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Physical Sciences and Mathematics Commons

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Engineering

Journal

1997

Catalytic reaction

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Full-Text Articles in Physical Sciences and Mathematics

Study On Electrochemical Methods Of Controlled Convolution ——A Simple Electron Transfer Reaction Followed By A Homogeneous Catalytic Reaction(Ⅰ), Ming Ma, Naixian Xie, Qianlei Gao, Yue Zeng Aug 1997

Study On Electrochemical Methods Of Controlled Convolution ——A Simple Electron Transfer Reaction Followed By A Homogeneous Catalytic Reaction(Ⅰ), Ming Ma, Naixian Xie, Qianlei Gao, Yue Zeng

Journal of Electrochemistry

A simple electron transfer reaction followed by a homogeneous catalytic reaction is studied in this paper by three kinds of controlled convolution electrochemical experimental methods, which are the constant semi integral (CSI), linear semi integral sweep (LSIS) and linear semi differential sweep (LSDS). According to the three methods, the following equations can be obtained: CSI: πmΨ iI 1(τ)-1=ξe θ LSIS: π2bI 2(τ)-1=ξe θ LSDS: 3π8dI 3(τ)-1=ξe θ Where mΨ i=m i/nFAD 1/2 oC * o, b=D 1/2 ov/nFAk 02 C * o, d=cD 3/2 o/nFAk 04 C * o, m i, v and c are constant value of semi integral, …