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Full-Text Articles in Physical Sciences and Mathematics

Theoretical Analysis Of Charge Conduction And Rectification In Self-Assembled-Monolayers In Molecular Junctions, Francis Adoah Aug 2023

Theoretical Analysis Of Charge Conduction And Rectification In Self-Assembled-Monolayers In Molecular Junctions, Francis Adoah

Electronic Theses and Dissertations, 2020-

As electrical devices shrink to the atomic scale, it is expected that Moore's law will soon be obsolete for semiconductor devices. In 1974, Avriam and Ratner predicted that organic devices could replace semiconductor technology, leading to extensive research on molecular-based organic devices. This dissertation delves into the theoretical frameworks used to examine the transport in molecular junctions and aims to enhance our comprehension of charge transport and conduction properties. The studies presented in this thesis illustrates that a molecule's alteration by just a single atom can change it from an insulator to a conductor, and also that, by fine-tuning the …


Design Of Stormwater Bmps For Surface And Groundwater Protection Based On Site-Scale Soil Properties: Phase I, Kelly Kibler, Lisa Chambers, Melanie Beazley Aug 2023

Design Of Stormwater Bmps For Surface And Groundwater Protection Based On Site-Scale Soil Properties: Phase I, Kelly Kibler, Lisa Chambers, Melanie Beazley

Florida DOT

Much of Earth’s nutrient cycling takes place in soils. Characteristics of soils control physical, chemical, and biological processes that determine rates of nutrient fluxes, storage, or transformation. As remediation of excess nutrients in stormwater runoff is one function of stormwater Best Management Practices (BMPs), the soil profile constitutes one of the most important factors of BMP design. Variation observed in BMP effectiveness (e.g., why one BMP design works effectively in one place and not another) can often be explained by variations in the soil profile, either through direct means or by a soil’s influence on hydraulics of stormwater flow through …


Comparing Phosphorus Removal Efficiencies And Mechanisms Via Two Cost-Effective Specialty Adsorbents In A Cascade Upflow Filtration System, Sydney Kilgus-Vesely Jan 2023

Comparing Phosphorus Removal Efficiencies And Mechanisms Via Two Cost-Effective Specialty Adsorbents In A Cascade Upflow Filtration System, Sydney Kilgus-Vesely

Honors Undergraduate Theses

Finding solutions to treat water that contains phosphorus is an important effort due to the harmful impacts it presents to both human health and the environment. Phosphorus is considered a limiting factor in water oftentimes and therefore controls the growth of algal bloom in a water body. The increase of algal populations due to wastewater effluent, stormwater runoff, and agricultural discharge in Florida waters has a direct link to the event of harmful algal blooms such as red tide in coastal regions, eutrophication of waterbodies, and fish kills. Finding low cost, energy efficient, and low maintenance green sorption media (GSM) …


Towards Explainable Ai Using Attribution Methods And Image Segmentation, Garrett J. Rocks Jan 2023

Towards Explainable Ai Using Attribution Methods And Image Segmentation, Garrett J. Rocks

Honors Undergraduate Theses

With artificial intelligence (AI) becoming ubiquitous in a broad range of application domains, the opacity of deep learning models remains an obstacle to adaptation within safety-critical systems. Explainable AI (XAI) aims to build trust in AI systems by revealing important inner mechanisms of what has been treated as a black box by human users. This thesis specifically aims to improve the transparency and trustworthiness of deep learning algorithms by combining attribution methods with image segmentation methods. This thesis has the potential to improve the trust and acceptance of AI systems, leading to more responsible and ethical AI applications. An exploratory …


Exploring A Lab-Scale Cascade Upflow Bioreactor System For Nitrogen Removal Via Biosorption Activated Media, Alejandra Robles Lecompte Jan 2023

Exploring A Lab-Scale Cascade Upflow Bioreactor System For Nitrogen Removal Via Biosorption Activated Media, Alejandra Robles Lecompte

Graduate Thesis and Dissertation 2023-2024

Many Best Management Practices (BMPs) have been developed to reduce excessive nutrients in stormwater runoff and mitigate harmful algal blooms in downstream receiving water bodies. This study demonstrates a new BMP by comparing two green sorption media (i.e., specialty adsorbents) for nutrient removal in cascade upflow biofiltration systems operated in parallel. The proposed filtration technology can control hydraulic gradients, prevent clogging and settlements, and increase hydraulic loading while removing more nutrients in an integrated physicochemical and microbiological treatment process. The two green sorption media being tested in this study include zero-valent-iron and perlite-based green sorption media (ZIPGEM) and biochar, iron, …