Physical Sciences and Mathematics Commons^™

The Effects Of Temperature On The Yields Of Aliphatic And Aromatic Products From The Supercritical Pyrolysis Of 1-Octene, Elizabeth Anne Hurst

LSU Doctoral Dissertations

Prior to their combustion, fuels for future high-speed aircraft are expected to experience supercritical conditions, leading to the production of polycyclic aromatic hydrocarbons (PAH), precursors to solid carbonaceous deposits, via pyrolytic reactions. These solid deposits can clog fuel-transfer lines, causing unsafe aircraft operation. To prevent the formation of fuel-line deposits, it is critical to understand the reaction pathways that lead to PAH formation in the supercritical fuel pyrolysis environment.

To better understand the role of large 1-alkenes in PAH formation, supercritical pyrolysis experiments with model fuel 1-octene, a representative 1-alkene product from supercritical n-alkane pyrolysis, have been performed. The …

Investigation Of Subsurface Stratigraphy And Groundwater Dynamics In The Mississippi River Delta, An Li

LSU Doctoral Dissertations

The Mississippi River Delta (MRD) is socioeconomically important to the state of Louisiana and the United States. Various types of land-water system data have been collected in the MRD. However, very few efforts have been made to utilize these datasets in modeling regional stratigraphy and groundwater dynamics in the MRD, especially for the upper 50 m of the depth. In this interval of depth, the Mississippi River and surrounding interdistributary bays intensively interact with the groundwater system. The lack of knowledge in regional stratigraphy and groundwater dynamics hinder an understanding of how hydrogeological setting affects processes such as surface-groundwater interaction, …

Numerical Modeling Of Wave Dynamics And Sediment Transport Near The Mississippi Birdfoot Delta And Barataria Estuary, Soroush Sorourian

LSU Doctoral Dissertations

The Barataria Basin is a large estuarine system in Southeastern Louisiana, connected to the Gulf of Mexico through a number of inlets, the most important of which is the Barataria Pass. This research examines, during April-June 2010 including both cold front passage and calm summer-time wind regimes, the wave dynamics in this basin and in its major inlets, morphological evolution near the Barataria Pass, and the budgeting and dispersal of the Mississippi River sediment in the birdfoot delta region. An unstructured grid, terrain following, high resolution coupled FVCOM-SWAVE-SED model is employed and validated in this study. The numerical model results …

Application Of X-Ray Grating Interferometry To Polymer/Flame Retardant Blends In Additive Manufacturing, Omoefe Joy Kio

LSU Doctoral Dissertations

X-ray grating interferometry is a nondestructive tool for visualizing the internal structures of samples. Image contrast can be generated from the absorption of X-rays, the change in phase of the beam and small-angle X-ray scattering (dark-field). The attenuation and differential phase data obtained complement each other to give the internal composition of a material and large-scale structural information. The dark-field signal reveals sub-pixel structural detail usually invisible to the attenuation and phase probe, with the potential to highlight size distribution detail in a fashion faster than conventional small-angle scattering techniques. This work applies X-ray grating interferometry to the study of …

An Airlifted Tidal Mesocosm For Oil Degradation Studies, Daniel Christopher Alt

LSU Doctoral Dissertations

Mesocosms were constructed to allow scientists to isolate variables in a microtidal marsh environment, mimicking the natural conditions found in Terrebonne Bay. The control offered by these mesocosms is given by a process control system that takes user inputs and automates water movement. Twelve mesocosms were constructed, each holding 4.02 m³ (142 ft³) of marsh soil and 3.88 m³ (137 ft³) of water to give 3 experimental levels and a control, all in triplicate.

Each mesocosms that was constructed contained marsh plants in soil plugs 9 feet in diameter and 3 feet deep. These …