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Synthesis And Hydration Of Alite-Calcium Sulfoaluminate Cement, Natechanok Chitvoranund, Frank Winnefeld, Craig Hargis, Barbara Lothenbach
Synthesis And Hydration Of Alite-Calcium Sulfoaluminate Cement, Natechanok Chitvoranund, Frank Winnefeld, Craig Hargis, Barbara Lothenbach
Craig Hargis
An alite-calcium sulfoaluminate (ACSA) clinker containing approximately 50% alite and 10% ye'elimite was synthesised at 1300°C using a laboratory furnace and 1% calcium fluoride (CaF2) as a mineraliser, ground and blended with 5% anhydrite. The hydration mechanism of the resulting ACSA cement was investigated experimentally using quantitative X-ray diffraction and thermogravimetry, as well as by thermodynamic modelling. During the first hours, mainly alite reacts. Ye'elimite starts to dissolve significantly after 2 d, as it is predominately present as inclusions within the alite matrix and thus reacts only after sufficient alite has dissolved to expose the ye'elimite domains within …