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Full-Text Articles in Physical Sciences and Mathematics
Polypyrrole Doped With Redox-Active Poly(2-Methoxyaniline-5-Sulfonic Acid) For Lithium Secondary Batteries, Yang Yang, Caiyun Wang, Syed A. Ashraf, Gordon G. Wallace
Polypyrrole Doped With Redox-Active Poly(2-Methoxyaniline-5-Sulfonic Acid) For Lithium Secondary Batteries, Yang Yang, Caiyun Wang, Syed A. Ashraf, Gordon G. Wallace
Gordon Wallace
Polypyrrole is a promising electrode material for flexible/bendable energy storage devices due to its inherent fast redox switching, mechanical flexibility, easy processability and being environmentally benign. However, its low attainable capacity limits its practical applications. Here, we synthesise a polypyrrole/poly(2-methoxyaniline-5-sulfonic acid) (PPy/PMAS) composite by incorporating redox-active PMAS into a PPy matrix via an electropolymerization method. For comparison, polypyrrole containing the electrochemically inert dopant p-toluenesulfonate (PPy-pTS) was prepared under the same conditions. The resultant PPy/PMAS film shows greatly improved electrochemical properties by harnessing the contribution from PMAS, i.e. higher specific capacity, better rate capability and improved cycling stability when used as …
Electrically Conductive Coatings Of Nickel And Polypyrrole/Poly(2- Methoxyaniline-5-Sulfonic Acid) On Nylon Lycra® Textiles, B C. Kim, P C. Innis, Gordon G. Wallace, C T.J Low, F C. Walsh, W J. Cho, K H. Yu
Electrically Conductive Coatings Of Nickel And Polypyrrole/Poly(2- Methoxyaniline-5-Sulfonic Acid) On Nylon Lycra® Textiles, B C. Kim, P C. Innis, Gordon G. Wallace, C T.J Low, F C. Walsh, W J. Cho, K H. Yu
Gordon Wallace
Woven nylon Lycra® has been coated with finely-divided electroless nickel-phosphorus, polypyrrole and electroless nickel/polypyrrole to produce flexible and electrically conductive textiles. The coated textiles were tested for their electrochemical activity, electrical resistivity and resistivity in response to mechanical strain. Pre-dyeing the textile with poly(2-methoxyaniline-5-sulfonic acid) (PMAS) prior to electroless metallization by electroless nickel and via chemical polymerization of polypyrrole was found to be beneficial in enhancing the resultant coating as well as stabilizing surface resistance responses when exposed to a wide range of strain. The mass gain due to the nickel coating was found to increase linearly with deposition time. …
Colour Tunable Electrochromic Devices Based On Pprodot-(Hx)2 And Pprodot-(Ethx)2 Polymers, Bo Weng, Syed Ashraf, Peter C. Innis, Gordon G. Wallace
Colour Tunable Electrochromic Devices Based On Pprodot-(Hx)2 And Pprodot-(Ethx)2 Polymers, Bo Weng, Syed Ashraf, Peter C. Innis, Gordon G. Wallace
Gordon Wallace
The most commonly used method to tune the colour transition states of an ECD is to modify the chemical structure of the electrochromic polymers to achieve the desired transparent to dark state switching colours. However, this approach can present significant synthetic challenges that typically result in a compromise in device performance parameters such as contrast range or stability as well as solvent processability. In this study we have investigated tuning the dark-state colour of an ECD (at +0.8 V) by solution mixing poly(3,3-dihexyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine) (PProDOT-(Hx)2), which has an excellent contrast performance but with an esthetically undesirable purple colour transition, with poly(3,3-bis(2-ethylhexyl)-3,4-dihydro-2H-thieno …
Advanced Chemical Oxidation And Toxicity Reduction Of 2,4,6-Trichlorophenol By Using Fenton's Reagent: Part Ii, Dechlorination Kinetics, Somnath Basu, Venkat Sreenivasan, Irvine W. Wei
Advanced Chemical Oxidation And Toxicity Reduction Of 2,4,6-Trichlorophenol By Using Fenton's Reagent: Part Ii, Dechlorination Kinetics, Somnath Basu, Venkat Sreenivasan, Irvine W. Wei
Irvine W. Wei
Laboratory investigation has shown that Fenton's Reagent is a very effective oxidant for 2,4,6-Trichlorophenol (TCP). The authors reported the first phase of this research, consisting of five different reactions of Fenton's Reagent on TCP, at the 1995 AIChE Summer National Meeting in Boston as Part I of this paper. The results demonstrated total removal of TCP, with almost complete release of aromatic ring bound chlorine atoms into chloride ions, significant reduction of TOC, and very importantly, significant toxicity reduction compared to the original substrate. These results suggested that Fenton's Reaction can be considered as a candidate process for treatment of …
Advanced Chemical Oxidation And Toxicity Reduction Of 2,4,6-Trichlorophenol By Using Fenton's Reagent: Part Iv, Reaction Mechanism And Kinetics, Somnath Basu, Irvine W. Wei
Advanced Chemical Oxidation And Toxicity Reduction Of 2,4,6-Trichlorophenol By Using Fenton's Reagent: Part Iv, Reaction Mechanism And Kinetics, Somnath Basu, Irvine W. Wei
Irvine W. Wei
No abstract provided.
A Conceptual Continuous Process For The Treatment And Toxicity Reduction Of Wastewater Contaminated With 2,4,6-Trichlorophenol: Extended Abstract, Somnath Basu, Irvine W. Wei
A Conceptual Continuous Process For The Treatment And Toxicity Reduction Of Wastewater Contaminated With 2,4,6-Trichlorophenol: Extended Abstract, Somnath Basu, Irvine W. Wei
Irvine W. Wei
Fenton's Reagent is an aqueous solution of ferrous ions and hydrogen peroxide. Through laboratory experiments Fenton's Reagent has been shown to be an excellent treatment agent for the removal of organic contaminants dissolved in water. It carries out oxidative degradation of various organic substrates using the principle of advanced chemical oxidation. This is an excellent alternate route for the removal of hazardous and toxic chemicals, which are recalcitrant to biological treatment. The authors of this paper conducted an extensive laboratory investigation to study the degradation of 2,4,6- Trichlorophenol (TCP) using Fenton's Reagent, reported elsewhere. The results indicated an optimum H₂O₂:TCP …
Advanced Chemical Oxidation And Toxicity Reduction Of 2,4,6-Trichlorophenol By Using Fenton's Reagent: Part I, Kuang-Wei (Stone) Chen, Somnath Basu, Irvine W. Wei
Advanced Chemical Oxidation And Toxicity Reduction Of 2,4,6-Trichlorophenol By Using Fenton's Reagent: Part I, Kuang-Wei (Stone) Chen, Somnath Basu, Irvine W. Wei
Irvine W. Wei
The objective of this study is to exmnine the removal of a priority chlorinated aromatic pollutant, 2,4,6-Trichlorophenol (TCP), in aqueous solution by using Fenton's Reagent (a mixture of hydrogen peroxide and ferrous iron catalyst). Chlorinated phenols are priority pollutants, regulated by stringent discharge litnits. The presence of chlorine increases the toxicity of these phenolic compounds and decreases their biodegradability. Therefore, the processes of oxidation and dechlorination of chlorinated phenols by using Fenton's Reagent were employed in this study. Experiments were conducted in one-liter stirred batch reactors at 20°C. Three parallel reactors were used for reactions between 0.25 mM 2,4,6-TCP and …