Physical Sciences and Mathematics Commons^™

Advances In Cellulose Nanomaterial-Based Foams For Environmental Applications, Md Musfiqur Rahman

Electronic Theses and Dissertations

The use of metal-oxide nanoparticles adsorbents is limited to fixed-bed columns in industrial-scale water treatment applications. This limitation is commonly attributed to the tendency of nanoparticles to aggregate, the use of non-sustainable and inefficient polymeric resins as supporting materials, or a lack of adsorption capacity. Foams and aerogels derived from cellulose nanomaterials have unique characteristics, such as high porosity and low density, which enables their use in a variety of environmental applications, including water treatment. However, the overall use of cellulose nanomaterial-based foams in various environmental sectors is limited due to the high cost of production associated with time- and …

A Map-Algebra-Inspired Approach For Interacting With Wireless Sensor Networks, Cyber-Physical Systems Or Internet Of Things, David Almeida

Electronic Theses and Dissertations

The typical approach for consuming data from wireless sensor networks (WSN) and Internet of Things (IoT) has been to send data back to central servers for processing and analysis. This thesis develops an alternative strategy for processing and acting on data directly in the environment referred to as Active embedded Map Algebra (AeMA). Active refers to the near real time production of data, and embedded refers to the architecture of distributed embedded sensor nodes. Network macroprogramming, a style of programming adopted for wireless sensor networks and IoT, addresses the challenges of coordinating the behavior of multiple connected devices through a …

Wave Attenuation Through Submerged Oyster Aquaculture Cages, Liam T. Hanley

Electronic Theses and Dissertations

Coastal erosion presents a growing issue to shorelines around the world and is especially harmful to Maine, a region where sea-level rise is higher than the global average. Green and hybrid coastal defense strategies are being implemented around the country to provide sustainable, habitat-friendly solutions to erosion control. Maine is a hotspot for commercial aquaculture, with an estimated $13.6 million economic impact. This study looks to bridge the gap between Maine aquaculture and the living shorelines initiative, by determining the wave attenuating properties of submerged oyster cages. The project will be able to inform local oyster farmers, resource planners, and …

Accessible Autonomy: Exploring Inclusive Autonomous Vehicle Design And Interaction For People Who Are Blind And Visually Impaired, Paul D. S. Fink

Electronic Theses and Dissertations

Autonomous vehicles are poised to revolutionize independent travel for millions of people experiencing transportation-limiting visual impairments worldwide. However, the current trajectory of automotive technology is rife with roadblocks to accessible interaction and inclusion for this demographic. Inaccessible (visually dependent) interfaces and lack of information access throughout the trip are surmountable, yet nevertheless critical barriers to this potentially lifechanging technology. To address these challenges, the programmatic dissertation research presented here includes ten studies, three published papers, and three submitted papers in high impact outlets that together address accessibility across the complete trip of transportation. The first paper began with a thorough …

Longitudinal Case-Control Study Of Mammographic Breast Tissue Subtypes, Kendra Batchelder

Electronic Theses and Dissertations

Breast density is a known risk factor for breast cancer. However, there has been limited research on potential subtypes of mammographic dense breast tissue to identify areas of active dense tissue that is structurally reorganizing and links to cancer dynamics, versus areas of passive dense tissue which remains organized. We hypothesize that the amounts of subtypes of mammographic dense tissue and the associated rate of change through time could provide insights into breast cancer risk. A retrospective study was conducted to investigate breast cancer using longitudinal screening mammograms and accompanying pathology reports collected in 2015. Patients were matched by age …

Nanocellulose Based Foams For Low-Cost Disposable Medical Applications, Dominic Kugell

Electronic Theses and Dissertations

Polyurethane foams have been a staple material for their use in medical positioners, such as post-surgery elevation pillows as well as specific tailored positioners for their use during surgery. Polyurethane foams are preferred because of their lower cost compared to other petroleum derived foams, their versatility, and suitable mechanical properties. However, the environmental impact, including both cost and perception, of these foams is immense. Therefore, alternatives are being explored with biopolymers emerging as a promising class of materials. Cellulose is one such polymer that has recently demonstrated desirable properties. In this study, cellulose nanofibrils (CNF), a household foaming agent, and …

Influence Of Platinum Nanoparticles On Ionic Transport And Hydrogen Reactivity Of Yttria-Stabilized Zirconia Thin Films, Firas Mahyob

Electronic Theses and Dissertations

Yttria-stabilized zirconia (YSZ) is a widely used ceramic material in solid oxide fuel cells, oxygen sensors, and sensing applications due to its high ionic conductivity, chemical inertness, and thermal stability. YSZ is promising active coating for use in miniaturized harsh environment wireless surface acoustic sensors to monitor gases such as H₂. Adding catalytic Pt nanoparticles can enhance gas reactivity and lead to associated film conductivity changes.

In this work, thin films with an (8% Y₂O₃ - 92% ZrO₂) composition were deposited onto piezoelectric langasite substrates using RF magnetron sputtering in Ar:O₂ - …

Hybrid Power Spectral And Wavelet Image Roughness Analysis, Basel White

Electronic Theses and Dissertations

The Two-Dimensional Wavelet Transform Modulus Maxima (2D WTMM) sliding window methodology has proven to be a robust approach, in particular for the extraction of the Hurst (H) roughness exponent from grayscale mammograms. The power spectrum is a computational analysis based on the Fourier transform that can be used to estimate the roughness of a scale-invariant image or region via the calculation of H. We aim to examine how the calculation of H in fractional Brownian motion (fBm) images and mammograms can be improved. fBm images are generated for H ∈ [0.00,1.00] for testing through the previous 2D …

Development And Applications Of Similarity Measures For Spatial-Temporal Event And Setting Sequences, Fuyu Xu

Electronic Theses and Dissertations

Similarity or distance measures between data objects are applied frequently in many fields or domains such as geography, environmental science, biology, economics, computer science, linguistics, logic, business analytics, and statistics, among others. One area where similarity measures are particularly important is in the analysis of spatiotemporal event sequences and associated environs or settings. This dissertation focuses on developing a framework of modeling, representation, and new similarity measure construction for sequences of spatiotemporal events and corresponding settings, which can be applied to different event data types and used in different areas of data science. The first core part of this dissertation …

Thermal Stability Of Platinum-Silicon Alloy Films Grown On Langasite Substrates For Use In Microwave Acoustic Sensor Technology, Kell Fremouw

Honors College

Wireless sensors that can operate in temperatures up to 1000°C are widely needed for real time monitoring of large-scale industrial processes. Such sensors will improve efficiency and prevent component failure. Under previous work at UMaine, Surface Acoustic Wave Resonator (SAWR) sensors fabricated on piezoelectric langasite (La₃Ga₅SiO₁₄) wafers have shown promise for wireless strain measurements at high temperatures. However, there is a major technical challenge in attaching SAWR langasite based sensors to metal parts because the large differences in the coefficient of thermal expansion (CTE) between langasite and metals leads to large thermal stresses and …

Anthropogenic Effects On Tidal Distortion In A Tidal River, Matthew D. Fischer

Electronic Theses and Dissertations

Tidal rivers are landward portions of estuarine systems constituting the union between coastal, tidally controlled settings and rivers, where fluvial processes dominate. In these reaches, river discharge (mean flow) and tides are the two most important mechanisms in controlling geophysical flows. The processes governing water levels and current amplitudes in tidal rivers are highly nonlinear and modulated by external forcings- thus requiring sophisticated techniques for accurate prediction and forecasting. Physical oceanographers and estuarine physicists tend to limit their study area to the maximum extent of the horizontal tide (salinity intrusion), not the most landward point influenced by tidal water levels. …

Quantifying Spatial Heterogeneity Of Wild Blueberries And Crop Water Stress Monitoring Using Remote Sensing Technologies, Kallol Barai

Electronic Theses and Dissertations

The wild blueberry is one of the major crops of Maine, with significant economic value and potential health benefits. Due to global climate change, drought impacts have been increasing significantly in recent years in the northeast region of the USA, causing significant economic losses in the agricultural sectors. It has been predicted to increase further in the future. Changing patterns of the elevated atmospheric temperatures, increased rainfall variabilities, and more frequent drought events have made the wild blueberry industry of Maine vulnerable, suggesting the adoption of novel approaches to mitigate the negative impacts of global climate changes. Also, wild blueberry …

Intersections Of Environmentalism, Chemistry, And Racism: An Experimental Study Of Halobenzene Hydrogenolysis And Critical Communication Studies Of Equitable Learning Practices Rooted In Black Feminism, Lauren O. Babb

Electronic Theses and Dissertations

Increasing concentrations of fluorinated aromatic compounds in surface water, groundwater, and soil pose threats to the environment. Fundamental studies that elucidate mechanisms of dehalogenation for C-X compounds (where X represents a halide) are required to develop effective remediation strategies. For halogenated benzenes, previously published research has suggested that the strength of the C-X bond is not rate-determining in the overall rate of dehalogenation. Instead, the rate-determining step has been hypothesized to be adsorption of the C-X compound onto the surface of a catalyst. Building on this hypothesis, in this work, we examine the reaction kinetics of fluorobenzene conversion to benzene, …

Development And Evaluation Of Modeling Approaches For Extrusion-Based Additive Manufacturing Of Thermoplastics, Christopher C. Bock

Electronic Theses and Dissertations

This work focuses on evaluating different modeling approaches and model parameters for thermoplastic AM, with the goal of informing more efficient and effective modeling approaches. First, different modeling approaches were tested and compared to experiments. From this it was found that all three of the modeling approaches provide comparable results and provide similar results to experiments. Then one of the modeling approaches was tested on large scale geometries, and it was found that the model results matched experiments closely. Then the effect of different material properties was evaluated, this was done by performing a fractional factorial design of experiments where …

Charged-Particle Interactions To Generate Novel Coatings And Materials, Pradnya D. Rao

Electronic Theses and Dissertations

A typical paper coating formulation contains anionically charged pigments and latex to provide a high-quality surface for printing. However, during application and drying, the latex can migrate to the surface or deep into the paper, resulting in weak coating layers or the need to use a high latex content to obtain the same strength properties. In this thesis, we have explored the introduction of cationically charged particles into the suspension as a way to reduce the amount of binder in the coatings, improve coating strength and reduce binder migration. With these aims in mind, we have generated cationic precipitated calcium …

Gradient Generating Microfluidic Coculture System For Disease Modeling And Neural Development, Phaneendra Chennampally

Electronic Theses and Dissertations

Cellular microenvironment or cell niche plays an important role in developmental biology and disease pathophysiology. Physical or chemical signals in microenvironment drive the cellular activity. These signaling molecules are generated from the surrounding cells/tissues as part of intercellular communication; a fundamental property of a cell. Dynamic profile of these signaling molecules in the microenvironment plays a pivotal role in transfer of molecular information from cell to cell in disease proliferation or fate determination. Recapitulating these signaling cues in an in vitro study is difficult to achieve using standard cell culture techniques. However microfluidic systems are capable of addressing these issues, …

Comparison Of Land Use And Flowslide Incidence In Palu Valley Following The 2018 Mw 7.5 Palu-Donggala Earthquake, Peta C. Fifield

Electronic Theses and Dissertations

The September 28 Mw 7.5 Palu-Donggala earthquake in Indonesia was the deadliest natural disaster in 2018. Five flowslides on the eastern side of Palu Valley, which were attributed to the substantial majority of deaths and economic losses in the region, occurred due to liquefaction of naturally dry alluvial deposits in gently sloping ground (2 to 6%). The requisite conditions for soil liquefaction are the presence of loose granular sediments and full saturation. Instigation of these catastrophic ground failures were linked to artificial saturation by an unlined agricultural irrigation canal. From a civil engineering perspective, the Palu ground failures on the …

Hydrodynamic Impacts Of Expanding Aquaculture, Zhilong Liu

Electronic Theses and Dissertations

Climate change may potentially change aquatic systems and bring certain risks for aquaculture development. Understanding interactions between aquaculture and the environment helps to ensure aquaculture expansion is sustainable in the future. It is critical to determine how farms influence tidal flow patterns, turbulence, mixing and material transport in estuaries. This research aims to determine the flow response of an oyster farm, predict how expanding farms and farm placement will alter estuarine dynamics, and understand how the design of a farm influences material transport.

The hydrodynamic response of a floating oyster aquaculture farm in a low inflow estuary (the Damariscotta River …

Coastal Windstorms Create Unsteady, Unpredictable Storm Surges In A Fluvial Maine Estuary, Preston Spicer, Pascal Matte, Kimberly Huguenard, Laura N. Rickard

Civil Engineering Faculty Scholarship

Storm surges create coastal flooding that can be damaging to life and property. In estuaries with significant river influence (fluvial), it is possible for tides, storm surge, and river discharge to interact and enhance surges relative to the immediate coast. These tide-surge-river interactions were previously identified in a fluvial Maine estuary as higher frequency (>four cycles per day) oscillations to storm surge which were proposed to be incited by enhanced friction and resonance during certain windstorm events (Spicer et al. 2019). The relative contributions to tide-surge-river interaction from atmospheric forcing variables (wind, barometric pressure, and externally generated surge) remains …

Nsf Career Award Supports Schwartz's Research On The Chemical Process For Making Rubber Component, Marcus Wolf

General University of Maine Publications

advance his ongoing dissection of the Lebedev process. The well-known, multi-step chemical reaction is used to make butadiene from biomass-derived ethanol. However, little research has been conducted on the Lebedev process at the molecular level. Understanding the intricacies of this process will help researchers create new catalysts necessary for the chemical reactions to make goods from both petroleum and biomass, that would increase butadiene yield.

Understanding Biomass Upgrading Through Hydrogenolysis Reactions: Kinetics And Mechanism, Jalal Tavana

Electronic Theses and Dissertations

This dissertation involves several hydrogenolysis reactions but is mainly focused on hydrodechlorination (HDC) of chlorobenzene (PhCl) and hydrodeoxygenation (HDO) of 2-furancarboxylic acid (FCA). Hydrodechlorination of PhCl has been the subject of research for some time. Here, we used a Pd/C catalyst to study this reaction though rigorous kinetics and mechanistic analyses in a CSTR reactor. The H₂/D₂ kinetic isotope effect (KIE) experiment revealed that H₂ is not involved in a rate controlling step. The kinetics data are in agreement with similar systems reported before and follow a first-order dependence on chlorobenzene, half order for hydrogen and …

Covid-19_Umaine News_Umaine Students Get Immersive Experience In Engineering Education, University Of Maine Division Of Marketing And Communications

Division of Marketing & Communications

Screenshot of UMaine News press release regarding Asli Sezen-Barrie, associate professor of curriculum, assessment and instruction in the University of Maine College of Education and Human Development redesigning her class on Teaching Science in the Secondary School to provide more opportunities for preservice teachers at UMaine to learn about engineering concepts and meet with engineers.

A Benefit-Cost Analysis Of Community Solar For Low To Moderate Income Residents Of Mount Desert Island, Maine, Abigayle Hargreaves

Honors College

No abstract provided.

Uav 6dof Simulation And Kalman Filter For Localizing Radioactive Sources, John G. Goulet

Electronic Theses and Dissertations

Unmanned Aerial Vehicles (UAVs) expand the available mission-space for a wide range of budgets. Using MATLAB, this project has developed a six degree of freedom (6DOF) simulation of UAV flight, an Extended Kalman Filter (EKF), and an algorithm for localizing radioactive sources using low-cost hardware. The EKF uses simulated low-cost instruments in an effort to estimate the UAV state throughout simulated flight.

The 6DOF simulates aerodynamics, physics, and controls throughout the flight and provides outputs for each time step. Additionally, the 6DOF simulation offers the ability to control UAV flight via preset waypoints or in realtime via keyboard input.

Using …

Using Cellulose Nanofibrils And Calcium Carbonate In Single-Use Utensils, Sierra Yost

Honors College

As humanity becomes aware of the environmental issues that come from plastics, substitutes for single-use plastic are needed. Straws, expanded polystyrene, and grocery bags especially have been placed under scrutiny, but there is a need to replace other single use plastics such as eating utensils and cup lids. In this thesis, the properties of cellulose nanofibrils and calcium carbonate mixtures are characterized to determine the feasibility of their use as a plastic replacement. Using cellulose nanofibrils poses two challenges: 1) it shrinks when dried causing difficulty in forming an object, and 2) it is produced in a 3 weight percent …

Minerva 2020, The Honors College

Minerva

This issue of Minerva includes an article on 2020 Honors Read Rising Out of Hatred; a piece by Professors Mimi Killinger and Katie Quirk on teaching during a pandemic; and a story on the UMaine UVote initiative led by Rob Glover and Jenny Desmond. Other highlights include reflections by current students; an article on the Honors Outdoor Program Series (HOPS); and profiles recognizing several alumni accomplishments.

Modeling Response Of Water Quality To Land-Use And Climate Change In Lake Auburn, Me, Nicholas Messina

Electronic Theses and Dissertations

Lake Auburn, Maine, USA, is a historically unproductive lake that has experienced multiple algal blooms since 2011. The lake is the water supply source for a population of ~60,000. We modeled past temperature, and concentrations of dissolved oxygen (DO) and phosphorus (P) in Lake Auburn by considering the watershed and internal contributions of P as well as atmospheric factors, and predicted the change in lake water quality in response to future climate and land-use changes. A stream hydrology and P-loading model (SimplyP) was used to generate input from two major tributaries into a lake model (MyLake) to simulate physical mixing, …

Tide And Storm Surge Dynamics In Estuaries Of Variable Morphology, Preston Spicer

Electronic Theses and Dissertations

Storm surges are the most destructive component of coastal storms, and climate change is predicted to enhance the frequency of intense storm events in the future. Currently, most storm surge forecasting assumes linear surges and the extent to which this assumption leads to model inaccuracies is currently unknown. The goals of this research are to characterize storm surge in estuaries and determine the contribution of nonlinear tide-surge interaction to total inland surges. A citizen science experiment was conducted in four estuaries in Maine. Results show the estuary shape influences surges through convergence, friction and man-made constrictions. These mechanisms modified total …

Perspectives On Water Resources Risk, Policy, And Stewardship, Anne Marie Lausier

Electronic Theses and Dissertations

Water management approaches have historically optimized water for human use and placed lower emphasis on the relationship between ecosystems and humans. Despite efforts to balance human and ecosystem needs, existing management approaches tend to prioritize some needs, knowledges, and values over others. Natural and anthropogenic changes pose challenges to water governance institutions due to policy inflexibility, and may lead to ecosystem degradation, water stress, and conflict among water users. This work seeks to redress these shortcomings through three scholarly contributions. First, a conceptual framework for Water Resources Stewardship is developed in support of equitable and adaptive solutions under changing conditions. …

Minerva 2019, The Honors College

Minerva

This issue of Minerva includes a farewell from departing Honors Dean, François Amar; an article on the new service-learning course HON 175 and the course's inaugural Hurricane Island experience; and a deep dive into the Servant Heart Research Collaborative and the group's visit to Sierra Leone, Africa. Other highlights include reflections by a number of Honors faculty who returned from sabbatical; and a look into 2019-2020 student thesis research and internship experiences.