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Full-Text Articles in Physical Sciences and Mathematics

Commissioning Of The Asta Laser Lab With Uv Pulse Length Characterization, Daniel Kelley, Jeff Corbett Aug 2012

Commissioning Of The Asta Laser Lab With Uv Pulse Length Characterization, Daniel Kelley, Jeff Corbett

STAR Program Research Presentations

The Linac Coherent Light Source (LCLS) at SLAC depends on a photocathode electron gun to provide the linear accelerator with the raw material – electrons – used for making X-ray laser pulses. The photocathode used in the LCLS Injector is a clean copper plate in high vacuum. When the cathode is struck with high energy UV light, electrons are liberated from its surface and then accelerated down the linac with radio-frequency electric fields. These fast-moving bunches of electrons are directed through an undulator magnet to radiate X-ray light.

Although scientists have been using photocathode techniques at SLAC for 25 years, …


An Overview Of Electrode Materials In Microbial Fuel Cells, Su-Qin Ci, Na Wu, Zhen-Hai Wen, Jing-Hong Li Jun 2012

An Overview Of Electrode Materials In Microbial Fuel Cells, Su-Qin Ci, Na Wu, Zhen-Hai Wen, Jing-Hong Li

Journal of Electrochemistry

Microbial fuel cells (MFCs) are devices that can directly convert organic chemical energy into electrical energy with microbial as catalysts. MFCs are a promising bio-electrochemical system with the potential to degrade organic sewage and produce electricity. This article supplies a critical and comprehensive review for the electrode materials concerning about anode and cathode in MFCs, including the fabrications, functional modifications and surface constructions of electrode materials, as well as their applications in MFCs. Additionally, the existing problems of electrode materials in current MFCs have been demonstrated in order to provide the guideline for exploring the next-generation electrode materials for MFCs.


Synthesis And Electrochemical Properties Of Lifeso4f/Graphene Composite As Cathode Material For Lithium-Ion Batteries, Wei Guo, Ya-Xia Yin, Li-Jun Wan, Yu-Guo Guo Apr 2012

Synthesis And Electrochemical Properties Of Lifeso4f/Graphene Composite As Cathode Material For Lithium-Ion Batteries, Wei Guo, Ya-Xia Yin, Li-Jun Wan, Yu-Guo Guo

Journal of Electrochemistry

The LiFeSO4F was successfully synthesized from the reactions of FeSO4?xH2O (x=1, 4, 7) with LiF in tetraethylene glycol media through a facile low temperature method. The structures and microscopic features of the products were characterized by XRD, SEM and TEM. TGA result shows the good thermal stability of the as-prepared LiFeSO4F. No diffraction peaks of the FeSO4 are observed in the as-prepared products with the starting material of either FeSO4?4H2O or FeSO4?7H2O, which should be ascribed to delaying the release of H2O from the hydrated compounds. Cyclic voltammetry (CV) curves and electrochemical impedance spectroscopy (EIS) results prove that the LiFeSO4F/graphene …


Preparation And Hydrogen Evolution Properties Of Ni/Ag2o/Ruo2-Pt Cathodes, Shu Huang, Xue-Ming Li, Wu-Lin Li, Wen Wang Feb 2012

Preparation And Hydrogen Evolution Properties Of Ni/Ag2o/Ruo2-Pt Cathodes, Shu Huang, Xue-Ming Li, Wu-Lin Li, Wen Wang

Journal of Electrochemistry

The Ni/Ag2O/RuO2-Pt composite cathode was prepared by sol-gel method using RuCl3 and H2PtCl6 as raw materials. The effects of heat treatment conditions and AgNO3 concentrations on hydrogen evolution properties were investigated. The morphology and composition of Ni/Ag2O/RuO2-Pt composite cathode have been characterized by XRD, XPS and SEM-EDS. It is demonstrated that the surface structure of Ni/Ag2O/RuO2-Pt composite cathode is more compact, with fewer cracks and larger surface roughness than pure nickel. At the conditions of 0.3 A?cm-2, 90 oC, and 11 mol?L-1 NaOH solution, the hydrogen evolution overpotential of Ni/Ag2O/RuO2-Pt composite cathode increases 484 mV with respect to pure nickel …


A Battery Composed Of A Polypyrrole Cathode And A Magnesium Alloy Anode-Toward A Bioelectric Battery, Yong Kong, Caiyun Wang, Yang Yang, Chee O. Too, Gordon G. Wallace Jan 2012

A Battery Composed Of A Polypyrrole Cathode And A Magnesium Alloy Anode-Toward A Bioelectric Battery, Yong Kong, Caiyun Wang, Yang Yang, Chee O. Too, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

A bioelectric battery can be implanted into the human body and relies on oxygen in the internal body fluid to produce electrical energy. In this work, a battery that uses polypyrrole doped with a biological polyelectrolyte (dextran sulfate, an anti-coagulant) as the cathode and bioresorbable Mg alloy (AZ61) as the anode was developed. This battery exhibited a discharge capacity of 565 mA h g-1 in phosphate buffered saline (PBS, pH = 7.4), a commonly used electrolyte in biological research; offering a specific energy density of similar to 790W h kg-1. The electrochemical properties of the cathode, anode …


K0.25mn2o4 Nanofiber Microclusters As High Power Cathode Materials For Rechargeable Lithium Batteries, Chaofeng Zhang, Chuanqi Feng, Peng Zhang, Zaiping Guo, Zhixin Chen, Sean Li, Hua-Kun Liu Jan 2012

K0.25mn2o4 Nanofiber Microclusters As High Power Cathode Materials For Rechargeable Lithium Batteries, Chaofeng Zhang, Chuanqi Feng, Peng Zhang, Zaiping Guo, Zhixin Chen, Sean Li, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

K0.25Mn2O4 microclusters assembled from single-crystalline nanofibers were synthesized via a hydrothermal process at different temperatures. The possibility of using these materials as cathode material for lithium ion batteries was studied for the first time. The charge/discharge results showed that the K0.25Mn2O4 nanofiber microclusters synthesized at 120 degrees C exhibit excellent lithium storage properties, with a high reversible capability (360 mA h g-1 at current density of 100 mA g-1) and stable lithium-ion insertion/de-insertion reversibility. The charge/discharge mechanism in lithium ion batteries was studied and proposed for the …


Lifepo4-Fe2p-C Composite Cathode: An Environmentally Friendly Promising Electrode Material For Lithium-Ion Battery, M. Mahfuzur Rahman, Jiazhao Wang, Rong Zeng, David Wexler, Hua-Kun Liu Jan 2012

Lifepo4-Fe2p-C Composite Cathode: An Environmentally Friendly Promising Electrode Material For Lithium-Ion Battery, M. Mahfuzur Rahman, Jiazhao Wang, Rong Zeng, David Wexler, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

In this investigation, the synthesis strategy is involved the creation of LiFePO4-Fe2P-C composites with a porous conductive architecture, which includes distinct regions or clusters containing antiferromagnetic LiFePO4 in close proximity to ferromagnetic Fe2P. The microstructure is achieved by using a simple ultra-fast solvent assisted manual grinding method, combined with solid state reaction, which can replace the time-consuming high energy ball milling method. The crystalline structure, morphology, and electrochemical characterization of the synthesised product are investigated systematically. The electrochemical performance is outstanding, especially the high C rate. The composite cathode is found to display specific capacity of 167 mAh g-1 at …