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Full-Text Articles in Physical Sciences and Mathematics

Adsorption And Reconfiguration Of Amphiphiles At Silica-Water Interfaces: Role Of Electrostatic Interactions, Van Der Waals Forces And Hydrogen Bonds, Yao Wu Nov 2020

Adsorption And Reconfiguration Of Amphiphiles At Silica-Water Interfaces: Role Of Electrostatic Interactions, Van Der Waals Forces And Hydrogen Bonds, Yao Wu

LSU Doctoral Dissertations

The ability to explore and predict metastable structures of hybrid self-assemblies is of central importance for the next generation of advanced materials with novel properties. As compared to their thermodynamically stable forms, the kinetically stabilized materials show improved functionality potentially over their stable counterparts. The self-assembly processes usually originate from weak intermolecular interactions, involving a dynamic competition between attractive and repulsive interactions. These weak forces, including van der Waals (vdW), electrostatic interaction and the hydrogen bonding (H-bonding), can be tuned by external stimuli, e.g., confinement, temperature and ionization, and consequently driving hybrid materials into different configurations. It is challenging to …


Using Spatial Analysis And Machine Learning Techniques To Develop A Comprehensive Highway-Rail Grade Crossing Consolidation Model, Samira Soleimani Oct 2020

Using Spatial Analysis And Machine Learning Techniques To Develop A Comprehensive Highway-Rail Grade Crossing Consolidation Model, Samira Soleimani

LSU Doctoral Dissertations

The safety of highway-railroad grade crossings (HRGC) is still an issue in the United States of America (USA). The grade crossing is where a railroad crosses a road at the same level without any over or underpass. To improve the safety of crossings, the crossings’ condition should be explored from several aspects such as engineering design (speed limit, warning signs, etc.), road condition (number of lanes, surface markings, etc.), rail design (the type of track, ballast, etc.), temporal variables (weather, visibility, time of day, lightning, etc.), social variables (population, race, etc.), and last but not least, spatial variables (the type …


Evolution Of Computational Thinking Contextualized In A Teacher-Student Collaborative Learning Environment., John Arthur Underwood May 2020

Evolution Of Computational Thinking Contextualized In A Teacher-Student Collaborative Learning Environment., John Arthur Underwood

LSU Doctoral Dissertations

The discussion of Computational Thinking as a pedagogical concept is now essential as it has found itself integrated into the core science disciplines with its inclusion in all of the Next Generation Science Standards (NGSS, 2018). The need for a practical and functional definition for teacher practitioners is a driving point for many recent research endeavors. Across the United States school systems are currently seeking new methods for expanding their students’ ability to analytically think and to employee real-world problem-solving strategies (Hopson, Simms, and Knezek, 2001). The need for STEM trained individuals crosses both the vocational certified and college degreed …


Physical And Biological Factors Controlling The Fate Of Nitrate In A Louisiana Coastal Deltaic Floodplain, Alexandra Christensen Apr 2020

Physical And Biological Factors Controlling The Fate Of Nitrate In A Louisiana Coastal Deltaic Floodplain, Alexandra Christensen

LSU Doctoral Dissertations

The Mississippi River Delta is threatened by a growing pressure to support large human populations in the United States both with food production, navigation systems, and urban development in the Mississippi River Basin. Nitrate-nitrogen load in the Mississippi River, up to 100 Tg N yr-1 from agricultural and urban runoff, leads to phytoplankton blooms and hypoxia across the Louisiana continental shelf, creating dead zones of low dissolved oxygen threatening a significant commercial fishery. Along the coast and river corridors, floodplain ecosystems have the capacity to retain and remove nitrate. This dissertation explores the role of productive, actively growing coastal …


The Long-Term Outlook Of The Mississippi-Atchafalaya Bifurcation: A Convergence Of Engineering, Economics, And Deltaic Evolution, Thomas Mitchell Andrus Apr 2020

The Long-Term Outlook Of The Mississippi-Atchafalaya Bifurcation: A Convergence Of Engineering, Economics, And Deltaic Evolution, Thomas Mitchell Andrus

LSU Doctoral Dissertations

The most recent and currently active delta lobe of the Mississippi River (MR) is the Atchafalaya-Wax Lake lobe, which was initiated approximately 400 years ago as a result of MR stream capture by the Atchafalaya River (AR). This capture process accelerated in the early to mid-1900s but further progress was prevented by construction and operation of the Old River Control Structure (ORCS) Complex. Many recent studies indicate that MR system below the ORCS is on a retreating geologic trajectory due to contributing factors such as sea level rise, subsidence, faulting, and declining hydraulic stream power. Diversions along the Lower MR …