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Effects Of Local Non-Equilibrium Solute Diffusion On Rapid Solidification Of Alloys, Sergey Sobolev Jan 1996

Effects Of Local Non-Equilibrium Solute Diffusion On Rapid Solidification Of Alloys, Sergey Sobolev

Sergey Sobolev

A conceptual foundation for the study of local non-equilibrium solute diffusion under rapid solidifica- tion conditions is proposed. The model takes into account the relaxation to local equilibrium of the solute flux and incorporates two diffusion speeds, VDb, the bulk liquid diffusion speed, and VDi, the interface diffusive speed, as the most important parameters governing the solute concentration in the liquid phase and solute partitioning. The analysis of the model predicts complete solute trapping and the transition to a purely thermally controlled solidification, which occur abruptly when the interface velocity V equals the bulk liquid diffusion speed VDb. The abrupt …


The Local-Nonequilibrium Temperature Field Around The Melting And Crystallization Front Induced By Picosecond Pulsed Laser Irradiation, Sergey Sobolev Jan 1996

The Local-Nonequilibrium Temperature Field Around The Melting And Crystallization Front Induced By Picosecond Pulsed Laser Irradiation, Sergey Sobolev

Sergey Sobolev

The local-nonequilibrium model for heat transport around melting and crystallization zone induced by ultrafast laser irradiation is considered. The model predicts strong overheating during melting of the material near the interface. Moreover, the local-nonequilibrium effects lead to an interface temperature gradient steeper than expected from the classical heat flow calculations. Possible modification of the kinetics of melting to include the relaxation effects is also discussed.