demographics and perceptions. This objective focuses on: 1) formulating agent utility functions for ABM, based on discrete choice theory; 2) applying ABM to account for the effect of information diffusion on community acceptance; and 3) explaining the relationship between initial conditions, topology, and rate of interactions, on one hand, and community acceptance on the other …

Drinking Water Disinfection By-Products Detection, Formation And The Precursors Removal Study, Runmiao Xue

Doctoral Dissertations

"Haloacetic acids (HAAs) and trihalomethanes (THMs) are two groups of commonly found disinfection by-products (DBPs). Iodinated THMs and HAAs were observed after disinfection of water containing high level of iodide and are proved to be more toxic than their corresponding chlorinated and brominated species. In the presented dissertation, a novel rapid and sensitive high performance ion chromatography-tandem mass spectrometry (HPIC-MS/MS) method has been developed for simultaneous analysis of all these HAAs, bromate, bromide, iodide, and iodate, seventeen compounds in total, without any tedious sample preparation. Besides an efficient analytical method for the detection of DBPs, seeking for a green disinfectant …

Single Particle-Inductively Coupled Plasma-Mass Spectrometry Technology Development For Metallic Nanoparticle Characterization In Complex Matrices, Yongbo Dan

Doctoral Dissertations

"As the rapid growing of nanotechnology, the release of engineered nanoparticles (ENPs) into the environment is inevitable. After entering the real environment, ENPs tend to react with different components of the ecosystem (e.g. water, soil, air, plants) and make their characterization difficult. Analyzing ENPs in these complex matrices still remains as a grand challenge. ENPs characterization is normally the first step of risk assessment. Current analytical techniques have shown some limitations in revealing the unique characteristics of ENPs in complex matrices and reliable analytical techniques are in urgent need. Single particle inductively coupled plasma mass spectrometry (SP-ICP-MS) is an emerging …

Process Design, Dynamics, And Techno-Economic Analysis Of A Sustainable Coal, Wind, And Small Modular Nuclear Reactor Hybrid Energy System, Kyle Lee Buchheit

Doctoral Dissertations

"The availability of cheap electricity is one of the biggest factors for improving quality of life. With the debate on the effects of carbon dioxide emissions continuing, several countries have either implemented or are considering the reduction of emissions through various economic means. The inclusion of a monetary penalty on carbon emissions would increase the prices of electricity produced by carbon-based sources. The push for large-scale renewable sources of energy has met problems with regards to energy storage and availability. The proposed coal, wind, and nuclear hybrid energy system would combine a renewable energy source, wind, with traditional and stable …

Dynamic Behavior Of Operational Wind Turbines Considering Aerodynamic And Seismic Load Interaction, Mohammad-Amin Asareh

Doctoral Dissertations

"With the advancements in the wind energy production industry, the demand for a cost effective and safe design of wind turbine structures is growing rapidly. The wide deployment of wind turbines in locations with high seismic hazard has lead engineers to take into account a more comprehensive seismic design of such structures. In response to the need for a computational tool that can perform coupled simulations of wind and seismic loads, a seismic module has been developed for the publicly available National Renewable Energy Laboratory (NREL) code, FAST, at the first step of this research. This achievement allows engineers working …

Performance Analysis And Modelling Of Hybrid Photovoltaic-Thermal Solar Panels, Nicole C. Annis

Doctoral Dissertations

A photovoltaic-thermal (PVT) panel was constructed, tested, and modelled using both MATLAB and TRNSYS. During the experimental testing, which took place on the Missouri University of Science and Technology campus in Rolla, Missouri; two identical PVT panels were tested alongside two PV panels to gather an electrical baseline for comparison. Approximately 69 days’ worth of data were of data were collected during the summer of 2014. The PV electrical, PVT electrical, PVT thermal and PVT combined (electrical and thermal) efficiencies were 3.5-5.6%, 3.4-5.4%, 20.9-11.6%, and 24.3-17.0%, respectively.

A MATLAB program was developed using existing equations for one-dimensional, quasi-steady model of …

Degradable Nanocomposite Preformed Particle Gel For Chemical Enhanced Oil Recovery Applications, Paul Tongwa

Doctoral Dissertations

”This work presents two new materials that can be potentially used in conformance control to increase ultimate oil recovery from mature oilfields.

The first product is a degradable nanocomposite preformed particle gel for enhanced in-depth mobility control. Three different types of degradable nanocomposite preformed particle gels were synthesized. These three nanocomposite hydrogels were made using Laponite XLG, Calcium Montmorillonite, and Sodium Montmorillonite nanomaterials. It was observed that after degradation, Laponite XLG nanocomposite hydrogels had the highest post-degradation viscosity (4437 cp), followed by sodium nanocomposite hydrogels (129 cp), and lastly calcium nanocomposite hydrogels (75.5 cp). Thus, degradable Laponite XLG nanocomposite hydrogels …