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Full-Text Articles in Physical Sciences and Mathematics

Magnetocapacitance Effect In Nonmultiferroic Yfe03 Single Crystal, Z X. Cheng, H Shen, J Xu, Peng Liu, S J. Zhang, Jianli Wang, Xiaolin Wang, S X. Dou Jul 2013

Magnetocapacitance Effect In Nonmultiferroic Yfe03 Single Crystal, Z X. Cheng, H Shen, J Xu, Peng Liu, S J. Zhang, Jianli Wang, Xiaolin Wang, S X. Dou

Jianli Wang

YFeO3 single crystal displays two relaxor-like dielectric relaxations, one at low temperature (170300 K) and one at high temperature (370520 K), which are attributed to the activation of electrons and oxygen vacancies, respectively. Above the temperature at which electrons are activated, the sample displays a large magnetocapacitance effect. Comparison of the impedance Cole-Cole plots measured with and without applied magnetic field reveals that the occurrence of magnetocapacitance effect is accompanied with an increasing in DC conductivity under magnetic field after the activation of electrons, which is explained by the enhancement of electron jumping in Fe2b-O-Fe3b chains by magnetic field. Thus …


Anisotropic And Excellent Magnetocaloric Properties Of La 0.7ca0.3mno3 Single Crystal With Anomalous Magnetization, J.C Debnath, Rong Zeng, Jung Ho Kim, Dapeng Chen, S X. Dou Jun 2013

Anisotropic And Excellent Magnetocaloric Properties Of La 0.7ca0.3mno3 Single Crystal With Anomalous Magnetization, J.C Debnath, Rong Zeng, Jung Ho Kim, Dapeng Chen, S X. Dou

Shi Xue Dou

Magnetic properties and the magnetocaloric effect (MCE) have been investigated in La0.7Ca0.3MnO3 single crystal with applied field along both the ab-plane and the c-direction. Due to the magnetocrystalline anisotropy, the crystal exhibits anisotropy in the MCE. Upon application of a 5 T field, the magnetic entropy changes (SM), reaching values of 7.668 J/(kg K) and 6.412 J/(kg K) for both the ab-plane and the c-direction, respectively. A magnetic entropy change of 3.3 J/(kg K) was achieved for a magnetic field change of 1.5 T at the Curie temperature, TC = 245 K. Due to the absence of grains in the …


Effect Of Frozen Spin On The Magnetocaloric Property Of La0.7ca0.3coo3 Polycrystalline And Single Crystal Samples, J C. Debnath, R Zeng, J H. Kim, P Shamba, Dapeng Chen, S X. Dou Jun 2013

Effect Of Frozen Spin On The Magnetocaloric Property Of La0.7ca0.3coo3 Polycrystalline And Single Crystal Samples, J C. Debnath, R Zeng, J H. Kim, P Shamba, Dapeng Chen, S X. Dou

Shi Xue Dou

Polycrystalline (PC) and single crystalline (SC) samples of La0.7Ca0.3CoO3 (LCCO) with the perovskite structure were synthesized by conventional solid-state reaction and the floating-zone growth method. We conducted isothermal magnetization measurements of the PC and SC samples at temperatures from 2.8 K to 140 K, and evaluated the magnetic entropy change (−ΔSM) under zero field cooling (ZFC) and field cooling (FC) to 2.8 K. An interesting result has been obtained, where the −ΔSM–T curves in the low temperature range show totally different features between the ZFC and FC cooling procedures. The −ΔSM shows a large inverse irreversibility value for the ZFC …


Single-Crystal Growth And Anisotropic Magnetic Properties Of Nonstoichiometric Three-Layer Sodium Cobalt Oxides, Dapeng Chen, Xiaolin Wang, C T Lin, S X. Dou Jun 2013

Single-Crystal Growth And Anisotropic Magnetic Properties Of Nonstoichiometric Three-Layer Sodium Cobalt Oxides, Dapeng Chen, Xiaolin Wang, C T Lin, S X. Dou

Shi Xue Dou

Large single crystals of α-NaxCoO2 (x=0.91, 0.92, and 0.93) have been successfully fabricated by using the traveling solvent floating zone method. Details on the crystal growth are discussed. The crystal structures were characterized using powder x-ray diffraction and Rietveld refinement. The magnetic susceptibility measurements show that the magnetic properties depend strongly on x. The compound was found to be antiferromagnetic at TN ≈ 20 K for x=0.91 and x=0.92, and paramagnetic for x=0.93. The in-plane and out-of-plane anisotropies were observed for the x=0.91 crystals. In addition, the derived anisotropic g-factor ratios (gab /gc) from the anisotropic susceptibility along H||ab and …


Magnetocapacitance Effect In Nonmultiferroic Yfe03 Single Crystal, Z X. Cheng, H Shen, J Xu, Peng Liu, S J. Zhang, Jianli Wang, Xiaolin Wang, S X. Dou Jun 2013

Magnetocapacitance Effect In Nonmultiferroic Yfe03 Single Crystal, Z X. Cheng, H Shen, J Xu, Peng Liu, S J. Zhang, Jianli Wang, Xiaolin Wang, S X. Dou

Shi Xue Dou

YFeO3 single crystal displays two relaxor-like dielectric relaxations, one at low temperature (170300 K) and one at high temperature (370520 K), which are attributed to the activation of electrons and oxygen vacancies, respectively. Above the temperature at which electrons are activated, the sample displays a large magnetocapacitance effect. Comparison of the impedance Cole-Cole plots measured with and without applied magnetic field reveals that the occurrence of magnetocapacitance effect is accompanied with an increasing in DC conductivity under magnetic field after the activation of electrons, which is explained by the enhancement of electron jumping in Fe2b-O-Fe3b chains by magnetic field. Thus …


Very Strong Intrinsic Flux Pinning And Vortex Avalanches In (Ba, K)Fe2as2 Superconducting Single Crystals, Xiaolin Wang, Shaban R. Ghorbani, Sung-Ik Lee, S X. Dou, C T Lin, T H. Johansen, K.H Muller, Zhenxiang Cheng, Germanas Peleckis, M Shabazi, A.J Qviller, V Yurchenko, G.L Sun, D.L Sun Jun 2013

Very Strong Intrinsic Flux Pinning And Vortex Avalanches In (Ba, K)Fe2as2 Superconducting Single Crystals, Xiaolin Wang, Shaban R. Ghorbani, Sung-Ik Lee, S X. Dou, C T Lin, T H. Johansen, K.H Muller, Zhenxiang Cheng, Germanas Peleckis, M Shabazi, A.J Qviller, V Yurchenko, G.L Sun, D.L Sun

Shi Xue Dou

We report that the (Ba,K)Fe2As2 crystal with Tc=32 K shows a pinning potential, U0, as high as 104 K, with U0 showing very little field dependence. The (Ba,K)Fe2As2 single crystals become isotropic at low temperatures and high magnetic fields, resulting in a very rigid vortex lattice, even in fields very close to Hc2. The isotropic rigid vortices observed in the two-dimensional (2D) (Ba,K)Fe2As2 distinguish this compound from 2D high-Tc cuprate superconductors with 2D vortices. The vortex avalanches were also observed at low temperatures in the (Ba,K)Fe2As2 crystal. It is proposed that it is the K substitution that induces both almost …


Flux Pinning And Vortex Transitions In Doped Bafe2as2 Single Crystals, S R. Ghorbani, X L. Wang, M Shabazi, S X. Dou, K Y. Choi, C T. Lin Jun 2013

Flux Pinning And Vortex Transitions In Doped Bafe2as2 Single Crystals, S R. Ghorbani, X L. Wang, M Shabazi, S X. Dou, K Y. Choi, C T. Lin

Shi Xue Dou

The vortex liquid-to-glass transition has been studied in Ba0.72K0.28Fe2As2 (BaK-122), Ba(Fe0.91Co0.09)2As2(BaCo-122), and Ba(Fe0.95Ni0.05)2As2(BaNi-122) single crystal with superconducting transition temperature, Tc=31.7, 17.3, and 18 K, respectively, by magnetoresistance measurements. For temperatures below Tc, the resistivity curves were measured in magnetic fields within the range of 0≤B≤13 T, and the pinning potential was scaled according to a modified model for vortex liquid resistivity. Good scaling of the resistivity q(B, T) and the effective pinning energy U0(B,T) were obtained. The vortex state is three-dimensional at temperatures lower than a characteristic temperature T*. The vortex phase diagram was determined based on the evolution of …


Josephson-Vortex Flow Resistance In Bi2sr2ca2cu3oy Single Crystals And Its Possible Application In The Manipulation Of Spin And Charge Textures In Diluted Magnetic Semiconductors, Xiaolin Wang, C T Lin, B Liang, S Yu, S Ooi, K Hirata, S Y Ding, Dongqi Shi, S X. Dou, Zhi W. Lin, Jian G. Zhu Jun 2013

Josephson-Vortex Flow Resistance In Bi2sr2ca2cu3oy Single Crystals And Its Possible Application In The Manipulation Of Spin And Charge Textures In Diluted Magnetic Semiconductors, Xiaolin Wang, C T Lin, B Liang, S Yu, S Ooi, K Hirata, S Y Ding, Dongqi Shi, S X. Dou, Zhi W. Lin, Jian G. Zhu

Shi Xue Dou

In this work, the flow of the Josephson vortices (JVs) has been studied for the highly anisotropic Bi2Sr2Ca2Cu3Oy (Bi2223) single crystals. A giant flow of JVs or giant positive magnetoresistance (MR) of over 500%-2000% was obtained in fields of 0.1-5 T and remained almost constant over a wide temperature range from 110 down to 4 K, in contrast to superconducting vortices (SVs), which only produced MR in the vicinity of Tc. The flow of the JVs is expected to be much faster than that of SVs. It is proposed that the Josephson vortices could be used to manipulate the spin …


Magnetic Anisotropy Of Naxcoo2 Single Crystals, Dapeng Chen, Xiaolin Wang, C T Lin, S X. Dou Jun 2013

Magnetic Anisotropy Of Naxcoo2 Single Crystals, Dapeng Chen, Xiaolin Wang, C T Lin, S X. Dou

Shi Xue Dou

We report the magnetic properties of single crystals of NaxCoO2 (x=0.42, 0.82, and 0.87). The magnetic susceptibility measurements revealed considerable anisotropy along H parallel to ab and H parallel to c for the as-grown single crystals. It was found that an antiferromagnetic transition with a Neel temperature T-N=21 K occurred for the x=0.82 sample, and there was a paramagnetic phase for the x=0.87 sample over a wide temperature range from 2 to 300 K, but the sample with x=0.42 shows a monotonic increase of chi with increasing temperature above similar to 100 K. In addition, the x=0.82 sample has the …


Platinum Electrodeposition On Unsupported Single Wall Carbon Nanotubes And Its Application As Methane Sensing Material, Enid Contes-De Jesus, Diana Santiago, Gilberto Casillas, Alvaro Mayoral, Cesar Magen, Miguel Jose-Yacaman, Jing Li, Carlos R. Cabrera Jan 2013

Platinum Electrodeposition On Unsupported Single Wall Carbon Nanotubes And Its Application As Methane Sensing Material, Enid Contes-De Jesus, Diana Santiago, Gilberto Casillas, Alvaro Mayoral, Cesar Magen, Miguel Jose-Yacaman, Jing Li, Carlos R. Cabrera

Australian Institute for Innovative Materials - Papers

This paper reports the decoration of single wall carbon nanotubes (SWCNTs) with platinum (Pt) nanoparticles using an electrochemical technique, rotating disk slurry electrode (RoDSE). Pt/SWCNTs were electrochemically characterized by cyclic voltammetry technique (CV) and physically characterized through the use of transmission electron microscopy (TEM), energy dispersive spectroscopy - X-ray florescence (EDS-XRF) and X-ray diffraction (XRD). After characterization it was found that electrodeposited nanoparticles had an average particle size of 4.1 ± 0.8 nm. Pt/SWCNTs were used as sensing material for methane (CH4) detection and showed improved sensing properties in a range of concentration from 50 ppm to 200 ppm parts …


The Flux Pinning Mechanism, And Electrical And Magnetic Anisotropy In Fe1.04te0.6se0.4 Superconducting Single Crystal, Mahboobeh Shahbazi-Manshadi, Xiaolin Wang, S X. Dou, H Fang, C T. Lin Jan 2013

The Flux Pinning Mechanism, And Electrical And Magnetic Anisotropy In Fe1.04te0.6se0.4 Superconducting Single Crystal, Mahboobeh Shahbazi-Manshadi, Xiaolin Wang, S X. Dou, H Fang, C T. Lin

Australian Institute for Innovative Materials - Papers

The temperature and magnetic field dependences of the magnetization and critical current density of Fe1.04Te0.6Se0.4 single crystals have been investigated, and the flux pinning mechanism has been analysed. The normalized pinning force (fp Fp/F p,max) vs. h(H/Hirr) curves, are scaled using the Dew-Hughes theory, f(h) ≈ hp(1 - h)q with p 1.35 and q 3.06. The angular dependence of the resistivity under different magnetic fields shows a dip-like structure, below the superconducting transition temperature. The anisotropic value of 2 was obtained using Ginzburg-Landau theory.


Magnetic Field Induced Discontinuous Spin Reorientation In Erfeo3 Single Crystal, Hui Shen, Zhenxiang Cheng, Fang Hong, Jiayue Xu, Shujuan Yuan, Shixun Cao, Xiaolin Wang Jan 2013

Magnetic Field Induced Discontinuous Spin Reorientation In Erfeo3 Single Crystal, Hui Shen, Zhenxiang Cheng, Fang Hong, Jiayue Xu, Shujuan Yuan, Shixun Cao, Xiaolin Wang

Australian Institute for Innovative Materials - Papers

The spin reorientation of ErFeO3 that spontaneously occurs at low temperature has been previously determined to be a process involving the continuous rotation of Fe3þ spins. In this work, the dynamic process of spin reorientation in ErFeO3 single crystal has been investigated by AC susceptibility measurements at various frequencies and static magnetic fields. Interestingly, two completely discontinuous steps are induced by a relatively large static magnetic field due to the variation in the magnetic anisotropy during this process. It provides deeper insights into the intriguing magnetic exchange interactions which dominate the sophisticated magnetic phase transitions in the orthoferrite systems.


Single-Pulse Terahertz Coherent Control Of Spin Resonance In The Canted Antiferromagnet Yfeo3, Mediated By Dielectric Anisotropy, Zuanming Jin, Zoltan Mics, Guohong Ma, Zhenxiang Cheng, Mischa Bonn, Dmitry Turchinovich Jan 2013

Single-Pulse Terahertz Coherent Control Of Spin Resonance In The Canted Antiferromagnet Yfeo3, Mediated By Dielectric Anisotropy, Zuanming Jin, Zoltan Mics, Guohong Ma, Zhenxiang Cheng, Mischa Bonn, Dmitry Turchinovich

Australian Institute for Innovative Materials - Papers

We report on the coherent control of terahertz (THz) spin waves in a canted antiferromagnet yttrium orthoferrite, YFeO3, associated with a quasiferromagnetic (quasi-FM) spin resonance at a frequency of 0.3 THz, using a single-incident THz pulse. The spin resonance is excited impulsively by the magnetic field component of the THz pulse. The intrinsic dielectric anisotropy of YFeO3 in the THz range allows for coherent control of both the amplitude and the phase of the excited spin wave. The coherent control is based on simultaneous generation of two interfering phase-shifted spin waves whose amplitudes and relative phase, dictated by the dielectric …


Spin Switching And Magnetization Reversal In Single-Crystal Ndfeo3, S J. Yuan, W Ren, F Hong, Y B. Wang, J C. Zhang, L Bellaiche, S X. Cao, G Cao Jan 2013

Spin Switching And Magnetization Reversal In Single-Crystal Ndfeo3, S J. Yuan, W Ren, F Hong, Y B. Wang, J C. Zhang, L Bellaiche, S X. Cao, G Cao

Australian Institute for Innovative Materials - Papers

We report an experimental and computational study of single-crystal NdFeO3, which features two inequivalent magnetic sublattices, namely, Fe and Nd sublattices that are coupled in an antiparallel fashion. This paper reveals that a strong interaction between 3d and 4f electrons of the two sublattices along with a spin-lattice coupling drives an extremely interesting magnetic state that is highly sensitive to the orientation and history of weak magnetic field. The following phenomena are particularly remarkable: (1) sharply contrasting magnetization M(T) along the a and c axes; (2) a first-order spin switching along the a axis below 29 K when the system …


Direct Observation Of Liquid-Like Behavior Of A Single Au Grain Boundary, Gilberto Casillas, Arturo Ponce, Jesus Velazquez-Salazar, M Jose-Yacaman Jan 2013

Direct Observation Of Liquid-Like Behavior Of A Single Au Grain Boundary, Gilberto Casillas, Arturo Ponce, Jesus Velazquez-Salazar, M Jose-Yacaman

Australian Institute for Innovative Materials - Papers

Behavior of matter at the nanoscale differs fromthat of the bulk due to confinement and surface effects. Here, we report a direct observation of liquid-like behavior of a single grain boundary formed by cold-welding Au nanoparticles, 40 nm in size, by mechanical manipulation in situ TEM. The grain boundary rotates almost freely due to the free surfaces and can rotate about 90 degrees. The grain boundary sustains more stress than the bulk, confirming a strong bonding between the nanoparticles.Moreover, this technique allows the measurement of the surface diffusion coefficient from experimental observations, which we compute for the Au nanoparticles. This …


Flux Pinning Mechanism In Bafe1.9ni0.1as2 Single Crystals: Evidence For Fluctuation In Mean Free Path Induced Pinning, M Shahbazi-Manshadi, X L Wang, K Y Choi, S X. Dou Jan 2013

Flux Pinning Mechanism In Bafe1.9ni0.1as2 Single Crystals: Evidence For Fluctuation In Mean Free Path Induced Pinning, M Shahbazi-Manshadi, X L Wang, K Y Choi, S X. Dou

Australian Institute for Innovative Materials - Papers

The flux pinning mechanism of BaFe1.9Ni0.1As2 superconducting crystals have been investigated systematically by magnetic measurements up to 13 T at various temperatures. The field dependence of the critical current density, Jc, was analysed within the collective pinning model. A remarkably good agreement between the experimental results and theoretical dl pinning curve is obtained, which indicates that pinning in BaFe1.9Ni0.1As2 crystal originates from spatial variation of the mean free path. Moreover, the normalized pinning force density, Fp, curves versus h1/4B/Birr (Birr is the irreversibility field) were scaled using the Dew-Hughes model. Analysis suggests that point pinning alone cannot explain the observed …


Crystal Growth, Structure And Thermal Properties Of Noncentrosymmetric Single Crystals Prca4o(Bo3)3+, Fapeng Yu, Shujun Zhang, Xiufeng Cheng, Xiulan Duan, Tingfeng Ma, Xian Zhao Jan 2013

Crystal Growth, Structure And Thermal Properties Of Noncentrosymmetric Single Crystals Prca4o(Bo3)3+, Fapeng Yu, Shujun Zhang, Xiufeng Cheng, Xiulan Duan, Tingfeng Ma, Xian Zhao

Australian Institute for Innovative Materials - Papers

Noncentrosymmetric praseodymium calcium oxyborate single crystals, PrCa4O(BO3)3 (PrCOB), were grown by the Czochralski technique. The monoclinic unit cell parameters were found to be a = 8.177 Å, b = 16.157 Å, c = 3.629 Å and Z = 2 with space group Cm. Crystal density was measured using the Archimedes method, being on the order of 3.47 g cm-3. Thermal properties of PrCOB were investigated, where the specific heat was found to be 0.63 J g-1 °C-1 at room temperature, increasing to 0.85 J g-1°C-1 at 700°C. The thermal expansion coefficients were measured to be α11 = 7.99, α22 = …