Physical Sciences and Mathematics Commons^™

Evaluating Direct Filtration As An Alternative To Conventional Carbon-Based Advanced Treatment For Indirect Potable Reuse, Savannah M. Flemmer

Civil & Environmental Engineering Theses & Dissertations

Hampton Roads Sanitation District (HRSD) is recharging purified wastewater into the Potomac Aquifer via the Sustainable Water Initiative for Tomorrow (SWIFT) project. Conventional SWIFT treatment applies coagulation, flocculation, sedimentation, ozonation, biofiltration, granular activated carbon (GAC) adsorption, and ultraviolet disinfection to secondary effluent to produce water that meets drinking water standards for managed aquifer recharge. HRSD is considering implementing direct filtration as an alternative to conventional treatment for two additional SWIFT facilities. Direct filtration presents an opportunity for significant cost savings by eliminating sedimentation, shortening flocculation detention time, and reducing coagulant usage. Without upstream removal of solids and organics, however, biofilters …

Heterogeneous Oxidation Of Catechol, Elizabeth A. Pillar, Ruixin Zhou, Marcelo I. Guzman

Chemistry Faculty Publications

Natural and anthropogenic emissions of aromatic hydrocarbons from biomass burning, agro-industrial settings, and fossil fuel combustion contribute precursors to secondary aerosol formation (SOA). How these compounds are processed under humid tropospheric conditions is the focus of current attention to understand their environmental fate. This work shows how catechol thin films, a model for oxygenated aromatic hydrocarbons present in biomass burning and combustion aerosols, undergo heterogeneous oxidation at the air–solid interface under variable relative humidity (RH = 0–90%). The maximum reactive uptake coefficient of O₃(g) by catechol γ_O3 = (7.49 ± 0.35) × 10^–6 occurs for …

Catechol Oxidation By Ozone And Hydroxyl Radicals At The Air-Water Interface, Elizabeth A. Pillar, Robert C. Camm, Marcelo I. Guzman

Chemistry Faculty Publications

Anthropogenic emissions of aromatic hydrocarbons promptly react with hydroxyl radicals undergoing oxidation to form phenols and polyphenols (e.g., catechol) typically identified in the complex mixture of humic-like substances (HULIS). Because further processing of polyphenols in secondary organic aerosols (SOA) can continue mediated by a mechanism of ozonolysis at interfaces, a better understanding about how these reactions proceed at the air–water interface is needed. This work shows how catechol, a molecular probe of the oxygenated aromatic hydrocarbons present in SOA, can contribute interfacial reactive species that enhance the production of HULIS under atmospheric conditions. Reactive semiquinone radicals are quickly produced upon …

Modeling Dynamics Of Ozone And Nitrogen Oxides At Summit, Greenland With A 1-D Process-Scale Model, Keenan Anton Murray

Dissertations, Master's Theses and Master's Reports - Open

This work presents a 1-D process scale model used to investigate the chemical dynamics and temporal variability of nitrogen oxides (NO_x) and ozone (O₃) within and above snowpack at Summit, Greenland for March-May 2009 and estimates surface exchange of NO_x between the snowpack and surface layer in April-May 2009. The model assumes the surface of snowflakes have a Liquid Like Layer (LLL) where aqueous chemistry occurs and interacts with the interstitial air of the snowpack. Model parameters and initialization are physically and chemically representative of snowpack at Summit, Greenland and model results are compared to …

Evaluation Of Ozone Trends In Southern Doña Ana County, New Mexico Thru Wind Rose Analysis And Use Of Noaa Hysplit Model, Maria Aurelia Sisneros

Open Access Theses & Dissertations

The objective of this study was to determine whether increasing ozone concentrations in 2012 and 2013 at the Santa Teresa air quality monitor in Doña Ana County, New Mexico were due to a local point source impacting this monitor only or part of a regional phenomenon that affects all the monitors within the Paso del Norte Region. In addition, the study focused on identifying local and regional/long-range source areas contributing transport ozone to the study area (southern Doña Ana County).

The study showed that increasing ozone levels were not unique to the Santa Teresa monitor due to the fact that …