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X-Ray Absorption Spectroscopy Study Of The Effect Of Rh Doping In Sr2Iro4, C. H. Sohn, Deok-Yong Cho, C. -T. Kuo, L. J. Sandilands, Tongfei Qi, Gang Cao, T. W. Noh

Center for Advanced Materials Faculty Publications

We investigate the effect of Rh doping in Sr₂IrO₄ using X-ray absorption spectroscopy (XAS). We observed appearance of new electron-addition states with increasing Rh concentration (x in Sr₂Ir_1−xRh_xO₄) in accordance with the concept of hole doping. The intensity of the hole-induced state is however weak, suggesting weakness of charge transfer (CT) effect and Mott insulating ground states. Also, Ir J_eff = 1/2 upper Hubbard band shifts to lower energy as x increases up to x = 0.23. Combined with optical spectroscopy, these results suggest a hybridisation-related mechanism, in …