Physical Sciences and Mathematics Commons^™

Plastic Debris In The Laurentian Great Lakes System, North America: Analysis Of Types, Abundances, And Sources, Ian A. Arturo

Electronic Thesis and Dissertation Repository

Understanding plastic pollution in the Laurentian Great Lakes system requires investigation of all plastic debris sizes and categories. Visible polymeric debris (VPD) mainly characterize shorelines, and microplastics (MPs;mm) are found in benthic and beach sediment. Field sampling of VPD from all five Great Lakes, visual and chemical identification of VPD types, and implementation of a matrix scoring technique (MST) indicate that plastic industries, urban areas, and shoreline recreation are major sources of VPD. Sampling for MPs in the St. Clair system, followed by preliminary density separation, and microscopy, suggest that wastewater treatment plants are a major source. This work is …

Spatial And Temporal Variation Of Nutrients In The Great Lakes-St. Lawrence Basin: Implications For Primary Production In Stream Ecosystems, Nolan Pearce

Electronic Thesis and Dissertation Repository

Growing human populations and associated land use activities has increased the amount of nutrients delivered to surface waters. Eutrophication from the over-enrichment of nitrogen and phosphorus has degraded ecosystem conditions in streams, lakes, and coastal areas worldwide. Thus, the management of anthropogenic nutrient loading is a global concern. This thesis employed a combination of field and experimental research to provide watershed managers with information on the spatial and temporal patterns in stream nutrient enrichment, and the associated ecological effects of anthropogenic nutrient loading in the Great Lakes-St. Lawrence basin. Four studies were completed to address this research goal. First, I …

Airborne Observations Of Thermal Anisotropy From Urban Residential Neighbourhoods In Salt Lake City, Utah, Samantha J. Claessens

Electronic Thesis and Dissertation Repository

Urban surface temperatures are important variables in urban climatological processes. This thesis examines the directional variability of remotely sensed urban surface temperatures (thermal anisotropy or Λ) for three vegetated residential neighbourhoods in Salt Lake City, Utah, USA. Airborne thermal remote sensing using a thermal imager sampled the directional brightness temperature (DBT) at three times within a day for each site. Results indicate that temporal variability over a 20 – 30-minute flight was not negligible. Average DBT were then extracted from atmospherically corrected images and plotted on polar plots. For low density residential neighbourhoods Λ is increased with increasing tree-canopy coverage …

Quantification Of Septic System Contribution To Nutrient Loads In Surface Waters, Archana Tamang

Electronic Thesis and Dissertation Repository

Freshwater systems worldwide are threatened by excessive nutrient (nitrogen and phosphorus) loading. This study evaluated the contribution of septic systems to stream nutrient loads in nine subwatersheds. Stream sampling was conducted during low and high discharge conditions, with samples analyzed for total phosphorus (TP), soluble reactive phosphorus (SRP), nitrate (NO₃-N), and acesulfame (ACE; wastewater tracer). Higher septic effluent reached the subwatershed outlets during high discharge conditions. Subwatersheds with newer households had a lower percentage of septic effluent reaching the stream compared with subwatersheds with older households. Seasonal and event-based ACE concentration-discharge relationships revealed that the hydrological pathways delivering …

Optimal Algorithms For Deriving Estimates Of Phytoplankton Biomass In Lakes From Landsat Satellite Imagery, Michael A. Dallosch

Electronic Thesis and Dissertation Repository

The frequency, intensity, and geographical distribution of harmful phytoplankton blooms are on the rise globally. There is a scientific need for estimates of historical and current phytoplankton data. This research develops mathematical algorithms for accurate assessment of surface chlorophyll-a (chl-a), a proxy for phytoplankton biomass, within freshwater lakes. Landsat satellite images (4-5 TM, 7 ETM and 8 OLI) were used to create predictive models (from 1984 to 2017) for seven ecoregions (ranging from the tropics to arctic). Correlation tests for 82 algorithms were conducted to establish the best fit models (linear, exponential, logarithmic, power) for chl-a …

Development Of Exploratory Data Analysis Methods For Chemical, Spatial And Temporal Analysis Of Surface Water Quality Data: The Ontario Provincial Water Quality Monitoring Network, Shuyang Wang

Electronic Thesis and Dissertation Repository

Surface water quality (SWQ) databases have been widely compiled to provide information characterizing environmental conditions. But SWQ databases appear to be under-utilized, given the large investment in their creation. One reason is that database spatial, temporal, and compositional dimension vary through time, reflecting changing priorities through time and contrasts between different agencies, making coherent analysis challenging. This thesis explores the Ontario Provincial Water Quality Monitoring Network (PWQMN) to derive higher order hydrochemical properties, to render SWQ data in “network space” permitting catchment-wide visualization, and in undertaking temporal trend analysis.

Rivers play a critical role in the terrestrial carbon cycle, but …

The Effect Of Sub-Facet Scale Geometry On Vertical Facet Temperatures In Urban Street Canyons, Rainer V.J. Hilland

Electronic Thesis and Dissertation Repository

Surface temperature plays a key role in many micro-scale urban processes. Walls comprise a significant percentage of the urban surface, yet are under-represented by many methods of thermal remote sensing and not considered in detail by micro-scale surface temperature mod- els. This thesis presents a novel method of mobile thermal observation performed in urban street canyons in London, ON that uses a thermal imager as well as a visual spectrum camera to provide dense spatial and temporal resolution of micro-scale wall temperature distributions. Images are manually classified by a series of nominal variables and the resulting data set discusses the …

Metabolomics For Biomonitoring: Evaluation, Recommendations, And Test Of Efficacy, Sarah M. Mckenzie

Electronic Thesis and Dissertation Repository

Effective biomonitoring of aquatic environments is an integral component of ecosystem protection. The metabolome is an emerging indicator that may have the potential to serve as an ideal bioindicator due to its intrinsic capacity to detect physiological changes in organisms that could foreshadow ecosystem change. My thesis consisted of two complementary objectives. First, the metabolome was evaluated against several established criteria for an ideal bioindicator and found to have significant potential. Recommendations were also made regarding implementation of the metabolome into existing biomonitoring programs. Second, the metabolome of Hexagenia spp. was evaluated as a potential indicator for environmental effects of …

Microclimate Variability Of Select Toronto Neighbourhoods Under Hot Summertime Conditions, Timothy Wiechers

Electronic Thesis and Dissertation Repository

Micrometeorological variability within cities has important implications for urban air and water quality, building energy consumption, and human health and thermal comfort. However, the monitoring of microscale climate is not routinely conducted. In most instances, primary meteorological observations are made under reproducible standard conditions (typically at an airport); but these open field observations tend to be unrepresentative of the intra-urban meteorological conditions.

This thesis used an alternative approach of conducting mobile traverse measurements using vehicle-mounted sensors to characterize the microclimates of Toronto, ON under hot, summertime weather conditions. Sampling occurred along two routes and incorporated sampling 8 intra-urban neighbourhoods with …

Modeling Of Suspended Sediment Concentration Using Conventional And Machine Learning Approaches, In Thames River, Canada, Issam Mohamed

Electronic Thesis and Dissertation Repository

Water resource management, planning, hydraulic design, environmental conservation, reservoir management and operation all require reliable information and data about Suspended Sediment Concentration (SSC). To predict such data, direct sampling and Sediment Rating Curves (SRC) are commonly utilized. Since direct sampling can be risky during extreme weather events and SRC cannot provide satisfactorily dependable results, engineers are trying to propose new precise fore-casting approaches. Various soft computing techniques have been applied to model different hydrological and environmental problems and have showed promising results in this regard. Although many studies have been performed to simulate the phenomena of SSC at numerous rivers …

Identification Of Thresholds In Benthic Macroinvertebrate Communities Associated With Agricultural Land Cover, Jeremy Peter Grimstead

Electronic Thesis and Dissertation Repository

Agricultural land use affects benthic macroinvertebrate (BMI) community structure but riparian forest may mitigate its impact to within a specific threshold. BMI communities were sampled in small streams within the Grand River, Thames River, and Long Point watersheds in southwestern Ontario. The study assessed the location and amount of agricultural land use associated with variation in BMI assemblage structure. Three land use distribution scenarios were evaluated to isolate specific ranges of agricultural land use at either the riparian or catchment scale, with the adjoining scale covering as wide a gradient of agricultural land use as possible. We did identify thresholds …

Temporal Variability In The Daytime Green Roof Energy Balance During Drying Periods, Dimuth C. Kurukulaarachchi

Electronic Thesis and Dissertation Repository

Green roofs are a building design element intended to increase evaporative cooling in cities during the summer, which helps alleviate the daytime impacts of heat on human health and energy consumption, and supports mitigation and adaptation to the local effects of climate change. Time varying energy balances were measured on a 0.15 m deep, ~ 60 m² modular green roof with Sedum spurium in London, Ontario for the summer of 2014. A lysimetry approach was used to measure latent heat Q_E. Net radiation Q^* and ground heat flux Q_G were also measured, with sensible heat …

Using Physical And Social Sensors In Real-Time Data Streaming For Natural Hazard Monitoring And Response, Yelena Kropivnitskaya

Electronic Thesis and Dissertation Repository

Technological breakthroughs in computing over the last few decades have resulted in important advances in natural hazards analysis. In particular, integration of a wide variety of information sources, including observations from spatially-referenced physical sensors and new social media sources, enables better estimates of real-time hazard. The main goal of this work is to utilize innovative streaming algorithms for improved real-time seismic hazard analysis by integrating different data sources and processing tools into cloud applications. In streaming algorithms, a sequence of items from physical and social sensors can be processed in as little as one pass with no need to store …

Anthropogenic Particles In Natural Sediment Sinks: Microplastics Accumulation In Tributary, Beach And Lake Bottom Sediments Of Lake Ontario, North America, Anika M. Ballent

Electronic Thesis and Dissertation Repository

Surface waters of the Great Lakes are known to be contaminated with microplastics, however, microplastics in the sediments of the region are poorly documented. This study provides a baseline of micro- and macro-plastics contamination in nearshore, tributary and beach sediments of Lake Ontario and the upper St. Lawrence River. Microplastics were quantified and characterized by morphology and composition using visual identification and Raman spectroscopy. Microplastics are most concentrated in nearshore sediments in the vicinity of urban and industrial regions. Concentrations in Humber Bay and Toronto Harbour consistently measured > 500 particles per kg dry sediment, and maximum concentrations of ~28,000 particles …

Field Scale Application Of Nanoscale Zero Valent Iron: Mobility, Contaminant Degradation, And Impact On Microbial Communities, Chris M.D. Kocur

Electronic Thesis and Dissertation Repository

This thesis began by verifying that nanoscale zero valent iron (nZVI) synthesis methods could be scaled up and implemented at the field scale in a safe manner. This led to successful demonstration of nZVI injection and mobility under constant head gravity injection into a contaminated utility corridor in Sarnia, Ontario. Where field studies have fallen short in the past was linking the somewhat qualitative field geochemical parameters to other evidence of nZVI transport. Definitive nZVI detection was elusive in previous field studies due to the highly reactive nature of the particles caused by their high surface area. nZVI was detected …

Exploration Of Spatial And Temporal Changes In Trophic Status Of Lakes In The Northern Temporal Forest Biome Using Remote Sensing, Aleksey Paltsev

Electronic Thesis and Dissertation Repository

There is a critical need for detailed surveys of lakes covering large spatial (>100 km²) and temporal scales (decades) to determine if there is an increase in the magnitude and frequency of phytoplankton blooms. Remote sensing was used to: (1) develop a regression model that relates chlorophyll a (chl-a) as a proxy of lake phytoplankton biomass to Landsat TM and ETM+ optical reflectance (r²=0.85, p

Land Use Interactions Drive Southwestern Ontario Stream Nutrient Concentrations, Renee L. Lazor

Electronic Thesis and Dissertation Repository

Human activities have transformed the landscape and altered natural habitats through intensive land uses including agriculture and urbanization. Identifying land use drivers of tributary nutrient concentrations and describing the magnitude and direction of their relationship are critical activities to improvement management of water quality in basins draining into the Great Lakes. The overarching goal of my thesis was to quantify the cumulative influence of spatial patterns in land use and land cover on variation of nutrient concentrations in tributaries of the Great Lakes. Biweekly water chemistry samples were collected in 29 streams located in southern Ontario between May and November, …

Potential Effects Of Changing Climate On The Physical, Chemical, And Biological Characteristics Of Alpine Lakes, Uinta Mountains, Utah, Usa, Shirley Ngai

Electronic Thesis and Dissertation Repository

Relationships between climate variables, lake characteristics and diatom community composition were determined for five lakes in the Uinta Mountains, Utah (USA) from spring 2010 to autumn 2013 to provide information to help predict the effects of climate change on lake ecosystems. Surface water temperatures increased with decreasing elevation although microclimates affected this relationship. Deeper water temperatures increased or stayed the same with increasing elevation, probably due to greater transparency or convective heating. Total phosphorus (TP) and chl a concentrations decreased in the spring/summer with warmer fall/winter temperatures, and nitrates in the spring increased with increased fall/winter precipitation. A significant correlation …

Multiple Approaches For Assessing Mangrove Biophysical And Biochemical Variables Using In Situ And Remote Sensing Techniques, Francisco Javier Flores De Santiago

Electronic Thesis and Dissertation Repository

Mangrove forests are important ecosystems and play a key role in maintaining the equilibrium in coastal lagoons and estuaries. However, in recent years, there has been a considerable loss of mangrove extension due to anthropogenic activities. Recent studies suggest that multiple in situ and remote sensing approaches must be carried out to understand the dynamics in these complex ecosystems. Therefore, the objective for this PhD dissertation is to develop multiple techniques for monitoring the seasonal biophysical and biochemical conditions of the mangrove forests. Particular objectives will include: i. Test the feasibility of using a Chlorophyll Content Index from a …

Topographic Influences On Trends And Cycles In Nutrient Export From Forested Catchments On The Precambrian Shield, Samson G. Mengistu

Electronic Thesis and Dissertation Repository

This dissertation explored topographic controls on spatial and temporal patterns in water yield and nutrient (carbon, nitrogen and phosphorus) export from forested headwater catchments in the Turkey Lakes Watershed in central Ontario, where other factors contributing to differences in water yield and nutrient export, including climate, geology, forest, and soils, are relatively constant. Topographic characteristics, including (a) hydrological flushing potential (expansion of water table into nitrate-N producing areas); (b) hydrological storage potential (area of wetlands, which can alternatively allow water and nutrients to bypass wetlands when storage capacity is filled with water or to trap them when not filled); and …