Physical Sciences and Mathematics Commons^™

Characterization Of Secondary Organic Aerosol Precursors Using Two-Dimensional Gas Chromatography With Time Of Flight Mass Spectrometry (Gc×Gc/Tofms), Melissa Jordan Roskamp

Dissertations and Theses

The oxidation of volatile organic compounds (VOCs) plays a role in both regional and global air quality through the formation of secondary organic aerosols (SOA). More than 1000TgC/yr of non-methane VOCs are emitted from biogenic sources (significantly greater than from anthropogenic sources). Despite this magnitude and potential importance for air quality, the body of knowledge around the identities, quantities and oxidation processes of these compounds is still incomplete (e.g., Goldstein & Galbally, 2007; Robinson et al., 2009). Two-dimensional gas chromatography paired with time-of-flight mass spectrometry (GC×GC/TOFMS) is a powerful analytical technique which is explored here for its role in better …

A Novel Approach To Flow Estimation In Tidal Rivers, Hamed Moftakhari Rostamkhani, David A. Jay, Stefan A. Talke, Tobias Kukulka, Peter D. Bromirski

Civil and Environmental Engineering Faculty Publications and Presentations

Reliable estimation of river discharge to the ocean from large tidal rivers is vital for water resources management and climate analyses. Due to the difficulties inherent in measuring tidal-river discharge, flow records are often limited in length and/or quality and tidal records often predate discharge records. Tidal theory indicates that tides and river discharge interact through quadratic bed friction, which diminishes and distorts the tidal wave as discharge increases. We use this phenomenon to develop a method of estimating river discharge for time periods with tidal data but no flow record. Employing sequential 32 day harmonic analyses of tidal properties, …

Predicting Landslides In Real Time, Michael J. Olsen

TREC Project Briefs

The Oregon Department of Transportation, or ODOT, has an ongoing struggle to maintain public highways against earth movements such as erosion, earthquakes and landslides. An earthquake or landslide can close down a road for days, while highway workers fight to keep supply lines open and repair the damage. Particularly along Oregon’s coastal roads with high sea cliffs, these natural processes are a constant threat to transportation infrastructure. The damage caused by gradual erosion is typically not detectable until there is a landslide or other disaster, costing the state considerable time and money to repair. New technology has the potential to …

Effects Of Molecular Structure Of The Oxidation Products Of Reactive Atmospheric Hydrocarbons On The Formation Of Secondary Organic Particulate Matter, Including The Effects Of Water, Negar Niakan

Dissertations and Theses

Organic aerosols have significant effects on human health, air quality and climate. Secondary organic aerosols (SOA) are produced by the oxidation of primary-volatile organic compounds (VOC). For example, α-pinene reacts with oxidants such as hydroxyl radical (OH), ozone (O₃), and nitrate radical (NO₃), accounting for a significant portion of total organic aerosol in the atmosphere. Experimental studies have shown that the oxidation process between α-pinene and ozone has the most significant impact in the formation of SOA (Hoffmann et al., 1997). Most of the models used to predict SOA formation, however, are limited in that they …

Characterization Of Nano-Scale Aluminum Oxide Transport Through Porous Media, Sasha Norien Norwood

Dissertations and Theses

Land application of biosolids has become common practice in the United States as an alternative to industrial fertilizers. Although nutrient rich, biosolids have been found to contain high concentrations of emerging contaminants (e.g. pharmaceuticals, personal care products) while containing a significant fraction of inorganic nano-scale colloidal materials such as oxides of iron, titanium, and aluminum.

Given their reactivity and small size, there are many questions concerning the potential migration of these nano-sized colloidal materials through the soil column and into our surface and groundwater bodies. Transport of emerging pollutants of concern through the soil column, at minimum, is impacted by …

Model For Acid-Base Chemistry In Nanoparticle Growth (Mabnag), Taina Yli-Juuti, Kelley Barsanti, L. Hildebrandt Ruiz, Antti-Jussi Kieloaho, U. Makkonen, Tuukka Petäjä, Taina Ruuskanen, Markku Kulmala, Ilona Riipinen

Civil and Environmental Engineering Faculty Publications and Presentations

Climatic effects of newly-formed atmospheric secondary aerosol particles are to a large extent determined by their condensational growth rates. However, all the vapours condensing on atmospheric nanoparticles and growing them to climatically relevant sizes are not identified yet and the effects of particle phase processes on particle growth rates are poorly known. Besides sulfuric acid, organic compounds are known to contribute significantly to atmospheric nanoparticle growth. In this study a particle growth model MABNAG (Model for Acid-Base chemistry in NAnoparticle Growth) was developed to study the effect of salt formation on nanoparticle growth, which has been proposed as a potential …

Analyzing Experimental Data And Model Parameters: Implications For Predictions Of Soa Using Chemical Transport Models, Kelley Barsanti, Annmarie G. Carlton, Serena H. Chung

Civil and Environmental Engineering Faculty Publications and Presentations

Despite critical importance for air quality and climate predictions, accurate representation of secondary organic aerosol (SOA) formation remains elusive. An essential addition to the ongoing discussion of improving model predictions is an acknowledgement of the linkages between experimental conditions, parameter optimization and model output, as well as the linkage between empirically-derived partitioning parameters and the physicochemical properties of SOA they represent in models. In this work, a "best available" set of SOA modeling parameters is selected by comparing predicted SOA yields and mass concentrations with observed yields and mass concentrations from a comprehensive list of published smog chamber studies. Evaluated …