Physical Sciences and Mathematics Commons^™

High-Resolution, Real-Time Three-Dimensional Shape Measurement, Song Zhang, Peisen S. Huang

Song Zhang

We describe a high-resolution, real-time 3-D shape measurement system based on a digital fringe projection and phase-shifting technique. It utilizes a single-chip digital light processing projector to project computer-generated fringe patterns onto the object, and a high-speed CCD camera synchronized with the projector to acquire the fringe images at a frame rate of 120frames∕s. A color CCD camera is also used to capture images for texture mapping. Based on a three-step phase-shifting technique, each frame of the 3-D shape is reconstructed using three consecutive fringe images. Therefore the 3-D data acquisition speed of the system is 40frames∕s. With this system, …

High-Resolution Mapping In Manus Basin, C. Roman, V. Ferrini

Christopher N. Roman

Near-bottom seafloor mapping with precisely navigated deep submergence vehicles has become increasingly common in a range of oceanographic settings. Recent mapping efforts at deep-water hydrothermal vent sites have resulted in high-resolution (sub-meter) bathymetry datasets that can be used to identify morphological features associated with volcanic, tectonic, and hydrothermal processes. The resolution of these maps, and our ability to accurately quantify the complex morphologic details of hydrothermal structures has been limited by a number of variables including navigational accuracy, sonar settings (e.g. acoustic wavelength, sonar orientation, ping rate), survey parameters (e.g. altitude, speed), data density, and data processing techniques (e.g. gridding …

Towards A New Taxation System For Motor Vehicles, Theodoros Zachariadis

Theodoros Zachariadis

No abstract provided.

Posterminaries: After Nabarro, Alexander H. King

Alexander H. King

With the passing of Frank Nabarro in July of this year, we have lost one of the founding fathers of materials science. His name appears in many of the textbooks from which we train our students today, and also on the spines of several volumes on dislocation theory, including his classic monograph on the subject. He rightly stands among the gods of our field. Ninety years old at his death, he was a sprightly dancer at the frontiers of knowledge, right up to the end.

The Importance Of Emerging Biobased Industries To Engineering And Technology, Kurt A. Rosentrater, R. Balamuralikrishma

Kurt A. Rosentrater

Our society has developed an insatiable demand for energy and material goods. Historically, these needs have been met primarily by fossil fuels and other non-renewable raw materials. As environmental concerns grow, however, renewable resources are gaining increased attention. This paper examines the emergence and importance that biobased industries are increasingly beginning to play. A biobased enterprise, similar in concept to a traditional refinery or factory, utilizes conversion technologies to produce various products. These operations are rapidly increasing both in number as well as in capacity throughout this country, and are poised to add significantly to the nation’s energy and material …

Analytical And Experimental Studies Of Properties Of Ethanol Coproduct-Filled Plastics, Robert Tatara, Andrew Otieno, Srikrishna Suraparaju, Kurt A. Rosentrater

Kurt A. Rosentrater

As the renewable fuels industry continues to grow, the quantity of resulting byproducts has expanded in tandem. Currently, these materials are primarily used for animal feed, but at some point will saturate the animal feeds market. Thus, it is necessary to investigate alternative methods and applications by which these coproducts can be utilized. One potential application for these process residues involves plastics manufacturing. Due, in part, to the increasing cost of resins and conventional fillers, alternate fillers have been increasingly sought. Many of these include biological materials such as grasses, bamboo, starch, chicken feathers, soy protein, and cellulose. Not only …

Analiza Możliwości Ograniczenia Emisji Zanieczyszczeń Powietrza Z Instalacji Spalania Odpadów Medycznych W Tarnowie, Robert Oleniacz

Robert Oleniacz

The paper presents initial research of effects of some factors on the amount of gaseous pollutants formation during medical waste incineration in a two-stage starved air fluidised bed reactor. In the research was included the impact of such factors as oxygen contents in flue gases, frequency of waste loading, momentary mass flow of waste and temperature in the secondary combustion chambers. Measurements showed that the waste incineration in large amount periodically caused excessive emissions incomplete combustion products (CO, HC), especially during wrong operation of the combustion system. The work demonstrated that the essential importance for CO and HC formation reducing …

Anaerobic Catalytic Oxidation Of Hydrocarbons In Moving Heat Waves. Case Simulation: Propane Oxidative Dehydrogenation In A Packed Adiabatic V-Ti Oxide Catalyst Bed, Andrey N. Zagoruiko

Andrey N Zagoruiko

The model simulation study has shown that the anaerobic process of oxidative dehydrogenation of propane under periodic alteration of feeding between propane and air may be realized in adiabatic catalyst beds in stable continuous cyclic mode in two-reactor scheme. In case of appropriate choice of process parameters (cycle duration, feeding flow rates) the process appears to be autothermal, i.e. it does not require any inlet gas preheating for stable operation. Compared to similar steady-state adiabatic process, the proposed process is characterized with much lower maximum catalyst temperatures, giving the way to process pure propane without diluting it with inert gases, …

Phase Field Theory Of Surface- And Size-Induced Microstructures, Valery I. Levitas, D.W. Lee, D. L. Preston

Valery I. Levitas

New surface- and size-induced microstructures are found as analytic solutions to a phase field theory of first-order phase transformations. A recently developed exact stability criterion, based on most destabilizing fluctuations, is used to analyze the stability and physical interpretation of each microstructure. Conditions for barrierless surface nucleation, i.e. relationship between surface energy, driving force for the transformation and sample size, are found. If they are met, some of these microstructures are destroyed resulting in the barrierless transformation to alternative phases.

Semicrystalline Thermoplastic Elastomeric Polyolefins: Advances Through Catalyst Development And Macromolecular Design, Atsushi Hotta, Eric W. Cochran, Janne Ruokolainen, Vikram Khann, Glenn H. Fredrickson, Edward J. Kramer, Yong-Woo Shin, Fumihiko Shimizu, Anna E. Cherian, Phillip D. Hustad, Jeffrey M. Rose, Geoffrey W. Coates

Eric W. Cochran

We report the design, synthesis, morphology, phase behavior, and mechanical properties of semicrystalline, polyolefin-based block copolymers. By using living, stereoselective insertion polymerization catalysts, syndiotactic polypropylene-block-poly(ethylene-co-propylene)-block-syndiotactic polypropylene and isotactic poly propylene-block-regioirregular poly propylene-block- isotactic polypropylene triblock copolymers were synthesized. The volume fraction and composition of the blocks, as well as the overall size of the macromolecules, were controlled by sequential synthesis of each block of the polymers. These triblock copolymers, with semicrystalline end-blocks and mid-segments with low glass-transition temperatures, show significant potential as thermoplastic elastomers. They have low Young's moduli, large strains at break, and better than 90% elastic recovery at …

Hydrogen And Deuterium Exchange On Pt(111) And Its Poisoning By Carbon Monoxide Studied By Surface Sensitive High-Pressure Techniques, Max Montano, Kaitlin M. Bratlie, Miquel Salmeron, Gabor A. Somorjai

Kaitlin M. Bratlie

Catalytic hydrogen/deuterium exchange on a platinum (111) single crystal and its poisoning with carbon monoxide was studied using scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy (XPS), sum frequency generation vibrational spectroscopy (SFG), and mass spectrometry under reaction conditions at pressures in the mTorr to atmospheric range. At 298 K and in the presence of 200 mTorr of hydrogen and 20 mTorr of deuterium the surface is catalytically active, producing HD with activation energy of 5.3 kcal/mol. Addition of 5 mTorr of CO stops the reaction completely. In situ STM images reveal an ordered surface structure of chemisorbed CO. At 353 …

Sum Frequency Generation Vibrational Spectroscopic And High-Pressure Scanning Tunneling Microscopic Studies Of Benzene Hydrogenation On Pt(111), Kaitlin M. Bratlie, Max O. Montano, Lucio D. Flores, Matti Paajanen, Gabor A. Somorjai

Kaitlin M. Bratlie

Sum frequency generation (SFG) vibrational spectroscopy and high-pressure scanning tunneling microscopy (HP-STM) have been used in combination for the first time to study a catalytic reaction. These techniques have been able to identify surface intermediates in situ during benzene hydrogenation on a Pt(111) single-crystal surface at Torr pressures.

Emisja Zanieczyszczeń Powietrza Z Procesu Grafityzacji Wyrobów Drobnych, Marian Mazur, Robert Oleniacz, Marek Bogacki, Przemysław Szczygłowski

Robert Oleniacz

The paper presents the research results of the air pollutant emissions from the graphitising process of fine carbon products in the Acheson furnace (discharge capacity 5,5 Mg). Research was performed for two kinds of raw material inputs (based on petroleum coke and pitch coke). Approximately 40-hours measurement series were carried out for each material including mainly such substances like carbon monoxide, hydrocarbons, nitrogen oxides, sulphur dioxide, hydrogen sulphide, carbon disulphide, ammonia, benzene, toluene, xylenes, total dust, tar substances and polycyclic aromatic hydrocarbons. Both average and maximum concentrations and mass streams in the flue gases and average emission factors were presented …

Comment On “Structural Stability Of Complex Hydrides: Libh4 Revisited”, Duane D. Johnson, Nikolai A. Zarkevich

Duane D. Johnson

A Comment on the Letter by Zbigniew Łodziana and Tejs Vegge, Phys. Rev. Lett. 93, 145501 (2004).

Structure Effects Of Benzene Hydrogenation Studied With Sum Frequency Generation Vibrational Spectroscopy And Kinetics On Pt(111) And Pt(100) Single-Crystal Surfaces, Kaitlin M. Bratlie, Christopher J. Kliewer, Gabor A. Somorjai

Kaitlin M. Bratlie

Sum frequency generation (SFG) surface vibrational spectroscopy and kinetic measurements using gas chromatography have identified at least two reaction pathways for benzene hydrogenation on the Pt(100) and Pt(111) single-crystal surfaces at Torr pressures. Kinetic studies at low temperatures (310-370 K) show that benzene hydrogenation does not proceed through cyclohexene. A Langmuir-Hinshelwood-type rate law for the low-temperature reaction pathway is identified. The rate-determining step for this pathway is the addition of the first hydrogen atom to adsorbed benzene for both single-crystal surfaces, which is verified by the spectroscopic observation of adsorbed benzene at low temperatures on both the Pt(100) and Pt(111) …

Posterminaries: The Scales Of Judgement, Alexander H. King

Alexander H. King

Materials scientists are generally well-versed in physics, and physics, above all, is a science of measurements. The first instinct of a physicist is to parse a problem in terms of its measurables in the dimensions of mass, length, and time, and it is the shifting of attention down the scale of length that particularly characterizes our present times as the Nano Age.

Novel Method For Structured Light System Calibration, Song Zhang, Peisen S. Huang

Song Zhang

System calibration, which usually involves complicated and time-consuming procedures, is crucial for any 3-D shape measurement system. In this work, a novel systematic method is proposed for accurate and quick calibration of a 3-D shape measurement system we developed based on a structured light technique. The key concept is to enable the projector to “capture” images like a camera, thus making the calibration of a projector the same as that of a camera. With this new concept, the calibration of structured light systems becomes essentially the same as the calibration of traditional stereovision systems, which is well established. The calibration …

Oxidative Carbonylation And Conjugated Processes With Carbon Monoxide Participation Catalyzed By Palladium Complexes (In Russian), Lev G. Bruk, Irina V. Oshanina, Sergey N. Gorodsky, Oleg N. Temkin

Sergey N. Gorodsky

No abstract provided.

Generic Nonsinusoidal Phase Error Correction For 3d Shape Measurement Using A Digital Video Projector, Song Zhang, Shing-Tung Yau

Song Zhang

Structured light system using a digital video projector is increasingly used for a 3-D shape measurement because of its digital nature. However, the nonlinear gamma of the projector causes the projected fringe patterns to be non-sinusoidal, which results in phase error therefore shape measurement error. Previous work showed that, by using a small look-up-table (LUT), this type of phase error can be reduced significantly for a three-step phase-shifting algorithm. In this research, we prove that this type of phase error compensation method is not limited to a three-step phase-shifting algorithm. It is generic for any phase-shifting algorithm. The phase error …

High-Resolution Real-Time 3d Absolute Coordinates Measurement Using A Fast Three-Step Phase-Shifting Algorithm, Song Zhang, Dale Royer, Shing-Tung Yau

Song Zhang

High-resolution, real-time 3-D absolute coordinate measurement is highly important in many fields. This paper presents such a system that measures 3-D absolute geometric shapes and positions at 30 frames per second (fps), with an image resolution of 532 × 500. The system is based on a digital fringe projection and fast three-step phase-shifting method. It utilizes a digital-light-processing (DLP) projector to project color encoded computer generated phase-shifted fringe patterns in grayscale, a high-speed CCD camera synchronized with the projector to capture fringe images at 90 fps. Based on the three-step phase-shifting algorithm, any successive three fringe images can be used …

Precision And Accuracy Of Thermal Calibration Of Atomic Force Microscopy Cantilevers, Nancy Burnham, G Matei, E Thoreson, J Pratt, D Newell

Nancy A. Burnham

To have confidence in force measurements made with atomic force microscopes(AFMs), the spring constant of the AFM cantilevers should be known with good precision and accuracy, a topic not yet thoroughly treated in the literature. In this study, we compared the stiffnesses of uncoated tipless uniform rectangular silicon cantilevers among thermal, loading, and geometric calibration methods; loading was done against an artifact from the National Institute of Standards and Technology (NIST). The artifact was calibrated at NIST using forces that were traceable to the International System of units. The precision and accuracy of the thermal method were found to be …

Ginzburg-Landau Theory Of Microstructures: Stability, Transient Dynamics, And Functionally Graded Nanophases, Valery I. Levitas, D. L. Preston, Dong Wook Lee

Valery I. Levitas

The stability, transient dynamics, and physical interpretation of microstructures obtained from a Ginzburg-Landau theory of first-order phase transformations are studied. The Jacobi condition for stability fails numerically, thus an alternative exact stability criterion, based on critical (most destabilizing) fluctuations, is developed. The degree-of-stability parameter is introduced to quantify the physical stability of long-lived unstable microstructures. For nanofilms, the existence of functionally graded nanophases is demonstrated. Numerical simulations indicate that graded nanophases can be produced by dissolving material from both surfaces of a nanofilm. Stability under finite fluctuations and post-bifurcation microstructure evolution are investigated numerically.

Partitioning Of E. Coli And Enterococci Between Planktonic And Sorbed Phases In Runoff From Pasturelands, Michelle L. Soupir, H. E. Saied Mostaghimi, Elizabeth F. Alphin

Michelle L. Soupir

Pathogens are the leading cause of surface water impairments in Virginia. Currently, Nonpoint Source (NPS) pollution models are most frequently used to determine the maximum allowable loading rates of bacteria from identified sources and they typically simulate bacterial transport to surface waters as a planktonic or free pollutant. Very few models attempt to partition between the planktonic and attached phases primarily because data on bacteria partitioning during overland flow events are currently not available. A field study was conducted to evaluate the partitioning of E. coli and enterococci between the planktonic and attached phases in runoff from pasturelands and to …

The Global Relevance Of Bio-Based Industries To Engineering And Technology Education, Kurt A. Rosentrater, Radha Balamuralikrishma

Kurt A. Rosentrater

The society in which we live has developed an insatiable demand for energy and material goods. In particular, recent data reveals that the aggressive pursuit of improved standards of living in the highly populated countries of India and China has contributed to increased demand for fossil fuels, which has exacerbated the recent spike in energy costs. Historically, these needs have been met primarily by fossil fuels and other non-renewable raw materials. As environmental concerns grow, however, renewable resources are gaining increased attention. This paper examines the emergence and importance that bio-based industries are increasingly beginning to play. A bio-based enterprise, …

Biorefining Of Renewable Resources—Emerging Opportunities For Engineering Education, Kurt A. Rosentrater

Kurt A. Rosentrater

The society in which we live has developed an insatiable demand for energy and material goods. Historically these needs have primarily been met by utilizing fossil fuels and other nonrenewable raw materials. As environmental concerns grow, however, renewable resources are gaining increased attention. This paper examines industrial biorefineries, which are at the leading edge of the development of emerging biobased industries. Biorefineries, similar in concept to traditional petroleum refineries, utilize various conversion technologies to produce multiple products, including fuels, chemicals, industrial products, and electrical power from renewable biomass sources, such as corn stover, residue straw, perennial grasses, legumes, and other …

Dynamics Of Surface Catalyzed Reactions; The Roles Of Surface Defects, Surface Diffusion, And Hot Electrons, Gabor Somorjai, Kaitlin Bratlie, Max Montano, Jeong Park

Kaitlin M. Bratlie

The mechanism that controls bond breaking at transition metal surfaces has been studied with sum frequency generation (SFG), scanning tunneling microscopy (STM), and catalytic nanodiodes operating under the highpressure conditions. The combination of these techniques permits us to understand the role of surface defects, surface diffusion, and hot electrons in dynamics of surface catalyzed reactions. Sum frequency generation vibrational spectroscopy and kinetic measurements were performed under 1.5 Torr of cyclohexene hydrogenation/dehydrogenation in the presence and absence of H2 and over the temperature range 300-500 K on the Pt(100) and Pt(111) surfaces. The structure specificity of the Pt(100) and Pt(111) surfaces …

Pomiary Wielkości Cząstek W Powietrzu W Czasie Rzeczywistym, Marek Bogacki, Robert Oleniacz, Marian Mazur, Stanisław Kamiński

Robert Oleniacz

The paper presents the new method for measurements of air particulate size distribution in real time using Kamika Infrared Particulate Sizer type P (IPS-P) with isokinetic air sampler. The device makes it possible to classify (sort) air particulates according to size into 256 granularity classes from about 0.4 µm up to 300 µm. Tests of the IPS-P prototype were conducted in Warsaw at the turn of 2005/2006 and some measurement results were presented in the work.

English title: Measurements of the particulate size distribution in the air in real-time.

Pre-Disaster Planning And Mitigation And Its Impact On Comprehensive Emergency Management And The Nation: Pre-Disaster Mitigation (Pdm) Program And The Population Protected, Thomas Lyons Carr Iii

Thomas Lyons (Thom) Carr III Appl.Sc., CEM

A Project for a Professional Degree submitted to The Faculty of School of Engineering and Applied Science of The George Washington University in partial fulfillment of the requirements for the degree of Applied Scientist of Engineering Management May 21, 2006

On October 10, 2000, The Disaster Mitigation Act of 2000 (DMA 2000 or DMA 2K) (Public Law 106-390) was enacted, amending the Robert T. Stafford Relief and Emergency Assistance Act and established new requirements for the national for hazard mitigation planning. States, Tribes, territories, and local governments now must have an approved mitigation plan in place prior to receiving certain …

Selective Catalytic Oxidation Of Hydrogen Sulfide For Cleanup Of Claus Tail Gases: Startup Of Industrial Installation At Omsk Refinery, Andrey N. Zagoruiko, Vladimir V. Mokrinskii, Nataly A. Chumakova, Galina A. Bukhtiarova, Sergey V. Vanag, Tatiana V. Borisova, Galina G. Isaeva, Boris G. Kozorog

Andrey N Zagoruiko

The presentation describes the experience of development and commercialization of the catalyst and the process for selective oxidation of H2S into sulfur, which was put into industrial operation at Omsk Refinery (Omsk, Russia) in 2004.

In Situ Sum Frequency Generation Vibrational Spectroscopy Observation Of A Reactive Surface Intermediate During High-Pressure Benzene Hydrogenation, Kaitlin M. Bratlie, Lucio D. Flores, Gabor A. Somorjai

Kaitlin M. Bratlie

Sum frequency generation surface vibrational spectroscopy and kinetic measurements using gas chromatography have been used to identify a reactive surface intermediate in situ during hydrogenation of benzene on a Pt(111) single crystal surface at Torr pressures. Upon adsorption at 310 K, both chemisorbed and physisorbed benzene coexist on the surface, a result which has not previously been observed. Kinetic measurements show a linear compensation effect for the production of both cyclohexane and cyclohexene. From these data the isokinetic temperature was identified and correlated to the chemisorbed benzene species, which were probed by means of vibrational spectroscopy. Additionally, chemisorbed benzene was …