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Full-Text Articles in Physical Sciences and Mathematics

Carbon Nanotube-Reduced Graphene Oxide Composites For Thermal Energy Harvesting Applications, Mark S. Romano, Na Li, Dennis Antiohos, Joselito M. Razal, Andrew Nattestad, Stephen Beirne, Shaoli Fang, Yongsheng Chen, Rouhollah Jalili, Gordon G. Wallace, Ray Baughman, Jun Chen Mar 2014

Carbon Nanotube-Reduced Graphene Oxide Composites For Thermal Energy Harvesting Applications, Mark S. Romano, Na Li, Dennis Antiohos, Joselito M. Razal, Andrew Nattestad, Stephen Beirne, Shaoli Fang, Yongsheng Chen, Rouhollah Jalili, Gordon G. Wallace, Ray Baughman, Jun Chen

Gordon Wallace

By controlling the SWNT-rGO electrode composition and thickness to attain the appropriate porosity and tortuosity, the electroactive surface area is maximized while rapid diffusion of the electrolyte through the electrode is maintained. This leads to an increase in exchange current density between the electrode and electrolyte which results in enhanced thermocell performance.


Manganosite-Microwave Exfoliated Graphene Oxide Composites For Asymmetric Supercapacitor Device Applications, Dennis Antiohos, Kanlaya Pingmuang, Mark Romano, Stephen Beirne, Tony C. Romeo, Phil Aitchison, Andrew I. Minett, Gordon G. Wallace, Sukon Phanichphant, Jun Chen Mar 2014

Manganosite-Microwave Exfoliated Graphene Oxide Composites For Asymmetric Supercapacitor Device Applications, Dennis Antiohos, Kanlaya Pingmuang, Mark Romano, Stephen Beirne, Tony C. Romeo, Phil Aitchison, Andrew I. Minett, Gordon G. Wallace, Sukon Phanichphant, Jun Chen

Gordon Wallace

Graphene based materials coupled with transition metal oxides are promising electrode materials in asymmetric supercapacitors owing to their unique properties which include high surface area, good chemical stability, electrical conductivity, abundance, and lower cost profile over time. In this paper a composite material consisting of graphene oxide exfoliated with microwave radiation (mw rGO), and manganosite (MnO) is synthesised in order to explore their potential as an electrode material. The composite material was characterised by scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were used to explore …


Ferroelectric And Ferromagnetic Nanofibers: Synthesis, Properties And Applications, A Jalalian, A M. Grishin, S X. Dou Jun 2013

Ferroelectric And Ferromagnetic Nanofibers: Synthesis, Properties And Applications, A Jalalian, A M. Grishin, S X. Dou

Shi Xue Dou

As first time, ferroelectric (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 (BCTZ), biocompatible (Na0.5K0.5)NbO3 (NKN), and ferromagnetic Y3Fe5O12 (YIG) nanofibers were synthesized by sol-gel assisted electrospining technique. Non-woven, bead-free 100 μm long fiber mat was formed from close-packed nanocrystals after calcination in air at 800°C (BCTZ and NKN) and 1100°C (YIG). BCTZ fibers are 200 nm in width whereas NKN and YIG fibers have smaller 50-100 nm diameter. X-ray diffraction and Raman spectroscopy show that BCTZ and NKN crystallized in tetragonal and rhombohedral polar phases in the vicinity of morphotropic phase boundary. Room temperature ferromagnetism in YIG fibers is indicated by a well formed M-H hysteresis …


Polypyrrole Coated Nylon Lycra Fabric As Stretchable Electrode For Supercapacitor Applications, Binbin Yue, Caiyun Wang, Xin Ding, Gordon G. Wallace Mar 2013

Polypyrrole Coated Nylon Lycra Fabric As Stretchable Electrode For Supercapacitor Applications, Binbin Yue, Caiyun Wang, Xin Ding, Gordon G. Wallace

Gordon Wallace

Wearable electronics offer the combined advantages of both electronics and fabrics. Being an indispensable part of these electronics, lightweight, stretchable and wearable power sources are strongly demanded. Here we describe a daily-used nylon lycra fabric coated with polypyrrole as electrode for stretchable supercapacitors. Polypyrrole was synthesized on the fabric via a simple chemical polymerization process with ammonium persulfate (APS) as an oxidant and naphthalene-2,6-disulfonic acid disodium salt (Na2NDS) as a dopant. This material was characterized with FESEM, FTIR, tensile stress, and studied as a supercapacitor electrode in 1.0 M NaCl. This conductive textile could endure 1000 stretching cycles with 100% …