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Full-Text Articles in Physical Sciences and Mathematics
Dissolution Of Chromium From Inhalable Primer Paint Particles Into A Simulated Lung Fluid, David A. Kauth
Dissolution Of Chromium From Inhalable Primer Paint Particles Into A Simulated Lung Fluid, David A. Kauth
Theses and Dissertations
The use of chromate as a corrosion inhibitor in primer paint is an essential component for the protection of aluminum-skinned aircraft and the primary source of hexavalent chromium (Cr (VI)) exposure to USAF aircraft painters. The objective of this research was to quantify the dissolution of chromate from freshly sprayed paint particles into a simulated lung fluid (SLF). Two primer paints were sprayed with a paint spray gun to generate overspray particles for collection into impingers filled with SLF. Particles were allowed to soak in SLF for 24 and 48 hours and then the particles were removed by centrifugation. The …
Optimization Of Palladium-Catalyzed In Situ Destruction Of Trichloroethylene-Contaminated Groundwater Using A Genetic Algorithm, Manuel Fernandez
Optimization Of Palladium-Catalyzed In Situ Destruction Of Trichloroethylene-Contaminated Groundwater Using A Genetic Algorithm, Manuel Fernandez
Theses and Dissertations
Conventional technologies for the treatment of groundwater contaminated with chlorinated solvents have limitations that have motivated development of innovative technologies. One such technology currently under development involves using palladium-on-alumina (Pd/Al) as a catalyst to promote dechlorination. Pd/Al catalyst may be used in-well as part of a re-circulating horizontal flow treatment well (HFTW) system. An HFTW system involves two or more dual-screened wells, with in-well reactors, to capture and treat contaminated groundwater without the need to pump the water to the surface. In this study, objective and fitness functions, based on system costs and TCE concentration requirements, were developed to optimize …
The Coupling Of Biotechnology With Electrochemistry: Electrodenitrification Of Water Using The Enzyme Nitrate Reductase, Cyril Geyer
Dissertations and Theses @ UNI
Nitrate is a worldwide contaminant that causes environmental (eutrophication) and human health (methemoglobinemia, cancers) concerns. Very few techniques are available to eliminate it from natural environment and they suffer from major drawbacks, such as production of unwanted byproducts (toxins or brine). The electrochemical reduction of nitrate on any electrode is relatively slow and catalysts or electron mediators are needed. The goal of this project was to develop a new process that could overcome these disadvantages. The project demonstrates the feasibility of using an enzyme, nitrate reductase, and a mediator, methyl viologen to transfer the electrons from the electrode to nitrate, …