Open Access. Powered by Scholars. Published by Universities.®
Physical Sciences and Mathematics Commons™
Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 2 of 2
Full-Text Articles in Physical Sciences and Mathematics
The Effect Of Microbial Growth On The Spectral Induced Polarization Response In Hanford Vadose Zone Sediment In The Presence Of Autunite, Alejandro Garcia
The Effect Of Microbial Growth On The Spectral Induced Polarization Response In Hanford Vadose Zone Sediment In The Presence Of Autunite, Alejandro Garcia
FIU Electronic Theses and Dissertations
Uranium contamination of the subsurface remains a significant problem at the Department of Energy Hanford site. A series of column experiments were conducted on Hanford sediment saturated with simulated groundwater to study the effects of aqueous bicarbonate and microbial growth on the mobility of Uranium. Spectral induced polarization (SIP) measurements in the columns were conducted concurrently with pore water sampling in order to monitor changes occurring inside the sediment after the initiation of microbial growth induced by glucose injection. The microbial growth caused significant increases in the real component of the complex conductivity and is the result of ion release …
The Cyclodextrin-Perfluorinated Surfactant Host-Guest Complex: Fundamental Studies For Potential Environmental Remediation And Therapeutic Applications, Mary J. Errico
FIU Electronic Theses and Dissertations
Perfluoroalkyl substances (PFASs) are contaminants of emerging concern, and have been detected in drinking water, wildlife, humans, and the environment. Cyclodextrins (CDs), cyclic sugars composed of glucose monomers, are proposed as a potential remediation strategy. CDs can form host-guest complexes with hydrophobic molecules; this complexation could be capitalized on for PFAS removal and sequestration. These dissertation projects aim to study the fundamental host-guest interactions between a variety of PFASs and CDs for eventual applications in environmental and biological remediation. 1D and 2D Nuclear magnetic resonance (NMR) spectroscopic methods were employed to determine the strength, dynamics, and structure of the CD:PFAS …