Physical Sciences and Mathematics Commons^™

Investigating Gulf Coast Aquifer System: Stratigraphy Reconstruction, Inverse Modeling, And Groundwater Stress Assessment, Shuo Yang

LSU Doctoral Dissertations

The Mississippi Embayment aquifer system (MEAS) and the Coastal Lowlands aquifer system (CLAS) provide substantial groundwater resources for human activities in the U.S. Gulf Coastal Plain. However, the overexploitation has led to groundwater depletion in the MEAS and the CLAS, threatening sustainable groundwater use. Such concern highlights the crucial need for an advanced understanding of stratigraphy and groundwater in these aquifer systems, which is essential for effective regional groundwater management. This dissertation presents a comprehensive investigation of MEAS and CLAS in the Louisiana and southwestern Mississippi region, encompassing three fundamental dimensions: stratigraphy reconstruction, groundwater modeling, and groundwater stress assessments. A …

Domain Specific Analysis Of Privacy Practices And Concerns In The Mobile Application Market, Fahimeh Ebrahimi Meymand

LSU Doctoral Dissertations

Mobile applications (apps) constantly demand access to sensitive user information in exchange for more personalized services. These-mostly unjustified-data collection tactics have raised major privacy concerns among mobile app users. Existing research on mobile app privacy aims to identify these concerns, expose apps with malicious data collection practices, assess the quality of apps' privacy policies, and propose automated solutions for privacy leak detection and prevention. However, existing solutions are generic, frequently missing the contextual characteristics of different application domains. To address these limitations, in this dissertation, we study privacy in the app store at a domain level. Our objective is to …

Application Of Distributed Fiber-Optic Sensing For Pressure Predictions And Multiphase Flow Characterization, Gerald Kelechi Ekechukwu

LSU Doctoral Dissertations

In the oil and gas industry, distributed fiber optics sensing (DFOS) has the potential to revolutionize well and reservoir surveillance applications. Using fiber optic sensors is becoming increasingly common because of its chemically passive and non-magnetic interference properties, the possibility of flexible installations that could be behind the casing, on the tubing, or run on wireline, as well as the potential for densely distributed measurements along the entire length of the fiber. The main objectives of my research are to develop and demonstrate novel signal processing and machine learning computational techniques and workflows on DFOS data for a variety of …

Compilation Optimizations To Enhance Resilience Of Big Data Programs And Quantum Processors, Travis D. Lecompte

LSU Doctoral Dissertations

Modern computers can experience a variety of transient errors due to the surrounding environment, known as soft faults. Although the frequency of these faults is low enough to not be noticeable on personal computers, they become a considerable concern during large-scale distributed computations or systems in more vulnerable environments like satellites. These faults occur as a bit flip of some value in a register, operation, or memory during execution. They surface as either program crashes, hangs, or silent data corruption (SDC), each of which can waste time, money, and resources. Hardware methods, such as shielding or error correcting memory (ECM), …

Sers Platform For Single Fiber Endoscopic Probes, Debsmita Biswas

LSU Doctoral Dissertations

Molecular detection techniques have huge potential in clinical environments. In addition to many other molecular detection techniques, endoscopic Raman spectroscopy has great ability in terms of minimal invasiveness and real-time spectra acquisition. However, Raman Effect is low in sensitivity, limiting the application. Surface-Enhanced Raman Scattering (SERS), addresses this limitation. SERS brings rough nano-metallic surfaces in contact with specimen molecules which enormously enhances Raman signals. This provides Raman spectroscopy with immense capabilities for diverse fields of applications.

Generally, in clinical probe applications, the spectrometer is brought near the target molecules for detection. Typically, optical fibers are used to couple spectrometers to …

Characterization Of Electrophoretic Deposited Zinc Oxide Nanopartices For The Fabrication Of Next-Generation Nanoscale Electronic Applications, Fawwaz Abduh A. Hazzazi

LSU Doctoral Dissertations

Several reports state that it is crucial to analyze nanoscale semiconductor materials and devices with potential benefits to meet the need for next-generation nanoelectronics, bio, and nanosensors. The progress in the electronics field is as significant now, with modern technology constantly evolving and a greater focus on more efficient robust optoelectronic applications. This dissertation focuses on the study and examination of the practicality of Electrophoretic Deposition (EPD) of zinc oxide (ZnO) nanoparticles (NPs) for use in semiconductor applications.

The feasibility of several synthesized electrolytes, with and without surfactants and APTES surface functionalization, is discussed. The primary objective of this study …

Efficient Low Dimensional Representation Of Vector Gaussian Distributions, Md Mahmudul Hasan

LSU Doctoral Dissertations

This dissertation seeks to find optimal graphical tree model for low dimensional representation of vector Gaussian distributions. For a special case we assumed that the population co-variance matrix $\Sigma_x$ has an additional latent graphical constraint, namely, a latent star topology. We have found the Constrained Minimum Determinant Factor Analysis (CMDFA) and Constrained Minimum Trace Factor Analysis (CMTFA) decompositions of this special $\Sigma_x$ in connection with the operational meanings of the respective solutions. Characterizing the CMDFA solution of special $\Sigma_x$, according to the second interpretation of Wyner's common information, is equivalent to solving the source coding problem of finding the minimum …

Practical Considerations And Applications For Autonomous Robot Swarms, Rory Alan Hector

LSU Doctoral Dissertations

In recent years, the study of autonomous entities such as unmanned vehicles has begun to revolutionize both military and civilian devices. One important research focus of autonomous entities has been coordination problems for autonomous robot swarms. Traditionally, robot models are used for algorithms that account for the minimum specifications needed to operate the swarm. However, these theoretical models also gloss over important practical details. Some of these details, such as time, have been considered before (as epochs of execution). In this dissertation, we examine these details in the context of several problems and introduce new performance measures to capture practical …

Synthesis Of Thiol-Acrylate Hydrogels For 3d Cell Culture And Microfluidic Applications, Anowar Hossain Khan

LSU Doctoral Dissertations

Globally cell culture is an $18.98 billion industry as of 2020, with an 11.6 percent annual growth rate. Drug discovery has an estimated worth of $69.8 billion in 2020 and is predicted to grow to $110.4 billion by 2025. Three-dimensional (3D) cell culture of cancer cells is one of the rapidly growing felids since it better recapitulates in vivo conditions compared to two-dimensional (2D) models. However, it is challenging to grow 3D tumor spheroids outside the body, and some of the existing technology can generate these spheroids outside the human body but poorly mimic in vivo tumor models. Therefore, there …

Computational Study Of The Reactions Of Heteroatomic Compounds On Ceo2, Suman Bhasker Ranganath

LSU Doctoral Dissertations

The mechanisms of ambient-temperature reactions of heteroatomic compounds catalyzed by ceria (CeO₂), an archetypical reducible oxide, for enzyme mimetics, environmental protection, and chemical synthesis are investigated in this dissertation using theoretical methods. CeO₂ is modeled with thermodynamically stable low-index surfaces exposed by commonly studied ceria thin films and nano particles. To understand phosphatase-like dephosphorylation activity, stable adsorption states and surface reactions of model phosphates are examined. Binding of the central P-atom to surface lattice oxygen (O_latt) supplemented by phosphoryl O-Ce interaction is the only stable adsorption state for the un-dissociated molecule. Deprotonation of phosphate monoesters, …

Droplet-Based Fuel Property Measurements, Wanjun Dang

LSU Doctoral Dissertations

Ongoing work to find renewable biofuels to function as drop-in replacements or blending components with gasoline has identified a large number of fuel candidates. Given the vast number of potential biomass-derived fuel molecules and limited sample sizes, screening tools are required to down-select candidate fuels having desired physical properties to ensure good engine performance. This work investigates approaches for rapid screening of candidate fuels using micro-liter sample sizes targeting four properties -- surface tension, viscosity, heat of vaporization (HOV), and vapor pressure. Measurement techniques for fuel properties are developed based on unit phenomena for liquid fuel droplets including droplet oscillation …

Laser Surface Treatment And Laser Powder Bed Fusion Additive Manufacturing Study Using Custom Designed 3d Printer And The Application Of Machine Learning In Materials Science, Hao Wen

LSU Doctoral Dissertations

Selective Laser Melting (SLM) is a laser powder bed fusion (L-PBF) based additive manufacturing (AM) method, which uses a laser beam to melt the selected areas of the metal powder bed. A customized SLM 3D printer that can handle a small quantity of metal powders was built in the lab to achieve versatile research purposes. The hardware design, electrical diagrams, and software functions are introduced in Chapter 2. Several laser surface engineering and SLM experiments were conducted using this customized machine which showed the functionality of the machine and some prospective fields that this machine can be utilized. Chapter 3 …

Simulation Of Compound Flood Events In Low-Gradient Coastal Watershed, Felix Luis Santiago-Collazo

LSU Doctoral Dissertations

Low-gradient coastal watersheds are susceptible to flooding caused by various flows such as rainfall, tides, and storm surge. Compound flooding occurs when at least two of these mechanisms happen simultaneously or in close succession. Different inundation models, observed data, and/or a combination of these are coupled through varying techniques involving one-way, loosely, tightly, or fully coupled approaches to assess compound flooding. This study presents a one-dimensional (1-D), fully coupled compound inundation model based on the Shallow Water equations. This model approach simultaneously simulates the free water surface variations in the ocean domain (i.e., tide and storm surge modeling), rainfall-runoff in …

Modeling Hydraulic Fracturing Initiation And Propagation In Porous Rock Formationsl, Chang Huang

LSU Doctoral Dissertations

Hydraulic fracturing has long been introduced to the oil and gas industry since the early nineteenth century for both reservoir characterization and reservoir stimulation. Despite the progress made in the last two decades, many challenges still have not been tackled regarding not only the propagation problem but also the initiation problem due to its complexity. The dissertation is divided into two stages, i.e., before and after fracture initiation. The first stage of the research aimed at improving the accuracy in solving the poro-mechanical response of wellbore during fluid injection before a tensile fracture occurs, which is crucial to determine the …

An Investigation Of The Effects Of Variable Magnetic Field Gradients On Soot And Co Emissions From Non-Premixed Hydrocarbon Flames, Edison Ekperechukwu Chukwuemeka

LSU Doctoral Dissertations

The interaction of the paramagnetic species in a combustion process with the mag- netic field placed in the vicinity of non-premixed flames affects the characteristics of the non-premixed flames - flame height and flame lift-off height. However, the effect of this magnetic interaction on the pollutants generated by the flame is unknown.

In general, pollutant formation is promoted in most combustion systems due to in- complete combustion of the hydrocarbon due to improper mixing. Since paramagnetic combustion species such as O2, O, OH, etc interacts with magnetic fields and possess a preferential motion direction, imposing magnetic field on non-premixed flames …

Adsorption And Transport Of Colloids At Interface And In Bulk, Jingyun Lee

LSU Doctoral Dissertations

Colloids are suspensions of microscopic insoluble particles dispersed in a continuum phase such as liquid or gas. Colloids are found in our everyday life from food and cosmetic industries to pharmaceutical and biomedical applications. Depending on a global minimum of the free-energy landscape, colloidal suspensions can be classified as two major classes: equilibrium or active colloidal system. This Ph.D dissertation presents strategies to engineer equilibrium self-assembled structures and out-of-equilibrium active matter using various interparticle forces.

First, we introduce the means to promote the equilibrium self-assembled structures driven by adsorption of colloids at interface. Typically, adsorption of colloids at interface is …

A Systematic Multiscale Investigation Of Nanoparticle-Assisted Co2 Enhanced Oil Recovery (Eor) Process For Shale Oil Reservoirs, Dayo A. Afekare

LSU Doctoral Dissertations

Shale oil reservoirs are prolific on the short term due to hydraulic fracturing and horizontal drilling but experience significant production decline, leading to poor ultimate recovery and leaving billions of barrels of oil buried in the ground. In this study, a systematic multi-scale investigation of an enhanced oil recovery (EOR) process using relatively inexpensive silicon dioxide nanoparticles and carbon dioxide for shale oil reservoirs was conducted. Using the Tuscaloosa Marine Shale (TMS) as a case study, aqueous dispersions of nanosilica in conjunction with CO₂ were investigated at nano-to-core scales. At the nanoscale, atomic force microscope was used to investigate …

Characterization, Immobilization, And Polymer Related Applications Of Watermelon Seed Powder, A Practical Source Of Urease Enzyme, Anthony Quan Quoc Mai

LSU Doctoral Dissertations

Urease enzyme was crystallized almost a century ago, and to this day its intrinsic stability is not ideal for everyday applications. This work introduces a new process by which a naturally encapsulated material, watermelon seed powder (WMSP), is characterized for its stability and activity. WMSP enzymatic activity has been measured for over a year at various storage conditions—exposed to ambient atmosphere for a year, WMSP retained above 90% activity. In aqueous conditions, the enzyme maintained above 60% activity after two months; with the addition of a preservative that number stays at about 90%. There is a pH shift of the …

Adsorption And Reconfiguration Of Amphiphiles At Silica-Water Interfaces: Role Of Electrostatic Interactions, Van Der Waals Forces And Hydrogen Bonds, Yao Wu

LSU Doctoral Dissertations

The ability to explore and predict metastable structures of hybrid self-assemblies is of central importance for the next generation of advanced materials with novel properties. As compared to their thermodynamically stable forms, the kinetically stabilized materials show improved functionality potentially over their stable counterparts. The self-assembly processes usually originate from weak intermolecular interactions, involving a dynamic competition between attractive and repulsive interactions. These weak forces, including van der Waals (vdW), electrostatic interaction and the hydrogen bonding (H-bonding), can be tuned by external stimuli, e.g., confinement, temperature and ionization, and consequently driving hybrid materials into different configurations. It is challenging to …

Using Spatial Analysis And Machine Learning Techniques To Develop A Comprehensive Highway-Rail Grade Crossing Consolidation Model, Samira Soleimani

LSU Doctoral Dissertations

The safety of highway-railroad grade crossings (HRGC) is still an issue in the United States of America (USA). The grade crossing is where a railroad crosses a road at the same level without any over or underpass. To improve the safety of crossings, the crossings’ condition should be explored from several aspects such as engineering design (speed limit, warning signs, etc.), road condition (number of lanes, surface markings, etc.), rail design (the type of track, ballast, etc.), temporal variables (weather, visibility, time of day, lightning, etc.), social variables (population, race, etc.), and last but not least, spatial variables (the type …

Evolution Of Computational Thinking Contextualized In A Teacher-Student Collaborative Learning Environment., John Arthur Underwood

LSU Doctoral Dissertations

The discussion of Computational Thinking as a pedagogical concept is now essential as it has found itself integrated into the core science disciplines with its inclusion in all of the Next Generation Science Standards (NGSS, 2018). The need for a practical and functional definition for teacher practitioners is a driving point for many recent research endeavors. Across the United States school systems are currently seeking new methods for expanding their students’ ability to analytically think and to employee real-world problem-solving strategies (Hopson, Simms, and Knezek, 2001). The need for STEM trained individuals crosses both the vocational certified and college degreed …

Physical And Biological Factors Controlling The Fate Of Nitrate In A Louisiana Coastal Deltaic Floodplain, Alexandra Christensen

LSU Doctoral Dissertations

The Mississippi River Delta is threatened by a growing pressure to support large human populations in the United States both with food production, navigation systems, and urban development in the Mississippi River Basin. Nitrate-nitrogen load in the Mississippi River, up to 100 Tg N yr^-1 from agricultural and urban runoff, leads to phytoplankton blooms and hypoxia across the Louisiana continental shelf, creating dead zones of low dissolved oxygen threatening a significant commercial fishery. Along the coast and river corridors, floodplain ecosystems have the capacity to retain and remove nitrate. This dissertation explores the role of productive, actively growing coastal …

The Long-Term Outlook Of The Mississippi-Atchafalaya Bifurcation: A Convergence Of Engineering, Economics, And Deltaic Evolution, Thomas Mitchell Andrus

LSU Doctoral Dissertations

The most recent and currently active delta lobe of the Mississippi River (MR) is the Atchafalaya-Wax Lake lobe, which was initiated approximately 400 years ago as a result of MR stream capture by the Atchafalaya River (AR). This capture process accelerated in the early to mid-1900s but further progress was prevented by construction and operation of the Old River Control Structure (ORCS) Complex. Many recent studies indicate that MR system below the ORCS is on a retreating geologic trajectory due to contributing factors such as sea level rise, subsidence, faulting, and declining hydraulic stream power. Diversions along the Lower MR …

The Effects Of Temperature On The Yields Of Aliphatic And Aromatic Products From The Supercritical Pyrolysis Of 1-Octene, Elizabeth Anne Hurst

LSU Doctoral Dissertations

Prior to their combustion, fuels for future high-speed aircraft are expected to experience supercritical conditions, leading to the production of polycyclic aromatic hydrocarbons (PAH), precursors to solid carbonaceous deposits, via pyrolytic reactions. These solid deposits can clog fuel-transfer lines, causing unsafe aircraft operation. To prevent the formation of fuel-line deposits, it is critical to understand the reaction pathways that lead to PAH formation in the supercritical fuel pyrolysis environment.

To better understand the role of large 1-alkenes in PAH formation, supercritical pyrolysis experiments with model fuel 1-octene, a representative 1-alkene product from supercritical n-alkane pyrolysis, have been performed. The …

Investigation Of Subsurface Stratigraphy And Groundwater Dynamics In The Mississippi River Delta, An Li

LSU Doctoral Dissertations

The Mississippi River Delta (MRD) is socioeconomically important to the state of Louisiana and the United States. Various types of land-water system data have been collected in the MRD. However, very few efforts have been made to utilize these datasets in modeling regional stratigraphy and groundwater dynamics in the MRD, especially for the upper 50 m of the depth. In this interval of depth, the Mississippi River and surrounding interdistributary bays intensively interact with the groundwater system. The lack of knowledge in regional stratigraphy and groundwater dynamics hinder an understanding of how hydrogeological setting affects processes such as surface-groundwater interaction, …

Numerical Modeling Of Wave Dynamics And Sediment Transport Near The Mississippi Birdfoot Delta And Barataria Estuary, Soroush Sorourian

LSU Doctoral Dissertations

The Barataria Basin is a large estuarine system in Southeastern Louisiana, connected to the Gulf of Mexico through a number of inlets, the most important of which is the Barataria Pass. This research examines, during April-June 2010 including both cold front passage and calm summer-time wind regimes, the wave dynamics in this basin and in its major inlets, morphological evolution near the Barataria Pass, and the budgeting and dispersal of the Mississippi River sediment in the birdfoot delta region. An unstructured grid, terrain following, high resolution coupled FVCOM-SWAVE-SED model is employed and validated in this study. The numerical model results …

Application Of X-Ray Grating Interferometry To Polymer/Flame Retardant Blends In Additive Manufacturing, Omoefe Joy Kio

LSU Doctoral Dissertations

X-ray grating interferometry is a nondestructive tool for visualizing the internal structures of samples. Image contrast can be generated from the absorption of X-rays, the change in phase of the beam and small-angle X-ray scattering (dark-field). The attenuation and differential phase data obtained complement each other to give the internal composition of a material and large-scale structural information. The dark-field signal reveals sub-pixel structural detail usually invisible to the attenuation and phase probe, with the potential to highlight size distribution detail in a fashion faster than conventional small-angle scattering techniques. This work applies X-ray grating interferometry to the study of …

An Airlifted Tidal Mesocosm For Oil Degradation Studies, Daniel Christopher Alt

LSU Doctoral Dissertations

Mesocosms were constructed to allow scientists to isolate variables in a microtidal marsh environment, mimicking the natural conditions found in Terrebonne Bay. The control offered by these mesocosms is given by a process control system that takes user inputs and automates water movement. Twelve mesocosms were constructed, each holding 4.02 m³ (142 ft³) of marsh soil and 3.88 m³ (137 ft³) of water to give 3 experimental levels and a control, all in triplicate.

Each mesocosms that was constructed contained marsh plants in soil plugs 9 feet in diameter and 3 feet deep. These …

Bipartite Quantum Interactions: Entangling And Information Processing Abilities, Siddhartha Das

LSU Doctoral Dissertations

The aim of this thesis is to advance the theory behind quantum information processing tasks, by deriving fundamental limits on bipartite quantum interactions and dynamics. A bipartite quantum interaction corresponds to an underlying Hamiltonian that governs the physical transformation of a two-body open quantum system. Under such an interaction, the physical transformation of a bipartite quantum system is considered in the presence of a bath, which may be inaccessible to an observer. The goal is to determine entangling abilities of such arbitrary bipartite quantum interactions. Doing so provides fundamental limitations on information processing tasks, including entanglement distillation and secret key …

The Tensile Root Strength Of Emergent Coastal Macrophytes, Lauris Olivia Hollis

LSU Doctoral Dissertations

Spartina patens is a dominant emergent macrophyte in fresh, intermediate, and brackish marshes along the Atlantic and Gulf coasts of United States where its biomechanical properties are a key component of wetland health and resilience. Its root biomass and tensile root strength are essential for anchorage, erosion protection, and are important determinants of soil strength. Nutrients and the herbicide atrazine are suspected of negatively impacting this wetland plant and others. The objectives of this study were to: 1) ascertain the tensile root strength of five emergent coastal macrophytes in coastal estuaries, and 2) test the effects of nutrient addition, atrazine …