Physical Sciences and Mathematics Commons^™

Quantifying Terrestrial Ecosystem Carbon Dynamics With Mechanistically-Based Biogeochemistry Models And In Situ And Remotely Sensed Data, Shaoqing Liu

Open Access Dissertations

Terrestrial ecosystem plays a critical role in the global carbon cycle and climate system. Therefore, it is important to accurately quantify the carbon dynamics of terrestrial ecosystem under future climatic change condition. This dissertation evaluates the regional carbon dynamics by using upscaling approach, mechanistically-based biogeochemistry models and in situ and remotely sensed data.

The upscaling studies based on FLUXNET network has provided us the spatial and temporal pattern of the carbon fluxes but it fails to consider the atmospheric CO2 effect given its important physiological role in carbon assimilation. In the second chapter, we consider the effect of atmospheric CO2 …

Policy Design Tool For Managing Indoor Residential Water Demand In Water-Scarce Regions, Mujahed M. Thneibat

Open Access Dissertations

In view of population growth; climate change; and economic evolution, water resources in numerous parts of the world have reached their natural capacities. Consequently, the ability of many countries to grow; meet the basic needs of inhabitants; and protect the environment will be endangered like never before unless water resources are smartly handled and managed. ^ In the past few decades, many developed and developing countries have suffered from water scarcity, and more are certain to follow. The water security dilemma is much more challenging in developing countries. Water utilities have had to follow regulatory plans to manage demand on …

Lower Food Web Dynamics In Lakes Michigan And Huron: Spatial And Temporal Responses To Recent Oligotrophication, Margaret Hutton Stadig

Open Access Theses

Nutrient abatement programs, originally enacted to counter eutrophication have successfully suppressed nutrient loads and relative primary production in marine and freshwater systems. Recently, the additive impacts of invasive filter feeders have further reduced offshore primary production in several aquatic systems throughout the world. It has been hypothesized that the biological activity of these invasive species may sequester nutrients within the nearshore benthic environment, creating steep gradients in primary production between nearshore and offshore habitats. In the Laurentian Great Lakes, past studies of oligotrophication have primarily focused on food web responses in offshore habitats. Organisms at higher trophic levels have been …

Gonadal Intersex In Teleosts: Mechanisms, Molecular Biomarkers And Diagnostic Assays, Ahmed M.E. Abdel-Moneim Mohamed

Open Access Dissertations

Natural and synthetic estrogenic and androgenic compounds are continuously released into aquatic ecosystems. Exposure of teleost fishes to these contaminants can negatively impact sex differentiation and reproductive output. Specifically, development of gonadal intersex in gonochoristic (fixed sex) fish species has been studied extensively in relation to exposure to this class of compounds. The main objectives of this dissertation were to: 1) conduct field and laboratory studies to investigate the molecular signaling pathways behind the development of gonadal intersex; and 2) establish molecular biomarkers and assays for testing the ability of environmental pollutants to develop this condition using a battery of …

Unraveling The Fingerprints Of Nox Using Stable Isotopes: Implications For Nox Source Partitioning And Oxidation Chemistry, Wendell William Walters

Open Access Dissertations

The nitrogen (N) and oxygen (O) stable isotope composition (δ15N & δ18O) of nitrogen oxides (NOx )may be a useful tool for constraining NOx emission sources as well as for understanding the atmospheric oxidation pathways responsible for its removal if various NOx sources and sink processes exhibit characteristic isotopic compositions (“fingerprints”). However, this requires (1) an accurate and complete inventory of δ15N(NOx) values from major emission sources, (2) an assessment of the kinetic and equilibrium isotope effects that can impact δ15N and δ18O values of NOx, (3) and test these assumptions by conducting accurate in situ δ15N and δ18O measurements …

Manufacturer Perspectives On Content Transparency And Material Health In The Us Building Products Industry, Alexandra A. Muller

Open Access Theses

Flawed U.S. federal regulation of chemicals has resulted in a materials market that undervalues human and environmental health in favor of the more traditional attributes of price, performance and aesthetics. In the building products industry, global, dynamic supply chains and proprietary information concerns further complicate the task of assessing the material health of products.

Voluntary material health programs in the green building industry are intended to incentivize the manufacture and selection of safer products by getting companies to gather and assess ingredient, hazard and risk information from their supply chain. Building product manufacturers considered early adopters of the main material …

Nutrient Runoff And Leachate After Land-Application Of Digestate In A Laboratory Study Using Rainfall Simulations, Min Xiao

Open Access Theses

There has been an increasing number of anaerobic digesters on livestock farms in the United States during the past two decades. Anaerobic digestion of manure allows production of renewable energy and generation of stabilized and nutrient-rich digestate that can be used as organic fertilizer. However, the majority of the existed studies using liquid digestate as fertilizer only focused on the effectiveness for crop yield, nutrient content and microorganism in soil. There is insufficient understanding in the environmental impact of digestate land-application. This laboratory study used six treatments including four different liquid digestate treatments, a chemical fertilizer treatment, and an unfertilized …

Role Of River Bathymetry In Hydraulic Modeling Of River Channels, Sayan Dey

Open Access Theses

Accurate geometric representation of the river channel is required for accurate hydraulic modeling of rivers. These are generally obtained through remote sensing techniques such as Light Detection and Ranging (LIDAR). However, these techniques lack the ability to model the submerged channel bed effectively and need to be complemented with surveyed bathymetric data for complete representation of the channel bathymetry, which can be time and cost prohibitive. An alternative to address this issue is to develop conceptual models that can estimate bathymetry.

This study aims to evaluate the potential of a conceptual model, the River Channel Morphology Model (RCMM) which estimates …

Enabling A Sustainable Economy Through Energy Systems Modeling: Solar-Centric, Efficient, Integrated And Continuous Process Synthesis And Optimization, Emre Gencer

Open Access Dissertations

The expected increase in food, energy and water demand due to increase in population and change in consumption habits in conjunction with diminishing fossil fuel reserves and increasing greenhouse gas emissions urge the development and implementation of alternative energy conversion techniques using renewable energy for a sustainable economy. Among renewable energy sources, solar energy is prominent due to its abundance. A sustainable economy can be created by producing building blocks foundational to meeting all basic human needs of daily existence. However, intermittencies and limitations on land area dedicated to harness solar energy are the major obstacles on widespread implementation of …

Enhancing Silymarin Fractionation Via Molecular Modeling Using The Conductor-Like Screening Model For Real Solvents, Emma C. Brace

Open Access Theses

The market for bio-based products from plant sources is on the rise. There is a global challenge to implement environmentally clean practices for the production of fuels and pharmaceuticals from sustainable resources. A significant hurdle for discovery of comparable plant-derived products is the extensive volume of trial-and-error experimentation required. To alleviate the experimental burden, a quantum mechanics based molecular modeling approach known as the COnductor-like Screening Model for Real Solvents (COSMO-RS) was used to predict the best biphasic solvent system to purify silymarins from an aqueous mixture. Silymarins are a class of flavonolignans present in milk thistle ( Silybum marianum …

Investigation Of Climate Variability And Climate Change Impacts On Corn Yield In The Eastern Corn Belt, Usa, Ruoyu Wang

Open Access Dissertations

The increasing demand for both food and biofuels requires more corn production at global scale. However, current corn yield is not able to meet bio-ethanol demand without jeopardizing food security or intensifying and expanding corn cultivation. An alternative solution is to utilize cellulose and hemi-cellulose from perennial grasses to fulfill the increasing demand for biofuel energy. A watershed level scenario analysis is often applied to figure out a sustainable way to strike the balance between food and fuel demands, and maintain environment integrity. However, a solid modeling application requires a clear understanding of crop responses under various climate stresses. This …

Simulation Of Conservation Practice Effects On Water Quality Under Current And Future Climate Scenarios, Carlington W. Wallace

Open Access Dissertations

Analysis of the effects of implementing different conservation practices, as well as increased levels of conservation practices under existing and projected future climate, will determine if current conservation practice recommendations will be sufficient to maintain soil and water resources. The Soil and Water Assessment Tool (SWAT) was used to study four watersheds of different sizes (CCW = 680 km2, F34 = 183 km2, AXL = 42 km 2 and ALG = 20 km2) located in Northeastern Indiana. The overarching goal of this study was to evaluate the effect of various agricultural practices on runoff and agricultural chemical losses under current …

Behavioral Responses And Policy Evaluation: Revisiting Water And Fuel Policies, Shanxia Sun

Open Access Dissertations

In my dissertation, I examine how policies regulating agricultural production and clean technology impact the environment. I focus on policies affecting water depletion, water pollution, and fuel consumption. I assess their cost-effectiveness by modeling and quantifying the behavioral responses of farmers and households.

My first essay focuses on decreasing groundwater depletion through increasing irrigation efficiency in Mexico. I quantify the impacts of different sources of inefficiency on groundwater extraction, and I evaluate the effectiveness of alternative policies that aim to reduce the over-extraction of groundwater. I find that mechanisms of electricity cost-sharing implemented in many wells have a sizable impact …

Economic And Environmental Impacts Of A Hypothetical Global Gmo Ban, Harrison H. Mahaffey

Open Access Theses

The objective of this research is to assess the global economic and greenhouse gas emission impacts of GMO crops. This is done by modeling two counterfactual scenarios and evaluating them apart and in combination. The first scenario models the impact of a global GMO ban. The second scenario models the impact of increased GMO penetration. The focus is on the price and welfare impacts, and land use change greenhouse gas (GHG) emissions associated with GMO technologies. Much of the prior work on the economic impacts of GMO technology has relied on a combination of partial equilibrium analysis and econometric techniques. …

Investigating U.S. Resident Perceptions Of Corporate Social Responsibility In Food And Agriculture, Carissa Jae Morgan

Open Access Theses

Corporations are prioritizing corporate social responsibility (CSR) activities by investing in and actively promoting their social practices. In the U.S. of the modern food supply chain creates a unique challenge for corporations to address concerns about social issues of consumers and non-consumers alike. This study is motivated by the need to better understand individuals’ perceptions of CSR as it pertains to the food supply chain. In April 2015 an online survey collected information from 1,201 U.S. residents with the objective of investigating individuals’ perceptions of relative importance of eight prominent CSR areas relevant to food and agriculture. Demographic, household consumption, …

Quantifying The Global N2o Emissions From Natural Ecosystems Using A Mechanistically-Based Biogeochemistry Model, Tong Yu

Open Access Theses

Nitrous oxide (N2O) has a great influence on atmospheric chemistry and climate. It is not only a major greenhouse gas, but also one of the largest ozone-depleting substances emitted from the biosphere. Process-based biogeochemistry modeling constrained by site-level observations is a feasible approach to quantifying its emissions at large temporal and spatial scales. This study developed a process-based biogeochemistry model of N2O emissions based on an extant biogeochemistry model, the Terrestrial Ecosystem Model (TEM). The model development includes: 1) incorporating the effects of physical conditions on both nitrification and denitrification and 2) implementing principles of the stoichiometry of carbon and …

An Evaluation Of Noise Reduction Strategies At Large Commercial Airports In The United States: A Policy Analysis And Framework Classification, Tyler Spence

Open Access Dissertations

Noise pollution from aircraft, specifically in the vicinity of airports as aircraft takeoff and land, is a problem that has been shown to have negative impacts on the welfare of humans, animals, and the surrounding environment. The problem may only become worse as air travel increases for cargo and passenger operations, populations increase, and the overall number of aircraft increase. Currently, guidance has been issued from the International Civil Aviation Organization on how to combat the issue of noise pollution through policy, both at that national regulatory level, and at the local airport level. This study evaluated the local airport …

Hydrologic And Water Quality Impacts From Perennial Crop Production On Marginal Lands, Qingyu Feng

Open Access Dissertations

Marginal lands are proposed as a viable option for producing biofeedstocks as these lands are not heavily engaged in agricultural production or may not be suitable for intensive row-crop food/feed production. However, meeting biofeedstock production goals will require large amount of marginal lands and the unintended consequences of producing biofeedstocks on marginal lands are not fully clear. The overall goal of this study was to evaluate the productivity of biofeedstocks on marginal lands and the potential impacts on hydrologic and water quality processes from the land use conversion.

This study was conducted in the Upper Mississippi River Basin (UMRB). First, …

Electric Power And The Global Economy: Advances In Database Construction And Sector Representation, Jeffrey C. Peters

Open Access Dissertations

The electricity sector plays a crucial role in the global economy. The sector is a major consumer of fossil fuel resources, producer of greenhouse gas emissions, and an important indicator and correlate of economic development. As such, the sector is a primary target for policy-makers seeking to address these issues. The sector is also experiencing rapid technological change in generation (e.g. renewables), primary inputs (e.g. horizontal drilling and hydraulic fracturing), and end-use efficiency. This dissertation seeks to further our understanding of the role of the electricity sector as part of the dynamic global energy-economy, which requires significant research advances in …