Physical Sciences and Mathematics Commons^™

A Study On The Integration Of A Novel Absorption Chiller Into A Microscale Combined Cooling, Heating, And Power (Micro-Cchp) System, Scott J. Richard

University of New Orleans Theses and Dissertations

This study explores the application of micro-CCHP systems that utilize a 30 kW gas microturbine and an absorption chiller. Engineering Equation Solver (EES) is used to model a novel single-effect and double-effect water-lithium bromide absorption chiller that integrates the heat recovery unit and cooling tower of a conventional CCHP system into the chiller’s design, reducing the cost and footprint of the system. The results of the EES model are used to perform heat and material balances for the micro-CCHP systems employing the novel integrated chillers, and energy budgets for these systems are developed. While the thermal performance of existing CCHP …

Disaster Data Management In Cloud Environments, Katarina Grolinger

Electronic Thesis and Dissertation Repository

Facilitating decision-making in a vital discipline such as disaster management requires information gathering, sharing, and integration on a global scale and across governments, industries, communities, and academia. A large quantity of immensely heterogeneous disaster-related data is available; however, current data management solutions offer few or no integration capabilities and limited potential for collaboration. Moreover, recent advances in cloud computing, Big Data, and NoSQL have opened the door for new solutions in disaster data management.

In this thesis, a Knowledge as a Service (KaaS) framework is proposed for disaster cloud data management (Disaster-CDM) with the objectives of 1) facilitating information gathering …

On The Interoperability Of Programming Languages Based On The Fork-Join Parallelism Model, Sushek Shekar

Electronic Thesis and Dissertation Repository

This thesis describes the implementation of MetaFork, a meta-language for concurrency platforms targeting multicore architectures. First of all, MetaFork is a multithreaded language based on the fork-join model of concurrency: it allows the programmer to express parallel algorithms assuming that tasks are dynamically scheduled at run-time. While MetaFork makes no assumption about the run-time system, it formally defines the serial C-elision of a MetaFork program. In addition, MetaFork is a suite of source-to-source compilers permitting the automatic translation of multithreaded programs between programming languages based on the fork-join model. Currently, this compilation framework supports the OpenMP and CilkPlus concurrency platforms. …

Electrochemical And Surface Compositional Studies On Uranium Dioxide, Mayuri Razdan

Electronic Thesis and Dissertation Repository

This thesis describes electrochemical and surface compositional studies performed on a number of simulated nuclear fuel (SIMFUEL) materials under conditions relevant to permanent disposal of spent nuclear fuel in a geologic repository. This is important since a number of critical issues have been identified in the event of waste container failure. The research performed was mainly focused in three areas: (i) the influence of low pH on the surface chemistry of UO₂, since acidity could develop within corrosion product deposits and flaws in the fuel; (ii) the combined influence of dissolved H₂ and H₂O_{2 …}

A Viscous Flow Analog To Prandtl’S Optimized Lifting Line Theory Utilizing Rotating Biquadratic Bodies Of Revolution, Mark Nathaniel Callender

Doctoral Dissertations

Prandtl’s lifting line theory expanded the Kutta-Joukowski theorem to calculate the lift and induced drag of finite wings. The circulation distribution about a real wing was represented by a superposition of infinitesimal vortex filaments. From this theory, the optimum distribution of circulation was determined to be elliptical. A consequence of this theory led to the prediction that the elliptical chord distribution on a real fixed wing would provide the elliptical circulation distribution. The author applied the same line of reasoning to lift-producing rotating cylinders in order to determine the cylindrical geometry that would theoretically produce an elliptical circulation distribution. The …

Bayesian Dictionary Learning For Single And Coupled Feature Spaces, Li He

Doctoral Dissertations

Over-complete bases offer the flexibility to represent much wider range of signals with more elementary basis atoms than signal dimension. The use of over-complete dictionaries for sparse representation has been a new trend recently and has increasingly become recognized as providing high performance for applications such as denoise, image super-resolution, inpaiting, compression, blind source separation and linear unmixing. This dissertation studies the dictionary learning for single or coupled feature spaces and its application in image restoration tasks. A Bayesian strategy using a beta process prior is applied to solve both problems.

Firstly, we illustrate how to generalize the existing beta …

Wind Turbine Controls For Farm And Offshore Operation, Zhongzhou Yang

Theses and Dissertations

Development of advanced control techniques is a critical measure for reducing the cost of energy for wind power generation, in terms of both enhancing energy capture and reducing fatigue load. There are two remarkable trends for wind energy. First, more and more large wind farms are developed in order to reduce the unit-power cost in installation, operation, maintenance and transmission. Second, offshore wind energy has received significant attention when the scarcity of land resource has appeared to be a major bottleneck for next level of wind penetration, especially for Europe and Asia. This dissertation study investigates on several wind turbine …

Assessing Trichloromethane Formation And Control In Algal-Stimulated Waters Amended With Nitrogen And Phosphorus, Clinton Mash

Graduate Theses and Dissertations

Nitrogen (N) and phosphorus (P) enrichments can stimulate algal growth in drinking water sources, which can cause increased production of disinfection byproduct (DBP) precursors. However, the effect of systematic N and P enrichments on DBP formation and control has not been adequately studied. In this work, we enriched samples from a drinking water source - sampled on April 5, May 30, and August 19, 2013 - with N and P to stimulate algal growth at N:P ratios covering almost five orders of magnitude (0.2-4,429). To simulate DBP-precursor removal processes at drinking water treatment plants (DWTPs), the samples were treated with …

Assessing The Impact Of Chlorine Residual On Trihalomethane And Haloacetonitrile Formation Under Chlorination And Chloramination Disinfection Regimes, Thien Duc Do

Graduate Theses and Dissertations

A disinfection byproduct (DBP) formation potential (FP) test can be used to indirectly measure the concentration of DBP precursors in natural waters, permitting assessment of various DBP-related treatment processes and control strategies. While these tests require a 7-day chlorine residual (CR) between 3-5 mg L^-1 as Cl², it is not well known if this recommended residual corresponds to the true DBPFP (i.e., the maximum concentrations) for trihalomethanes (THMs) and haloacetonitriles (HANs). In this study, THMs and HANs were quantified as a function of CR under three common disinfection regimes: (1) free chlorine at pH 7.0 (FC7), (2) …

Extracting The Structure And Conformations Of Biological Entities From Large Datasets, Ali Dashti

Theses and Dissertations

In biology, structure determines function, which often proceeds via changes in conformation. Efficient means for determining structure exist, but mapping conformations continue to present a serious challenge. Single-particles approaches, such as cryogenic electron microscopy (cryo-EM) and emerging "diffract & destroy" X-ray techniques are, in principle, ideally positioned to overcome these challenges. But the algorithmic ability to extract information from large heterogeneous datasets consisting of "unsorted" snapshots - each emanating from an unknown orientation of an object in an unknown conformation - remains elusive.

It is the objective of this thesis to describe and validate a powerful suite of manifold-based algorithms …

Design And Development Of A Low-Cost Handheld Picoammeter, Malcolm Stagg

Honors Theses

No abstract provided.

Characterization Techniques And Electrolyte Separator Performance Investigation For All Vanadium Redox Flow Battery, Zhijiang Tang

Doctoral Dissertations

The all-vanadium redox flow battery (VRFB) is an excellent prospect for large scale energy storage in an electricity grid level application. High battery performance has lately been achieved by using a novel cell configuration with advanced materials. However, more work is still required to better understand the reaction kinetics and transport behaviors in the battery to guide battery system optimization and new battery material development. The first part of my work is the characterization of the battery systems with flow-through or flow-by cell configurations. The configuration difference between two cell structures exhibit significantly different polarization behavior. The battery output can …

An Experimental And Computational Evaluation Of The Importance Of Molecular Diffusion In Gas Gravity Currents, Jeremy Jac Herman

Graduate Theses and Dissertations

The accidental release of hazardous, denser-than-air gases during their transport or manufacture is a vital area of study for process safety researchers. This project examines the importance of molecular diffusion on the developing concentration field of a gas gravity current released into a calm environment. Questions which arose from the unexpectedly severe explosion in 2005 at Buncefield, England were of particular interest. The accidental overfilling of a large tank with gasoline on a completely calm morning led to a massive open air explosion. Forensic evidence showed that at the time of ignition, a vapor cloud, most of which now appears …

Tin Sensitization For Electroless Plating, Xingfei Wei

Graduate Theses and Dissertations

The tin sensitization process has been used in electroless plating since 1940s Brenner and Riddell developed the electroless plating for surface metallization method. It was found to be an interesting topic to study tin sensitization for chemically controlling metal deposition on different substrates, because the tin sensitization process had critical effects on the electroless plated metal thin films. Nowadays electroless plating metal deposition is still an important method for depositing metals. It has a few advantages over the vapor deposition and electrodeposition method, such as work in an ambient condition, on nonconductive substrates, and without extra power input. Applying electroless …

Dynamic Queue Management For Hospital Emergency Room Services, Kar Way Tan

Dissertations and Theses Collection (Open Access)

The emergency room (ER) – or emergency department (ED) – is often seen as a place with long waiting times and a lack of doctors to serve the patients. However, it is one of the most important departments in a hospital, and must efficiently serve patients with critical medical needs. In the existing literature, addressing the issue of long waiting times in an ED often takes the form of single-faceted queue-management strategies that are either from a demand perspective or from a supply perspective. From the demand perspective, there is work on queue design such as priority queues, or queue …

Sediment Microbial Fuel Cell As Sustainable Power Resource, Ananta Kothapalli

Theses and Dissertations

This research demonstrates that Ceratophyllum demersum a root less non vascular aquatic plant has negatively affected the power generation from a Sediment Microbial Fuel cell (SMFC). In SMFC the reduced organic matter in the sediment in water produces electrons, which reduces oxygen. Whereas in Plant SMFC continuous supply of organic matter to the anode is done by rhizodeposition (root exudates). Six SMFCs were run for more than 3 months to see the effect of plants, pH and temperature on power generation. Out of six only two SMFC showed stable data. The maximum power density 18 ± 1mW/m3 was generated from …

Applying Computational Methods To Interpret Experimental Results In Tribology And Enantioselective Catalysis, Michael Garvey

Theses and Dissertations

Computational methods are rapidly becoming a mainstay in the field of chemistry. Advances in computational methods (both theory and implementation), increasing availability of computational resources and the advancement of parallel computing are some of the major forces driving this trend.

It is now possible to perform density functional theory (DFT) calculations with chemical accuracy for model systems that can be interrogated experimentally. This allows computational methods to supplement or complement experimental methods. There are even cases where DFT calculations can give insight into processes and interactions that cannot be interrogated directly by current experimental methods.

This work presents several examples …

An Experimental Investigation Characterizing The Tribological Performance Of Natural And Synthetic Biolubricants Composed Of Carboxylic Acids For Energy Conservation And Sustainability, Carlton Jonathan Reeves

Theses and Dissertations

Over the last several decades the lubrication industry has been striving to bring bio-based lubricants known as biolubricants to prominence. The reasons for the increased environmental initiatives are due to depletion of oil reserves, increases in oil price, stringent government regulations on petroleum-based oils, and most importantly, concerns for protecting the environment. With an estimated, 50% of all lubricants entering the environment and much of these being composed of toxic mineral oils, biolubricants have begun to witness a resurgence. This experimental investigation seeks to develop a new class of ecofriendly biolubricants that are less toxic to the environment, derived from …

Microfluidics Guided By Redox-Magnetohydrodynamics (Mhd) For Lab-On-A-Chip Applications, Vishal Sahore

Graduate Theses and Dissertations

Unique microfluidic control actuated by simply turning off and on microfabricated electrodes in a small-volume system was investigated for lab-on-a-chip applications. This was accomplished using a relatively new pumping technique of redox-magnetohydrodynamics (MHD), which as shown in this dissertation generated the important microfluidic features of flat flow profile and fluid circulation. MHD is driven by the body force, FB = j × B, which is the magnetic part of the Lorentz force equation, and its direction is given by the right hand rule. The ionic current density, j, was generated in an equimolar solution of potassium ferri/ferro cyanide by applying …

Molecular Dynamics Model Of Carbon Nanotubes In Epon 862/Detda Polymer, Guttormur Arnar Ingvason

Doctoral Dissertations and Master's Theses

The aerospace industry is interested in increasing the strength while reducing the weight of carbon fiber composite materials. Adding single walled carbon nanotubes (SWCNT) to a polymer matrix can achieve that goal by improving delamination properties of the composite. Due to the complexity of polymer molecules and the curing process, few 3-D Molecular Dynamics simulations of a polymer-SWCNT composite have been run. Our model runs on the Large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS), with a COMPASS (Condensed phase Optimized Molecular Potential for Atomistic Simulations Studies) potential to represent the interactions between the atoms of the polymer and the SWCNT. This …

Extension Of A High-Order Petrov-Galerkin Implementation Applied To Non-Radiating And Radar Cross Section Geometries, William L. Shoemake

Masters Theses and Doctoral Dissertations

Capabilities of a high-order Petrov-Galerkin solver are expanded to include N-port systems. Tait-Bryan angles are employed to launch electro-magnetic waves in arbitrary directions allowing off axis ports to be driven. The transverse-electric (TE) formulation is added allowing waveguide geometries to be driven directly. A grid convergence study is performed on a coax-driven waveguide system. Physical data are matched to a hybrid-T junction (magic-T) electromagnetic waveguide structure to verify the TE driving formulation along with the Tait-Bryan angles and modified post-processing routines. A simple sphere case is used to exercise the radar cross section (RCS) routines and to examine the benefits …

Stabilized Finite Elements For Compressible Turbulent Navier-Stokes, Jon Taylor Erwin

Masters Theses and Doctoral Dissertations

In this research a stabilized finite element approach is utilized in the development of a high-order flow solver for compressible turbulent flows. The Reynolds averaged Navier-Stokes (RANS) equations and modified Spalart-Almaras (SA) turbulence model are discretized using the streamline/upwind Petrov-Galerkin (SUPG) scheme. A fully implicit methodology is used to obtain steady state solutions or to drive unsteady problems at each time step. Order of accuracy is assessed for inviscid and viscous flows in two and three dimensions via the method of manufactured solutions. Proper treatment of curved surface geometries is of vital importance in high-order methods, especially when high aspect …

Validation Of Interpolative Interfaces For Rotorcraft Applications, Adam L. Cofer

Masters Theses and Doctoral Dissertations

The study uses computational methods to simulate fluid flow on the NASA ROBIN helicopter model and on a simplified rotor geometry previously tested at Mississippi State. The ROBIN model and the rotor are run using an unstructured grid. Results from the Tenasi flow solver are compared against both simulated and wind tunnel data. Tenasi is an unstructured, Reynolds Averaged Navier-Stokes (RANS) solver developed at the SimCenter: National Center for Computational Engineering, located at the University of Tennessee at Chattanooga. Steady-state results for the isolated ROBIN fuselage and unsteady results for both fuselage and rotor systems are computed. In the unsteady …

Synthesis Of Ferrocene Copolymers And Investigation Of Their Electrochemical Properties., Alzharani Ahmed

Electronic Theses & Dissertations

Ferrocene is an organometallic compound. It is a classical metallocene consisting of two cyclopentadienyl rings bound on opposite sides of a central iron atom. Such organometallic compounds are also called sandwich compounds. Ferrocene copolymers have well known electrochemical capabilities. The main objective of this thesis is to synthesize vinyl ferrocene copolymers and test their electrochemical properties in aqueous solutions with different electrolytes (sodium nitrate, sodium perchlorate, and phosphate buffered saline). Vinylferrocene and 3-phenyl[5]ferrocenophane-1,5- dimethylene were synthesized using a Wittig reaction. Both ferrocene monomers were copolymerized with N-ethylmaleimide and N-phenylmaleimide and the resulting polymers were analyzed by Gel Permeation chromatography, IR …

Structural Characterization Of Super-Acid Oligomerized Fatty Esters., Esam Allehyani

Electronic Theses & Dissertations

Fatty acid methyl esters can be oligomerized with very strong acid catalysts - superacids such as tetrafluoroboric or triflic acid with formation of dimer and trimer fatty acids at much lower temperature, such as 80-90 °C, than what is used presently. Insight into the reaction of polymerization of fatty esters/ acids can be obtained by structural characterization. This would determine the properties of the oligomeric products and their ability to substitute currently used materials. It was presumed that dimer fatty, trimer fatty acid esters, and oligomeric fatty acid esters are produced by polymerization of fatty acid methyl esters by a …

Attitudes And Behaviors In Online Communities: Empirical Studies Of The Effects Of Social, Community, And Individual Characteristics, Richard Kumi

Graduate Theses and Dissertations

Online communities and communities of practice bring people together to promote and support shared goals and exchange information. Personal interactions are important to many of these communities and one of the important outcomes of personal interactions in online communities and communities of practice is user-generated content. The three essays in the current study examines behavior motivation in online communities and communities of practice to understand how Social and personal psychological factors, and user-generated influence attitudes, intentions and behaviors in online communities.

The first essay addresses two research questions. First, how does Social capital influence exchange and combination behaviors in online …

Monodentate, Bidentate And Photocrosslinkable Thiol Ligands For Improving Aqueous Biocompatible Quantum Dots, Hiroko Takeuchi

Graduate Theses and Dissertations

Water-soluble Quantum Dots (QDs) are highly sensitive fluorescent probes that are often used to study biological species. One of the most common ways to render QDs water-soluble for such applications is to apply hydrophilic thiolated ligands to the QD surface. However, these ligands are labile and can be easily exchanged on the QD surface, which can severely limit their application. As one way to overcome this limitation while maintaining a small colloidal size of QDs, we developed a method to stabilize hydrophilic thiolated ligands on the surface of QDs through the formation of a crosslinked shell using a photocrosslinking approach. …

Formulation Development Of A Polymer-Drug Matrix With A Controlled Release Profile For The Treatment Of Glaucoma, Eric W. Tsoi

Master's Theses

Glaucoma is the leading cause of blindness in the United States accounting for 9-12% of all cases of blindness. Currently, the front line treatment for glaucoma are prostaglandins that may have to be taken up to several times a day. Even with proper treatment, roughly 11% of the patients using the treatment are non-compliant and lose their vision. In this project, ForSight Laboratories has developed a pharmaceutical drug delivering implant with the capability of sustaining long-term release of a prostaglandin as a new way to treat the condition. This project reports the product development of a polymer drug matrix with …

Lipid Production By Microalgae Treating Municipal Wastewater, James Edward Kelley

Master's Theses

Microalgae hold much promise as a feedstock in liquid biofuel production. Lipid content of microalgae cells range from 30-80% dry weight of biomass. It is projected that microalgae can produce between 1,000-6,500 gallons/acre/year of oil. Currently, production of industrial algae operates in open raceway ponds that use minimal capital and energy inputs to culture algae. Raceway ponds can also be used to grow microalgae from municipal waste streams. Although high biomass productivity can be achieved in these systems, there remains a large production gap between large volumes of biomass cultivation and high lipid content from microalgae cells. Low lipid content …

Impacts Of Climate Changes On The Spatiotemporal Distribution Of Precipitation In The Western United States, Peng Jiang

UNLV Theses, Dissertations, Professional Papers, and Capstones

Precipitation in the Intermountain West is characterized by its great variability in both spatial and temporal distributions. Moreover, the spatiotemporal distribution of the precipitation is changing due to the climate changes. In this dissertation, three studies are conducted to investigate the multi-scale temporal variability of precipitation, the performance of current climate models on this variability, the influence of large-scale ocean oscillations on heavy precipitation, and the impact of human induced global warming on storm properties.

The first study is to examine the performance of current climate models on the simulation of the multi-scale temporal variability determined from the observed station …