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Full-Text Articles in Physical Sciences and Mathematics

Ambient Facile Synthesis Of Gram-Scale Copper Selenide Nanostructures From Commercial Copper And Selenium Powder, Xinqi Chen, Zhen Li, S X. Dou Dec 2014

Ambient Facile Synthesis Of Gram-Scale Copper Selenide Nanostructures From Commercial Copper And Selenium Powder, Xinqi Chen, Zhen Li, S X. Dou

Australian Institute for Innovative Materials - Papers

Grams of copper selenides (Cu2-xSe) were prepared from commercial copper and selenium powders in the presence of thiol ligands by a one-pot reaction at room temperature. The resultant copper selenides are a mixture of nanoparticles and their assembled nanosheets, and the thickness of nanosheets assembled is strongly dependent on the ratio of thiol ligand to selenium powder. The resultant Cu2-xSe (0 ≤ x ≤ 0.25) nanostructures were treated with hydrazine solution to remove the surface ligands and then explored as a potential thermoelectric candidate in comparison with commercial copper selenide powders. The research provides a novel …


Synthesis And Formation Mechanism Of Cuins2 Nanocrystals With A Tunable Phase, Chao Yu, Linlin Zhang, Long Tian, Dan Liu, Fanglin Chen, Cheng Wang Nov 2014

Synthesis And Formation Mechanism Of Cuins2 Nanocrystals With A Tunable Phase, Chao Yu, Linlin Zhang, Long Tian, Dan Liu, Fanglin Chen, Cheng Wang

Faculty Publications

Chalcopyrite CuInS2 (CIS) hierarchical structures composed of nanoflakes with a thickness of about 5 nm were synthesized by a facial solvothermal method. The thermodynamically metastable wurtzite phase CIS would be obtained by using InCl3 instead of In(NO3)3 as In precursor. The effects of the In precursor and the volume of concentrated HCl aqueous solution on the phases and morphologies of CIS nanocrystals have been systematically investigated. Experimental results indicated that the obtained phases of CIS nanocrystals were predominantly determined by precursor-induced intermediate products. The photocatalytic properties of chalcopyrite and wurtzite CIS in visible-light-driven degradation of …


One-Pot Aqueous Synthesis Of Cysteine-Capped Cdte/Cds Core-Shell Nanowires, Yukai Shan, Zhen Xiao, Yongming Chuan, Hongli Li, Minglong Yuan, Zhen Li, S X. Dou Oct 2014

One-Pot Aqueous Synthesis Of Cysteine-Capped Cdte/Cds Core-Shell Nanowires, Yukai Shan, Zhen Xiao, Yongming Chuan, Hongli Li, Minglong Yuan, Zhen Li, S X. Dou

Shi Xue Dou

Highly fluorescent cysteine-capped CdTe/CdS core-shell nanowires were successfully synthesized by reacting CdCl2 with NaHTe in aqueous solution under refluxing at 100 °C for 140 min. On increasing the reaction time from 10 to 140 min, CdTe/CdS nanocrystals gradually grew into nanorods and eventually completely evolved into nanowires. The nanowires have amino and carboxyl functional groups on their surfaces and can be well dispersed in aqueous solution. The as-prepared CdTe/CdS nanowires show a fluorescence quantum yield (QY) of 7.25 % due to the unique nature of cysteine and the formation of a CdS shell on the surface of the CdTe core, …


Size-Dependent Interactions Of Metal Nanoparticles With Fluorophores And Semiconductors, Liyana A. Wajira Ariyadasa Apr 2014

Size-Dependent Interactions Of Metal Nanoparticles With Fluorophores And Semiconductors, Liyana A. Wajira Ariyadasa

Dissertations

In recent years, nanoscale metallic particles have gained considerable interest due to their potential applications in advanced technology. Despite such interest, synthetic procedures that produce gram-scale, well-defined metallic nanoparticles with controlled size and shape, especially with diameters less than 5 nm remains a challenge. Our work has focused on developing synthetic procedures that produce well-defined platinum and palladium metal nanoparticles in the 1-5 nm size range. Thioether ligands were used as stabilizers and resulted in metal nanoparticles with controlled size. The nanoparticles were characterized using transmission electron microscopy (TEM), x-ray diffraction (XRD), selected area electron diffraction (SAED), x-ray photoelectron spectroscopy …


Facile Synthesis Of Reduced Graphene Oxide/Mwnts Nanocomposite Supercapacitor Materials Tested As Electrophoretically Deposited Films On Glassy Carbon Electrodes, Widsanusan Chartarrayawadee, Simon E. Moulton, Chee O. Too, Byung C. Kim, Rao Yepuri, Anthony C. Romeo, Gordon G. Wallace Mar 2014

Facile Synthesis Of Reduced Graphene Oxide/Mwnts Nanocomposite Supercapacitor Materials Tested As Electrophoretically Deposited Films On Glassy Carbon Electrodes, Widsanusan Chartarrayawadee, Simon E. Moulton, Chee O. Too, Byung C. Kim, Rao Yepuri, Anthony C. Romeo, Gordon G. Wallace

Gordon Wallace

This paper reports on a facile synthesis method for reduced graphene oxide (rGO)/multi-walled carbon nanotubes (MWNTs) nanocomposites. The initial step involves the use of graphene oxide to disperse the MWNTs, with subsequent reduction of the resultant graphene oxide/MWNTs composites using l-ascorbic acid (LAA) as a mild reductant. Reduction by LAA preserves the interaction between the rGO sheets and MWNTs. The dispersion-containing rGO/MWNTs composites was characterized and electrophoretically deposited anodically onto glassy carbon electrodes to form high surface area films for capacitance testing. Pseudo capacitance peaks were observed in the rGO/MWNTs composite electrodes, resulting in superior performance with capacitance values up …


Formation Of Magnesium Diboride-Based Materials With High Critical Currents And Mechanical Characteristics By High-Pressure Synthesis, Tetiana Prikhna, W. Gawalek, Ya M. Savchuk, N. V. Sergienko, V. E. Moshchil, M. Wendt, M. Zeisberger, T. Habisreuther, V. B. Sverdun, S X. Dou, S. N. Dub, V. S. Melnikov, Ch Schmidt, J. Dellith, P. A. Nagorny Mar 2014

Formation Of Magnesium Diboride-Based Materials With High Critical Currents And Mechanical Characteristics By High-Pressure Synthesis, Tetiana Prikhna, W. Gawalek, Ya M. Savchuk, N. V. Sergienko, V. E. Moshchil, M. Wendt, M. Zeisberger, T. Habisreuther, V. B. Sverdun, S X. Dou, S. N. Dub, V. S. Melnikov, Ch Schmidt, J. Dellith, P. A. Nagorny

Shi Xue Dou

The developed method of high-pressure synthesis (HPS) allows producing nanostructural highly dense material based on MGB2, which possesses the highest superconducting and mechanical characteristics among the known world analogues, in the form of blocks that are suitable for application in SC electromotors and pumps. Additions of Zr can increase critical current density (jc) of synthesized at 2 GPa and 750-800 °C MGB2 in the same manner as additions of Ta or Ti, i.e. due to the absorption of impurity hydrogen forming the ZrH2. The formation of ZrB2 phase at higher synthesis temperatures (about 950 °C) in HPS MGB2 does not …


Direct Synthesis Of Rgo/Cu2o Composite Films On Cu Foil For Supercapacitors, Xiangmao Dong, Kun Wang, Chongjun Zhao, Xiuzhen Qian, Shi Chen, Zhen Li, Hua-Kun Liu, S X. Dou Mar 2014

Direct Synthesis Of Rgo/Cu2o Composite Films On Cu Foil For Supercapacitors, Xiangmao Dong, Kun Wang, Chongjun Zhao, Xiuzhen Qian, Shi Chen, Zhen Li, Hua-Kun Liu, S X. Dou

Shi Xue Dou

Reduced graphene oxide/cuprous oxide (RGO/Cu2O) composite films were directly synthesized on the surface of copper foil substrates through a straight redox reaction between GO and Cu foil via a hydrothermal approach. Characterization of the resultant composites with X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, and field emission scanning electron microscope (FESEM) confirms the formation of Cu2O and reduction of GO, in which Cu2O nanoparticles were well covered by RGO. The resultant composites (referred to as RGO/Cu2O/Cu) were directly used as electrodes for supercapacitors, and their electrochemical performance was assessed by cyclic voltammetry (CV), galvanostatic charge–discharge (GCD), and electrochemical impedance spectrometry …


Facile Synthesis Of Highly Efficient One-Dimensional Plasmonic Photocatalysts Through Ag@Cu2o Core-Shell Heteronanowires, Jinyan Xiong, Zhen Li, Jun Chen, Shanqing Zhang, Lianzhou Wang, S X. Dou Jan 2014

Facile Synthesis Of Highly Efficient One-Dimensional Plasmonic Photocatalysts Through Ag@Cu2o Core-Shell Heteronanowires, Jinyan Xiong, Zhen Li, Jun Chen, Shanqing Zhang, Lianzhou Wang, S X. Dou

Australian Institute for Innovative Materials - Papers

A novel class of one-dimensional (1D) plasmonic Ag@Cu2O core-shell heteronanowires have been synthesized at room temperature for photocatalysis application. The morphology, size, crystal structure and composition of the products were investigated by XRD, SEM, TEM, XPS, and UV-vis instruments. It was found the reaction time and the amount of Ag nanowires play crucial roles in the formation of well-defined 1D Ag@Gu(2)O core-shell heteronanowires. The resultant 1D Ag@Cu2O NWs exhibit much higher photocatalytic activity toward degradation of organic contaminants than Ag@Cu2O core-shell nanopartides or pure Cu2O nanospheres under solar light irradiation. The drastic enhancement in photocatalytic activity could be attributed to …


Microemulsion-Assisted Synthesis Of Nanosized Li-Mn-O Spinel Cathodes For High-Rate Lithium-Ion Batteries, Xianhong Rui, Wenping Sun, Qingyu Yan, Tuti M. Lim, Maria Skyllas-Kazacos Jan 2014

Microemulsion-Assisted Synthesis Of Nanosized Li-Mn-O Spinel Cathodes For High-Rate Lithium-Ion Batteries, Xianhong Rui, Wenping Sun, Qingyu Yan, Tuti M. Lim, Maria Skyllas-Kazacos

Australian Institute for Innovative Materials - Papers

Li1.16Mn1.84O4 nanoparticles (50-90 nm) with cubic spinel structure are synthesized by combining a microemulsion process to produce ultrafine Mn(OH)2 nanocrystals (3-8 nm) with a solid-state lithiation step. The nanostructured lithium-rich Li1.16Mn1.84O4 shows stable cycling performance and superior rate capabilities as compared with the corresponding bulk material, for example, the nano-sized Li1.16Mn1.84O4 electrode shows stable reversible capacities of 74 mAhg-1 during the 1000th cycle at a high rate of 40 C between 3.0 and 4.5 V. In addition, Li1.16Mn1.84O4 nanoparticles also show high Li storage properties over an enlarged voltage window of 2.0-4.5 V with high capacities and stable cyclability, for …


Template Free Synthesis Of Cus Nanosheet-Based Hierarchical Microspheres: An Efficient Natural Light Driven Photocatalyst, M Tanveer, Chuanbao Cao, Zulfiqar Ali, Imran Aslam, Faryal Idrees, Waheed S. Khan, Faheem K. Butt, Muhammad Nawaz Tahir, Nasir Mahmood Jan 2014

Template Free Synthesis Of Cus Nanosheet-Based Hierarchical Microspheres: An Efficient Natural Light Driven Photocatalyst, M Tanveer, Chuanbao Cao, Zulfiqar Ali, Imran Aslam, Faryal Idrees, Waheed S. Khan, Faheem K. Butt, Muhammad Nawaz Tahir, Nasir Mahmood

Australian Institute for Innovative Materials - Papers

Well controlled nanosheets-based hierarchical microspheres (NSHMS) of pure covellite phase CuS were synthesized using a facile PVP assisted solvothermal process. The reaction conditions were optimized using various amounts of PVP to develop unique hierarchical structured hollow microspheres. CuS hollow structures have a bandgap of ~1.97 eV. These mesoporous structures exhibit excellent photocatalytic activity in degradation of organic dyes (Methylene Blue) under natural light in comparison to other structures of copper sulphide. These photocatalysts show extraordinary reusability with over 96.5% degradation of organic dye after 6th cycle. A "bottom-up" assembly was successfully developed to synthesize hollow microspheres with unique and well …


Direct Synthesis Of Rgo/Cu2o Composite Films On Cu Foil For Supercapacitors, Xiangmao Dong, Kun Wang, Chongjun Zhao, Xiuzhen Qian, Shi Chen, Zhen Li, Hua-Kun Liu, S X. Dou Jan 2014

Direct Synthesis Of Rgo/Cu2o Composite Films On Cu Foil For Supercapacitors, Xiangmao Dong, Kun Wang, Chongjun Zhao, Xiuzhen Qian, Shi Chen, Zhen Li, Hua-Kun Liu, S X. Dou

Australian Institute for Innovative Materials - Papers

Reduced graphene oxide/cuprous oxide (RGO/Cu2O) composite films were directly synthesized on the surface of copper foil substrates through a straight redox reaction between GO and Cu foil via a hydrothermal approach. Characterization of the resultant composites with X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, and field emission scanning electron microscope (FESEM) confirms the formation of Cu2O and reduction of GO, in which Cu2O nanoparticles were well covered by RGO. The resultant composites (referred to as RGO/Cu2O/Cu) were directly used as electrodes for supercapacitors, and their electrochemical performance was assessed by cyclic voltammetry (CV), galvanostatic charge–discharge (GCD), and electrochemical impedance spectrometry …


Optimization Of The Sequential Polymerization Synthesis Method For Polypyrrole Films, Danial Sangian, Wen Zheng, Geoffrey M. Spinks Jan 2014

Optimization Of The Sequential Polymerization Synthesis Method For Polypyrrole Films, Danial Sangian, Wen Zheng, Geoffrey M. Spinks

Australian Institute for Innovative Materials - Papers

Polypyrrole (PPy) is widely used as an electroactive material and is most often synthesized using electrochemical polymerization. Recently, a new electropolymerization method [1] was introduced that involved preparing the PPy as a sequential series of electrodeposited layers with solvent washing in between each deposited layer. This method enabled high quality PPy free-standing films to be prepared in a relatively short time. The purpose of the present study was to investigate the effect of the polymerization current density on the mechanical and electrical properties of the sequentially polymerized (SEP) PPy films. It was found that a low current density (0.1 mA/cm2) …


A Solvothermal Strategy: One-Step In Situ Synthesis Of Self-Assembled 3d Graphene-Based Composites With Enhanced Lithium Storage Capacity, Jingjing Ma, Jiulin Wang, Yu-Shi He, Xiao Zhen Liao, Jun Chen, Jiazhao Wang, Tao Yuan, Zi-Feng Ma Jan 2014

A Solvothermal Strategy: One-Step In Situ Synthesis Of Self-Assembled 3d Graphene-Based Composites With Enhanced Lithium Storage Capacity, Jingjing Ma, Jiulin Wang, Yu-Shi He, Xiao Zhen Liao, Jun Chen, Jiazhao Wang, Tao Yuan, Zi-Feng Ma

Australian Institute for Innovative Materials - Papers

A facile and controllable approach has been developed to synthesize three-dimensional (3D) graphene-based monoliths. Here, as a proof-of-concept experiment, self-assembled 3D CoO/graphene sheets (CoO/GS) composites with porous structures have been successfully fabricated in an ethanol medium by a one-step, in situ growth, solvothermal method. During the process, the in situ nucleation and growth of CoO particles on GS were tuned by the formation of a 3D GS network. In the as-prepared composites, the self-assembled 3D GS network around the CoO particles can not only provide a 3D conductive matrix, but also buffer the volume changes of CoO and restrain the …


Rapid Synthesis Of Li4ti5o12/Graphene Composite With Superior Rate Capability By A Microwave-Assisted Hydrothermal Method, Yi Shi, Jie Gao, Hector D. Abruna, Hua-Kun Liu, Huijun Li, Jiazhao Wang, Yuping Wu Jan 2014

Rapid Synthesis Of Li4ti5o12/Graphene Composite With Superior Rate Capability By A Microwave-Assisted Hydrothermal Method, Yi Shi, Jie Gao, Hector D. Abruna, Hua-Kun Liu, Huijun Li, Jiazhao Wang, Yuping Wu

Australian Institute for Innovative Materials - Papers

Li4Ti5O12 microspheres composed of nanoflakes wrapped in graphene nanosheets have been synthesized by an advanced microwave-hydrothermal (MW-HT) method for the preparation following by an annealing step. Microwave-assisted synthesis processes are appealing, as they can rapidly synthesize materials with a high degree of control of particle size and morphology at low cost. The resultant composite reveals a unique loose structure which could avoid the restacking of graphene sheets and offer rapid lithium ion diffusion paths. Therefore the Li4Ti5O12/graphene electrode has highly desirable properties: a specific capacity approaching the theoretical value, stable cycling, and exceptional rate capability. The composite also can be …


Porous Ni0.5zn0.5fe2o4 Nanospheres: Synthesis, Characterization, And Application For Lithium Storage, Min Zhang, Xuanwen Gao, Zhenfa Zi, Jianming Dai, Jiazhao Wang, Shulei Chou, Changhao Liang, Xuebin Zhu, Yuping Sun, Hua-Kun Liu Jan 2014

Porous Ni0.5zn0.5fe2o4 Nanospheres: Synthesis, Characterization, And Application For Lithium Storage, Min Zhang, Xuanwen Gao, Zhenfa Zi, Jianming Dai, Jiazhao Wang, Shulei Chou, Changhao Liang, Xuebin Zhu, Yuping Sun, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

Monodisperse porous Ni0.5Zn0.5Fe2O4 nanospheres have been successfully synthesized by the solvothermal method. The diameter of the nanospheres can be tuned by controlling the reactant concentration. Lower reactant concentration is favoured for the synthesis of mesoporous Ni0.5Zn0.5Fe2O4 nanospheres with higher surface area. The electrochemical results show that mesoporous Ni0.5Zn0.5Fe2O4 nanospheres exhibit high reversible specific capacity (1110 mAh g-1) for Li storage and high capacity retention, with 700 mAh g-1 retained up to 50 cycles. The excellent electrochemical properties could be attributed to the large surface area and mesoporous structure. The results suggest that Ni0.5Zn0.5Fe2O4 could be a promising high capacity anode …


Synthesis Of Potential Theranostic System Consisting Of Methotrexate-Immobilized (3-Aminopropyl)Trimethoxysilane Coated Α-Bi2o3 Nanoparticles For Cancer Treatment, Kathrin Bogusz, Moeava Tehei, Callum Stewart, Marjorie Mcdonald, Dean Cardillo, Michael Lerch, Stephanie Corde, Anatoly Rosenfeld, Hua-Kun Liu, Konstantin Konstantinov Jan 2014

Synthesis Of Potential Theranostic System Consisting Of Methotrexate-Immobilized (3-Aminopropyl)Trimethoxysilane Coated Α-Bi2o3 Nanoparticles For Cancer Treatment, Kathrin Bogusz, Moeava Tehei, Callum Stewart, Marjorie Mcdonald, Dean Cardillo, Michael Lerch, Stephanie Corde, Anatoly Rosenfeld, Hua-Kun Liu, Konstantin Konstantinov

Australian Institute for Innovative Materials - Papers

In this study we present the synthesis of a new theranostic system consisting of a core-shell structured nanoceramic-drug conjugate that can potentially combine chemotherapeutic, targeting, diagnostic and radio dose enhancing features in cancer treatment. The conjugate is made of α-Bi2O3 nanoparticles (NPs) which were first coated with (3-aminopropyl)trimethoxysilane (APTMS) to form a core-shell structure and then attached with methotrexate (MTX) through amidation between the amine moieties on the shell and the carboxylic acid groups on MTX. While α-Bi2O3 NPs with high effective atomic number can serve as both contrast agent and radiosensitiser in dose enhancement radiation therapy, MTX as an …


One-Pot Synthesis Of Α-Fe2o3 Nanoparticles-Decorated Reduced Graphene Oxide For Efficient Nonenzymatic H2o2 Biosensor, Ming-Yan Wang, Tao Shen, Meng Wang, Dong-En Zhang, Zhi-Wei Tong, Jun Chen Jan 2014

One-Pot Synthesis Of Α-Fe2o3 Nanoparticles-Decorated Reduced Graphene Oxide For Efficient Nonenzymatic H2o2 Biosensor, Ming-Yan Wang, Tao Shen, Meng Wang, Dong-En Zhang, Zhi-Wei Tong, Jun Chen

Australian Institute for Innovative Materials - Papers

Hematite nanoparticles (α-Fe2O3) are successfully decorated on the reduced graphene oxide (rGO) sheets through a simple, one-step, hydrothermal method without addition of other reducing agents. The α-Fe2O3/rGO hybrid was characterized by scanning electron micrographs, X-ray diffraction, X-ray photoelectron spectroscopy, and Raman spectroscopy. This α-Fe2O3/rGO hybrid has been successfully applied in the catalytic performance toward the reduction of H2O2. The nonenzymatic sensor demonstrates a linear relationship over a wide concentration range of 5.0–4495.0 μM (R = 0.9998), a low detection limit of 1.0 μM, and a high sensitivity of 126.9 μA cm−2 mM−1 to the detection of H2O2.


One-Pot Aqueous Synthesis Of Cysteine-Capped Cdte/Cds Core-Shell Nanowires, Yukai Shan, Zhen Xiao, Yongming Chuan, Hongli Li, Minglong Yuan, Zhen Li, S X. Dou Jan 2014

One-Pot Aqueous Synthesis Of Cysteine-Capped Cdte/Cds Core-Shell Nanowires, Yukai Shan, Zhen Xiao, Yongming Chuan, Hongli Li, Minglong Yuan, Zhen Li, S X. Dou

Australian Institute for Innovative Materials - Papers

Highly fluorescent cysteine-capped CdTe/CdS core-shell nanowires were successfully synthesized by reacting CdCl2 with NaHTe in aqueous solution under refluxing at 100 °C for 140 min. On increasing the reaction time from 10 to 140 min, CdTe/CdS nanocrystals gradually grew into nanorods and eventually completely evolved into nanowires. The nanowires have amino and carboxyl functional groups on their surfaces and can be well dispersed in aqueous solution. The as-prepared CdTe/CdS nanowires show a fluorescence quantum yield (QY) of 7.25 % due to the unique nature of cysteine and the formation of a CdS shell on the surface of the CdTe core, …


Ambient Scalable Synthesis Of Surfactant-Free Thermoelectric Cuagse Nanoparticles With Reversible Metallic-N-P Conductivity Transition, Chao Han, Qiao Sun, Zhenxiang Cheng, Jianli Wang, Zhen Li, Gao Qing (Max) Lu, S X. Dou Jan 2014

Ambient Scalable Synthesis Of Surfactant-Free Thermoelectric Cuagse Nanoparticles With Reversible Metallic-N-P Conductivity Transition, Chao Han, Qiao Sun, Zhenxiang Cheng, Jianli Wang, Zhen Li, Gao Qing (Max) Lu, S X. Dou

Australian Institute for Innovative Materials - Papers

Surfactant-free CuAgSe nanoparticles were successfully synthesized on a large scale within a short reaction time via a simple environmentally friendly aqueous approach under room temperature. The nanopowders obtained were consolidated into pellets for investigation of their thermoelectric properties between 3 and 623 K. The pellets show strong metallic characteristics below 60 K and turn into an n-type semiconductor with increasing temperature, accompanied by changes in the crystal structure (i.e., from the pure tetragonal phase into a mixture of tetragonal and orthorhombic phases), the electrical conductivity, the Seebeck coefficient, and the thermal conductivity, which leads to a figure of merit (ZT) …


One-Step Synthesis Of Graphene/Polypyrrole Nanofiber Composites As Cathode Material For A Biocompatible Zinc/Polymer Battery, Sha Li, Kewei Shu, Chen Zhao, Caiyun Wang, Zaiping Guo, Gordon G. Wallace, Hua-Kun Liu Jan 2014

One-Step Synthesis Of Graphene/Polypyrrole Nanofiber Composites As Cathode Material For A Biocompatible Zinc/Polymer Battery, Sha Li, Kewei Shu, Chen Zhao, Caiyun Wang, Zaiping Guo, Gordon G. Wallace, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

The significance of developing implantable, biocompatible, miniature power sources operated in a low current range has become manifest in recent years to meet the demands of the fast-growing market for biomedical microdevices. In this work, we focus on developing high-performance cathode material for biocompatible zinc/polymer batteries utilizing biofluids as electrolyte. Conductive polymers and graphene are generally considered to be biocompatible and suitable for bioengineering applications. To harness the high electrical conductivity of graphene and the redox capability of polypyrrole (PPy), a polypyrrole fiber/graphene composite has been synthesized via a simple one-step route. This composite is highly conductive (141 S cm …


Synthesis And Electrochemical Properties Of Wo3/C For Lithium Ion Batteries, Hong Gao, Shuijin S. Yang, Chuanqi Feng, Jiazhao Wang, Zaiping Guo Jan 2014

Synthesis And Electrochemical Properties Of Wo3/C For Lithium Ion Batteries, Hong Gao, Shuijin S. Yang, Chuanqi Feng, Jiazhao Wang, Zaiping Guo

Australian Institute for Innovative Materials - Papers

WO3/C nanorods were prepared by a combination of hydrothermal synthesis method and the solid phase reaction method, using (NH4)10H2(W2O7)6, H2C2O4·2H2O and glucose(carbon source) as raw materials. The effects of different proportions of glucose on the morphologies and electrochemical properties of the final products were systematically investigated. The results showed that the WO3/C nanorods prepared with the 10 wt.% glucose as carbon source exhibited the highest reversible specific capacity (807 mAh g-1) at current density …


Recent Progress On Synthesis, Multi-Scale Structure, And Properties Of Y-Si-O Oxides, Ziqi Sun, M S. Li, Y C. Zhou Jan 2014

Recent Progress On Synthesis, Multi-Scale Structure, And Properties Of Y-Si-O Oxides, Ziqi Sun, M S. Li, Y C. Zhou

Australian Institute for Innovative Materials - Papers

Yttrium silicates (Y-Si-O oxides), including Y2Si2O7, Y2SiO5, and Y4·67(SiO4)3O apatite, have attracted wide attentions from material scientists and engineers, because of their extensive polymorphisms and important roles as grain boundary phases in improving the high-temperature mechanical/thermal properties of Si3N4 and SiC ceramics. Recent interest in these materials has been renewed by their potential applications as high-temperature structural ceramics, oxidation protective coatings, and environmental barrier coatings (EBCs). The salient properties of Y-Si-O oxides are strongly related to their unique chemical bonds and …