Open Access. Powered by Scholars. Published by Universities.®

Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

Articles 1 - 13 of 13

Full-Text Articles in Physical Sciences and Mathematics

Enhancement Of Transition Temperature In Fexse0.5te0.5 Film Via Iron Vacancies, J C. Zhuang, Wai K. Yeoh, Xiangyuan Cui, Jung Ho Kim, Dongqi Shi, Z X. Shi, S P. Ringer, Xiaolin Wang, S X. Dou Oct 2014

Enhancement Of Transition Temperature In Fexse0.5te0.5 Film Via Iron Vacancies, J C. Zhuang, Wai K. Yeoh, Xiangyuan Cui, Jung Ho Kim, Dongqi Shi, Z X. Shi, S P. Ringer, Xiaolin Wang, S X. Dou

Shi Xue Dou

The effects of iron deficiency in Fe x Se0.5Te0.5 thin films (0.8 ≤ x ≤ 1) on superconductivity and electronic properties have been studied. A significant enhancement of the superconducting transition temperature (TC ) up to 21 K was observed in the most Fe deficient film (x = 0.8). Based on the observed and simulated structural variation results, there is a high possibility that Fe vacancies can be formed in the Fe x Se0.5Te0.5 films. The enhancement of TC shows a strong relationship with the lattice strain effect induced by Fe vacancies. Importantly, the presence of Fe vacancies alters the …


Large Magnetoelectric Coupling In Magnetically Short-Range Ordered Bi5ti3feo15 Film, Hongyang Zhao, Hideo Kimura, Zhenxiang Cheng, Minoru Osada, Jianli Wang, Xiaolin Wang, S X. Dou, Yan Liu, Jianding Yu, Takao Matsumoto, Tetsuya Tohei, Naoya Shibata, Yuichi Ikuhara Oct 2014

Large Magnetoelectric Coupling In Magnetically Short-Range Ordered Bi5ti3feo15 Film, Hongyang Zhao, Hideo Kimura, Zhenxiang Cheng, Minoru Osada, Jianli Wang, Xiaolin Wang, S X. Dou, Yan Liu, Jianding Yu, Takao Matsumoto, Tetsuya Tohei, Naoya Shibata, Yuichi Ikuhara

Shi Xue Dou

Multiferroic materials, which offer the possibility of manipulating the magnetic state by an electric field or vice versa, are of great current interest. However, single-phase materials with such cross-coupling properties at room temperature exist rarely in nature; new design of nano-engineered thin films with a strong magneto-electric coupling is a fundamental challenge. Here we demonstrate a robust room-temperature magneto-electric coupling in a bismuth-layer-structured ferroelectric Bi5Ti3FeO15 with high ferroelectric Curie temperature of ~1000 K. Bi5Ti3FeO15 thin films grown by pulsed laser deposition are single-phase layered perovskit with nearly (00l)-orientation. Room-temperature multiferroic behavior is demonstrated by a large modulation in magneto-polarization and …


Interface Strain-Induced Multiferroicity In A Smfeo3 Film, Zhenxiang Cheng, Fang Hong, Yuanxu Wang, Kiyoshi Ozawa, Hiroki Fujii, Hideo Kimura, Yi Du, Xiaolin Wang, S X. Dou Oct 2014

Interface Strain-Induced Multiferroicity In A Smfeo3 Film, Zhenxiang Cheng, Fang Hong, Yuanxu Wang, Kiyoshi Ozawa, Hiroki Fujii, Hideo Kimura, Yi Du, Xiaolin Wang, S X. Dou

Shi Xue Dou

An epitaxial pseudocubic SmFeO3 thin film on (100) Nb-SrTiO 3 was studied based on ferroelectric (FE) characterization and magnetic measurements. High-resolution transmission electron microscopy images clarify the nature of the epitaxial growth, the stress-induced structural distortion at the film/substrate interface, and the existence of two different orientation lattices. Clear grain boundaries can be seen, which could introduce an extra local distortion. Rectangular FE loops can be observed at room temperature, even by just applying a small voltage ranging from -1 to +1 V, indicative of the presence of FE polarization. Piezoelectric force microscopy images confirm the existence of FE domains …


Microscopic Model For Exchange Bias From Grain-Boundary Disorder In A Ferromagnet/Antiferromagnet Thin Film With A Nanocrystalline Microstructure, David L. Cortie, A G. Biternas, R W. Chantrell, Xiaolin Wang, Frank Klose Jan 2014

Microscopic Model For Exchange Bias From Grain-Boundary Disorder In A Ferromagnet/Antiferromagnet Thin Film With A Nanocrystalline Microstructure, David L. Cortie, A G. Biternas, R W. Chantrell, Xiaolin Wang, Frank Klose

Australian Institute for Innovative Materials - Papers

Monte Carlo spin simulations were coupled to a Voronoi microstructure-generator to predict the magnitude and behavior of exchange bias in a ferromagnet/antiferromagnet (AF) thin film bilayer with a nanocrystalline microstructure. Our model accounts for the effects of irregular grain-shapes, finite-sized particles, and the possible presence of local random-fields originating from the antiferromagnet's grain-boundary regions. As the grain-boundary represents a crystal-structure distortion, we model the local effect on the exchange constants in the Gaussian approximation which can cause regions resembling a spin glass confined to an unusual 2D topology. Although an ensemble of completely disconnected AF grains isolated by non-magnetic barriers …


Large Magnetoelectric Coupling In Magnetically Short-Range Ordered Bi5ti3feo15 Film, Hongyang Zhao, Hideo Kimura, Zhenxiang Cheng, Minoru Osada, Jianli Wang, Xiaolin Wang, S X. Dou, Yan Liu, Jianding Yu, Takao Matsumoto, Tetsuya Tohei, Naoya Shibata, Yuichi Ikuhara Jan 2014

Large Magnetoelectric Coupling In Magnetically Short-Range Ordered Bi5ti3feo15 Film, Hongyang Zhao, Hideo Kimura, Zhenxiang Cheng, Minoru Osada, Jianli Wang, Xiaolin Wang, S X. Dou, Yan Liu, Jianding Yu, Takao Matsumoto, Tetsuya Tohei, Naoya Shibata, Yuichi Ikuhara

Australian Institute for Innovative Materials - Papers

Multiferroic materials, which offer the possibility of manipulating the magnetic state by an electric field or vice versa, are of great current interest. However, single-phase materials with such cross-coupling properties at room temperature exist rarely in nature; new design of nano-engineered thin films with a strong magneto-electric coupling is a fundamental challenge. Here we demonstrate a robust room-temperature magneto-electric coupling in a bismuth-layer-structured ferroelectric Bi5Ti3FeO15 with high ferroelectric Curie temperature of ~1000 K. Bi5Ti3FeO15 thin films grown by pulsed laser deposition are single-phase layered perovskit with nearly (00l)-orientation. Room-temperature multiferroic behavior is demonstrated by a large modulation in magneto-polarization and …


A Study Of Ti-Doped Wo3 Thin Films Using Comparative Theoretical And Experimental Approach, Aurelio Paez Jan 2014

A Study Of Ti-Doped Wo3 Thin Films Using Comparative Theoretical And Experimental Approach, Aurelio Paez

Open Access Theses & Dissertations

Metal oxides like Tungsten Oxide (WO3) are well documented and characterized in the literature, with uses in darkening windows and mirrors, flat computer displays, solar panel cooling, and sensors (of interest in this study). Ti doping of WO3 is less documented and the focus of this study. Sample thin films of pure WO3 and varyingly Ti doped WO3 were prepared using Radio Frequency magnetron sputtering (RF) (13.56 MHz) to grow thin films on a silicon substrate. This study aims to compare multiple Ti doping percentages in WO3 theoretically and then compare with experimental data taken from thin films of various …


Interface Strain-Induced Multiferroicity In A Smfeo3 Film, Zhenxiang Cheng, Fang Hong, Yuanxu Wang, Kiyoshi Ozawa, Hiroki Fujii, Hideo Kimura, Yi Du, Xiaolin Wang, S X. Dou Jan 2014

Interface Strain-Induced Multiferroicity In A Smfeo3 Film, Zhenxiang Cheng, Fang Hong, Yuanxu Wang, Kiyoshi Ozawa, Hiroki Fujii, Hideo Kimura, Yi Du, Xiaolin Wang, S X. Dou

Australian Institute for Innovative Materials - Papers

An epitaxial pseudocubic SmFeO3 thin film on (100) Nb-SrTiO 3 was studied based on ferroelectric (FE) characterization and magnetic measurements. High-resolution transmission electron microscopy images clarify the nature of the epitaxial growth, the stress-induced structural distortion at the film/substrate interface, and the existence of two different orientation lattices. Clear grain boundaries can be seen, which could introduce an extra local distortion. Rectangular FE loops can be observed at room temperature, even by just applying a small voltage ranging from -1 to +1 V, indicative of the presence of FE polarization. Piezoelectric force microscopy images confirm the existence of FE domains …


Enhancement Of Transition Temperature In Fexse0.5te0.5 Film Via Iron Vacancies, J C. Zhuang, Wai K. Yeoh, Xiangyuan Cui, Jung Ho Kim, Dongqi Shi, Z X. Shi, S P. Ringer, Xiaolin Wang, S X. Dou Jan 2014

Enhancement Of Transition Temperature In Fexse0.5te0.5 Film Via Iron Vacancies, J C. Zhuang, Wai K. Yeoh, Xiangyuan Cui, Jung Ho Kim, Dongqi Shi, Z X. Shi, S P. Ringer, Xiaolin Wang, S X. Dou

Australian Institute for Innovative Materials - Papers

The effects of iron deficiency in Fe x Se0.5Te0.5 thin films (0.8 ≤ x ≤ 1) on superconductivity and electronic properties have been studied. A significant enhancement of the superconducting transition temperature (TC ) up to 21 K was observed in the most Fe deficient film (x = 0.8). Based on the observed and simulated structural variation results, there is a high possibility that Fe vacancies can be formed in the Fe x Se0.5Te0.5 films. The enhancement of TC shows a strong relationship with the lattice strain effect induced by Fe vacancies. Importantly, the presence of Fe vacancies alters the …


Highly Oriented Lifepo4 Thin Film Electrodes Via Chemical Solution Deposition, Qi Li, Shulei Chou, Jiazhao Wang, Dongqi Shi, Hua-Kun Liu Jan 2014

Highly Oriented Lifepo4 Thin Film Electrodes Via Chemical Solution Deposition, Qi Li, Shulei Chou, Jiazhao Wang, Dongqi Shi, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

Highly oriented LiFePO4 thin-film electrodes were fabricated via chemical solution deposition combined with spin coating. The effects of the precursor concentrations and types of substrates on microstructures and electrochemical performances were studied. Single-phase LiFePO4 with orientations perpendicular to the (211)/(020) and (311) planes prepared using stainless steel as substrate presents the capacity of 4.9 μAh•cm-2 and the apparent activation energy of 59.2 kJ•mol-1, indicating its great potential to be used as cathode material for lithium thin film batteries.


Non-Wettable, Oxidation-Stable, Brightly Luminescent, Perfluorodecyl-Capped Silicon Nanocrystal Film, Chenxi Qian, Wei Sun, Liwei Wang, Chanlong Chen, Kristine Liao, Wendong Wang, Jia Jia, Benjamin D. Hatton, Gilberto Casillas, Marty Kurylowicz, Christopher M. Yip, Melanie L. Mastronardi, Geoffrey A. Ozin Jan 2014

Non-Wettable, Oxidation-Stable, Brightly Luminescent, Perfluorodecyl-Capped Silicon Nanocrystal Film, Chenxi Qian, Wei Sun, Liwei Wang, Chanlong Chen, Kristine Liao, Wendong Wang, Jia Jia, Benjamin D. Hatton, Gilberto Casillas, Marty Kurylowicz, Christopher M. Yip, Melanie L. Mastronardi, Geoffrey A. Ozin

Australian Institute for Innovative Materials - Papers

Here we describe for the first time the synthesis of colloidally stable, brightly luminescent perfluorodecyl-capped silicon nanocrystals and compare the properties of solutions and films made from them with those of their perhydrodecyl-capped relatives. The perfluorodecyl capping group compared to the perhydrodecyl capping group yields superior hydrophobicity and much greater resistance to air oxidation, the enhanced electron-withdrawing character induces blue shifts in the wavelength of photoluminescence, and the lower-frequency carbon-fluorine stretching modes disfavor non-radiative relaxation pathways and boost the absolute photoluminescence quantum yield. Together these attributes bode well for advanced materials and biomedical applications founded upon perfluorodecyl-protected silicon nanocrystals.


Significant Tunability Of Thin Film Functionalities Enabled By Manipulating Magnetic And Structural Nano-Domains, Igor A. Golovchanskiy, Alexey V. Pan, Sergey A. Fedoseev, Michael Higgins Jan 2014

Significant Tunability Of Thin Film Functionalities Enabled By Manipulating Magnetic And Structural Nano-Domains, Igor A. Golovchanskiy, Alexey V. Pan, Sergey A. Fedoseev, Michael Higgins

Australian Institute for Innovative Materials - Papers

The influence of laser frequency on the structure and physical properties of thin films grown by pulsed laser deposition has been studied. Different types of thin films, hard ferromagnetic FePt L10 and quasi-single crystal superconducting YBa2Cu3O7 (YBCO), have been used for demonstration of the effect. Significant structural modifications have been obtained for the films with similar thicknesses. These modifications are shown to dramatically control their corresponding properties, providing an instrumental ability for tuning the practical characteristics of the films by changing the laser frequency of their deposition. In particular, 20-fold increase of coercive field and modification of demagnetization mechanism are …


Mechanically Strong High Performance Layered Polypyrrole Nano Fibre/Graphene Film For Flexible Solid State Supercapacitor, Sha Li, Chen Zhao, Kewei Shu, Caiyun Wang, Zaiping Guo, Gordon G. Wallace, Hua-Kun Liu Jan 2014

Mechanically Strong High Performance Layered Polypyrrole Nano Fibre/Graphene Film For Flexible Solid State Supercapacitor, Sha Li, Chen Zhao, Kewei Shu, Caiyun Wang, Zaiping Guo, Gordon G. Wallace, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

Paper like flexible electrode becomes one of the most important research objects recently in request of the fast expanding market of portable electronics. Flexible solid state supercapacitors are shortlisted as one of the most promising energy devices to power electronics with medium to high power density requirements. In this work, we developed a simple but effective way to produce a mechanically strong and electrochemically active RGO/polypyrrole (PPy) fibre paper. A well-bedded microstructure was created with interlaced polypyrrole fibres evenly distributed between the graphene layers. Such microstructure can create enormous amount of pores and therefore provides larger interfaces for charge carrier …


Temperature Dependent Photoexcited Carrier Dynamics In Multiferroic Bifeo3 Film: A Hidden Phase Transition, Zeyu Zhang, Zuanming Jin, Qunfeng Pan, Yue Xu, Xian Lin, Guohong Ma, Zhenxiang Cheng Jan 2014

Temperature Dependent Photoexcited Carrier Dynamics In Multiferroic Bifeo3 Film: A Hidden Phase Transition, Zeyu Zhang, Zuanming Jin, Qunfeng Pan, Yue Xu, Xian Lin, Guohong Ma, Zhenxiang Cheng

Australian Institute for Innovative Materials - Papers

The ultrafast carrier dynamics of the multiferroic BiFeO3 film in a broad temperature range is investigated using optical pump-probe spectroscopy. The photoexcited electrons release their energy with optical phonons emission through electron-phonon coupling in about 1 ps. The following intermediate process is identified as dynamical spin-lattice coupling in several picoseconds. Furthermore, the peak values of the optical reflectivity and the time constants of carrier relaxation channels show significant changes while the temperature varies from 137.5 K to around 195 K, this aligns with the previously reported hidden phase transition. Our study demonstrates that ultrafast spectroscopy is a sensitive method to …