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Full-Text Articles in Physical Sciences and Mathematics

Modeling Napl Dissolution From Pendular Rings In Idealized Porous Media, Junqi Huang, John A. Christ, Mark N. Goltz, Avery H. Demond Oct 2015

Modeling Napl Dissolution From Pendular Rings In Idealized Porous Media, Junqi Huang, John A. Christ, Mark N. Goltz, Avery H. Demond

Faculty Publications

The dissolution rate of nonaqueous phase liquid (NAPL) often governs the remediation time frame at subsurface hazardous waste sites. Most formulations for estimating this rate are empirical and assume that the NAPL is the nonwetting fluid. However, field evidence suggests that some waste sites might be organic wet. Thus, formulations that assume the NAPL is nonwetting may be inappropriate for estimating the rates of NAPL dissolution. An exact solution to the Young‐Laplace equation, assuming NAPL resides as pendular rings around the contact points of porous media idealized as spherical particles in a hexagonal close packing arrangement, is presented in this …


Semianalytical Solutions For Transport In Aquifer And Fractured Clay Matrix System, Junqi Huang, Mark N. Goltz Oct 2015

Semianalytical Solutions For Transport In Aquifer And Fractured Clay Matrix System, Junqi Huang, Mark N. Goltz

Faculty Publications

A three‐dimensional mathematical model that describes transport of contaminant in a horizontal aquifer with simultaneous diffusion into a fractured clay formation is proposed. A group of semianalytical solutions is derived based on specific initial and boundary conditions as well as various source functions. The analytical model solutions are evaluated by numerical Laplace inverse transformation and analytical Fourier inverse transformation. The model solutions can be used to study the fate and transport in a three‐dimensional spatial domain in which a nonaqueous phase liquid exists as a pool atop a fractured low‐permeability clay layer. The nonaqueous phase liquid gradually dissolves into the …