Physical Sciences and Mathematics Commons^™

Uv-Curable Organic-Inorganic Hybrid Polyurethane Coating, Shiyin Yu

Master's Theses and Doctoral Dissertations

This thesis explored a series of organic-inorganic hybrid polyurethane oligomers with varying molecular weights and functional groups (acrylate and/or silane) that were cured with a single ultraviolet (UV) trigger but two photo-initiators. Upon UV irradiation, the free-radical initiator initiated a free-radical reaction for acrylate cross-linking, and the photo-latent base initiated a sol-gel reaction for condensation of the silanes. This study explored the cure extent of both reactions by FTIR for acrylates and silanes and a weight-loss method for silanes as a function of functional group concentration and time. The general film properties were also studied. The results showed that the …

Impact Of Highway Work Zones On Traffic Crashes: A Case Study In Michigan, Qadri Hafez Shaheen

Master's Theses and Doctoral Dissertations

Infrastructure in the US is severely aged and outdated. This presents a seemingly paradoxical problem in the field of construction management: In order to fix and make roads and highways more safe, construction zones must become inherently less safe in the process. There is a high cost to taxpayers and drivers, as work zones experience a significant amount of crashes and fatalities each year. To mitigate some of the factors that contribute to these crashes, this paper attempts to deliver guidelines on how to update relevant crash data, identify relevant factors, and create recommendations accordingly. The research focused particularly on …

Mobile Device Vulnerabilities & Securities, Luke Rondeau

Senior Honors Theses and Projects

An investigation on current mobile vulnerabilities and research into security. Also, a proof of concept to show the ease of injecting an Android phone with a virus.

A Novel Defense Mechanism Against Web Crawler Intrusion, Alireza Aghamohammadi

Master's Theses and Doctoral Dissertations

Web robots also known as crawlers or spiders are used by search engines, hackers and spammers to gather information about web pages. Timely detection and prevention of unwanted crawlers increases privacy and security of websites. In this research, a novel method to identify web crawlers is proposed to prevent unwanted crawler to access websites. The proposed method suggests a five-factor identification process to detect unwanted crawlers. This study provides the pretest and posttest results along with a systematic evaluation of web pages with the proposed identification technique versus web pages without the proposed identification process. An experiment was performed with …

Studies Of Polymers In Fouling Release Coating Science, Haoran Chen

Master's Theses and Doctoral Dissertations

In chapter one, we describe our studies of the solubility properties of two biocides in F127 aqueous solutions. One is zinc omadine and the other is C9211. The partition coefficients of these two biocides were also determined from the analytical results.

In chapter two, we conducted phase related studies of a triblock copolymer, PEO400- PBO55-PEO400 in aqueous solution. The phase diagram features of PEO400-PBO55-PEO400 in water are compared with those of F127. We believe the lack of a lower gel to liquid transition boundary in this system is because of the relatively longer PEO segments relative to the PBO segment. …