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Full-Text Articles in Physical Sciences and Mathematics

Impacts Of Oil And Gas Wastes On Landfill Leachate, Sewage Treatment Plants, And The Environment, Lauren Badertscher Aug 2021

Impacts Of Oil And Gas Wastes On Landfill Leachate, Sewage Treatment Plants, And The Environment, Lauren Badertscher

Electronic Theses and Dissertations

Between January 2011 and March 2021 oil and gas wells in Pennsylvania produced

305,637,795 barrels of liquid waste and 6,992,957 tons of solid waste with the majority from

Marcellus Shale unconventional wells. This waste is not considered hazardous and over 89% of

the solid waste generated by unconventional and conventional oil and gas extraction has been

disposed of in landfills over the past decade. This study examined trends in the quantity of waste

produced and methods of disposal. Landfills accepting this waste were identified and their

general method of leachate treatment, using onsite facilities or offsite at wastewater treatment

plants, …


Caffeine Used As A Tracer Of Wastewater Contamination In South Florida, Stephanie Spence Jan 2017

Caffeine Used As A Tracer Of Wastewater Contamination In South Florida, Stephanie Spence

Honors Program Theses

In this study, a method was developed to analyze caffeine levels of water samples collected in Miami, Florida. The method was used to determine caffeine concentrations in reclaimed water samples and environmental water samples using on-line solid phase extraction (SPE) high pressure liquid chromatography (HPLC) high resolution mass spectrometry (HRMS). The rising use and disposal of pharmaceuticals and personal care products are becoming a concern as contaminants increasingly enter lakes, streams, and rivers without proper removal by traditional wastewater treatment processes. Caffeine may be used as a chemical tracer to indicate the presence of contamination in water samples and to …


Phosphorus Removal Using Titanium Dioxide Nanoparticles In Wastewater Treatment, Suyoung Choi Mr. Jan 2016

Phosphorus Removal Using Titanium Dioxide Nanoparticles In Wastewater Treatment, Suyoung Choi Mr.

Theses and Dissertations (Comprehensive)

Due to eutrophication caused by nutrients such as phosphorus (P), local surface water near military garrisons and camps has been deteriorated for several years in the Republic of Korea. Thus, in order to remove excessive P in local fresh water, various size of titanium dioxide (TiO2) were used.

In the first investigation, TiO2 mixed bulk powder (particle size > 5µm) showed maximum P removal with pH dependence (higher pH shows lower P removal), that was approximately 27%. To determine adsorption isotherms, Langmuir and Freudlich models were used. The experimental data was better fit by a Langmuir model compared …


Chemical Removal Of Total Phosphorus From Wastewater To Low Levels And Its Analysis, Farah Ateeq Jan 2016

Chemical Removal Of Total Phosphorus From Wastewater To Low Levels And Its Analysis, Farah Ateeq

Theses and Dissertations (Comprehensive)

Numerous studies have been conducted on the removal of inorganic phosphorus (P) from wastewater, but a push towards lower effluent targets necessitates the additional removal of organic phosphorus as well. This study tested the ability of manganese oxide nanoparticles and iron oxide as potential catalysts for conversion of organic P into more readily removable inorganic forms, as well as the role of iron(III) chloride as coagulant to subsequently allow P to be removed by solids/liquid separation. Removals of 99-101% were obtained for model compounds at pH 5-7, 0.05-0.5 M H2O2, and Fe:P molar ratio of 5:1. …


Analysis And Treatment Of Emerging Polar Contaminants, Daniel E. Connors Jan 2009

Analysis And Treatment Of Emerging Polar Contaminants, Daniel E. Connors

Electronic Theses and Dissertations

Two major classes of polar compounds have recently become a major focus as sources of contamination of water systems. Pharmaceuticals and personal care products (PPCPs) enter water through wastewater streams, and many of these compounds survive current wastewater treatment processes. High production volume chemicals (HPVCs), defined as chemicals produced in excess of one million pounds per year have numerous entries into surface and drinking waters due to their ubiquity. The commonality between many of these compounds is their polarity, which makes them water-soluble.

While both PPCPs and HPVCs have been entering into the environment for decades, advances in analyte detection …