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Physical Sciences and Mathematics Commons

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Engineering

Selected Works

Shi Xue Dou

2014

Composites

Articles 1 - 4 of 4

Full-Text Articles in Physical Sciences and Mathematics

Thermoelectric Performance Of N-Type (Pbte)0.75(Pbs)0.15(Pbse)0.1 Composites, Sima Aminorroaya Yamini, Heng Wang, Dianta Ginting, David R. G Mitchell, S X. Dou, G. Jeffrey Snyder Oct 2014

Thermoelectric Performance Of N-Type (Pbte)0.75(Pbs)0.15(Pbse)0.1 Composites, Sima Aminorroaya Yamini, Heng Wang, Dianta Ginting, David R. G Mitchell, S X. Dou, G. Jeffrey Snyder

Shi Xue Dou

Lead chalcogenides (PbQ, Q = Te, Se, S) have proved to possess high thermoelectric efficiency for both n-type and p-type compounds. Recent success in tuning of electronic band structure, including manipulating the band gap, multiple bands, or introducing resonant states, has led to a significant improvement in the thermoelectric performance of p-type lead chalcogenides compared to the n-type ones. Here, the n-type quaternary composites of (PbTe)0.75(PbS)0.15(PbSe)0.1 are studied to evaluate the effects of nanostructuring on lattice thermal conductivity, carrier mobility, and effective mass variation. The results are compared with the similar ternary systems of (PbTe)1-x(PbSe)x, (PbSe) 1-x(PbS)x, and (PbS)1-x(PbTe)x. The …


Thermoelectric Performance Of Tellurium-Reduced Quaternary P-Type Lead-Chalcogenide Composites, Sima Aminorroaya Yamini, Heng Wang, Zachary M. Gibbs, Yanzhong Pei, David R. G Mitchell, S X. Dou, G. Jeffrey Snyder Oct 2014

Thermoelectric Performance Of Tellurium-Reduced Quaternary P-Type Lead-Chalcogenide Composites, Sima Aminorroaya Yamini, Heng Wang, Zachary M. Gibbs, Yanzhong Pei, David R. G Mitchell, S X. Dou, G. Jeffrey Snyder

Shi Xue Dou

A long-standing technological challenge to the widespread application of thermoelectric generators is obtaining high-performance thermoelectric materials from abundant elements. Intensive study on PbTe alloys has resulted in a high figure of merit for the single-phase ternary PbTe-PbSe system through band structure engineering, and the low thermal conductivity achieved due to nanostructuring leads to high thermoelectric performance for ternary PbTe-PbS compounds. Recently, the single-phase p-type quaternary PbTe-PbSe-PbS alloys have been shown to provide thermoelectric performance superior to the binary and ternary lead chalcogenides. This occurs via tuning of the band structure and from an extraordinary low thermal conductivity resulting from high-contrast …


High-Performance Sodium-Ion Batteries And Sodium-Ion Pseudocapacitors Based On Mos2/Graphene Composites, Yunxiao Wang, Shulei Chou, David Wexler, Hua-Kun Liu, S X. Dou Oct 2014

High-Performance Sodium-Ion Batteries And Sodium-Ion Pseudocapacitors Based On Mos2/Graphene Composites, Yunxiao Wang, Shulei Chou, David Wexler, Hua-Kun Liu, S X. Dou

Shi Xue Dou

Sodium-ion energy storage, including sodium-ion batteries (NIBs) and electrochemical capacitive storage (NICs), is considered as a promising alternative to lithium-ion energy storage. It is an intriguing prospect, especially for large-scale applications, owing to its low cost and abundance. MoS2 sodiation/desodiation with Na ions is based on the conversion reaction, which is not only able to deliver higher capacity than the intercalation reaction, but can also be applied in capacitive storage owing to its typically sloping charge/discharge curves. Here, NIBs and NICs based on a graphene composite (MoS2/G) were constructed. The enlarged d-spacing, a contribution of the graphene matrix, and the …


A Facile Route To Synthesize Transition Metal Oxide/Reduced Graphene Oxide Composites And Their Lithium Storage Performance, Chongjun Zhao, Shulei Chou, Yunxiao Wang, Cuifeng Zhou, Hua-Kun Liu, S X. Dou Mar 2014

A Facile Route To Synthesize Transition Metal Oxide/Reduced Graphene Oxide Composites And Their Lithium Storage Performance, Chongjun Zhao, Shulei Chou, Yunxiao Wang, Cuifeng Zhou, Hua-Kun Liu, S X. Dou

Shi Xue Dou

Transition metal oxide (Mn3O4, Fe2O3, Co3O4, and ZnO) and reduced graphene oxide (RGO) composites were successfully synthesized via a hydrothermal method using the direct reaction between the corresponding metal powder and graphene oxide (GO). In this process, the GO can be reduced by transition metal powder in water, and the nanosized metal oxide can be obtained, and homogeneously mixed with and wrapped by RGO to form a metal oxide/RGO composite at the same time. X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, and scanning and transmission electron microscopy were used to characterize the as-prepared materials. The different experimental parameters, including reactants, …