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Engineering

UNLV Theses, Dissertations, Professional Papers, and Capstones

Hydrogen production

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Full-Text Articles in Physical Sciences and Mathematics

Chemical And Electronic Surface Structure Of Chalcopyrite-Based Thin Films For Solar Water Splitting, James C. Carter May 2020

Chemical And Electronic Surface Structure Of Chalcopyrite-Based Thin Films For Solar Water Splitting, James C. Carter

UNLV Theses, Dissertations, Professional Papers, and Capstones

In recent years, various thin film solar devices have reached markedly high efficiencies on both the laboratory and large area scale. To further evaluate their potential, and help drive device optimization of efficient solar devices, a detailed understanding of the chemical and electronic structure of the surfaces and interfaces is required. It is these interfaces that play a pivotal role in dictating aspects of device performance. Chalcopyrite-based materials, such as Cu(In,Ga)S2 (CIGS) are regarded as one of the most promising absorber materials for use in highly efficient solar devices. In the context of photoelectrochemical (PEC) hydrogen generation, the tunability of …


Experimental And Numerical Study Of A Proton Exchange Membrane Electrolyzer For Hydrogen Production, Sachin S. Deshmukh Jan 2009

Experimental And Numerical Study Of A Proton Exchange Membrane Electrolyzer For Hydrogen Production, Sachin S. Deshmukh

UNLV Theses, Dissertations, Professional Papers, and Capstones

Hydrogen as a fuel source has received attention from researchers globally due to its potential to replace fossil based fuels for energy production. Research is being performed on hydrogen production, storage and utilization methods to make its use economically feasible relative to current energy sources. The PEM electrolyzer is used to produce hydrogen and oxygen using water and electricity. Focus of our study is to provide a benchmark experiment and numerical model of a single cell electrolyzer that can assist in improving the current state of understanding of this system. Parametric analysis of an experimental cell was performed to understand …


Study Of Corrosion Of Materials In The Sulfur-Iodine Hydrogen Production Cycle, Thao Trung Ho Jan 2009

Study Of Corrosion Of Materials In The Sulfur-Iodine Hydrogen Production Cycle, Thao Trung Ho

UNLV Theses, Dissertations, Professional Papers, and Capstones

Hydrogen is of great interest since the availability of traditional fossil fuels is in decline. Strictly speaking, hydrogen is not a primary source of energy but is an energy carrier, since energy typically must be used from another source (electricity, natural gas, coal, etc.) to produce it. Of hydrogen production techniques, the Sulfur-Iodine thermochemical water splitting process (S-I cycle), which was proposed by General Atomics (GA), is promising with its simplicity and high efficiency. Most of the chemicals are recycled except water. However, the S-I cycle operates in a harsh, corrosive environment in the presence of a mixture of iodine …