Physical Sciences and Mathematics Commons^™

Direct Electrochemistry And Glucose Biosensing Of Glucose Oxidase-Gold Nanoparticles Composite Synthesized By Enzyme Method, Fang He, Xiao-Li Qin, Ying-Chun Fu, Chao Chen, Qing-Ji Xie, Shou-Zhuo Yao

Journal of Electrochemistry

Glucose oxidase (GOx)-gold nanoparticles (AuNPs) composite was synthesized by the one-pot enzyme reaction in the mixture solution of NaAuCl₄, GOx and glucose, and a Nafion/GOx-AuNPs/glassy carbon electrode was fabricated by the cast-coating method to examine the direct electrochemistry of GOx and the biosensing performance on this electrode. Such a GOx-AuNPs composite showed good direct-electrochemistry activity and bioactivity of GOx, probably because the enzyme-mediated AuNPs are close to the redox active centers of GOx. This enzyme electrode exhibited a linear amperometric response to glucose concentration (0.54 mmol·L^-1) at -0.4 V (vs. SCE), and a detection limit of …

Synthesis Of Namnpo4 By Spraying Drying-High Temperature Sintering And Its Electrochemical Performance, Xiao-Chen Lin, Xiao-Biao Wu, Xu Hou, Yong Yang

Journal of Electrochemistry

As a cathode material for sodium ion batteries, NaMnPO₄/C nanocomposite is successfully synthesized by the combination of spraying drying and high temperature sintering methods. The crystal structure of the as-synthesized phosphate material is confirmed as the natrophilite NaMnPO₄, which possesses orthorhombic symmetry and Pmnb space group. It is shown that the precursors are hollow spherical particles and the obtained product consists of micro-scaled secondary particles, which are composed of NaMnPO₄ nanocrystallites (tens of nanometres) and amorphous carbon networks. The ionic and electronic conductivities of NaMnPO₄ are both effectively enhanced with the help of this …

Electrochemical Applications Of Single-Walled Carbon Nanohorns, Su-Ping Li, Huai-Min Guan, Shu-Yun Zhu, Muhammad Rehan Hassan Shah Gilani, Saima Hanif, Guo-Bao Xu, Yue-Jin Tong

Journal of Electrochemistry

Single-wall carbon nanohorns (SWCNHs) have unique properties, such as a large specific surface area, good electrical conductivity and biocompatibility. It has been widely utilized in many fields. In the present review, the progress in electrochemistry study of SWCNHs has been summarized and the future research trends have been proposed.

Comparison In Factors Affecting Electrochemical Properties Of Thermal-Reduced Graphene Oxide For Supercapacitors, Peng Xiao, Da-Hui Wang, Jun-Wei Lang

Journal of Electrochemistry

In this paper, thermal-reduced graphene oxide (T-RGO) materials are synthesized by modified Hummer’s method, followed by thermal reduction under argon atmosphere at different temperatures. Electrochemical investigations show that, for T-RGO electrodes, good electrical conductivity is necessary and the surface functional groups play more significant role than the specific surface area in determining the electrochemical capacitance. The T-RGO obtained at 900 °C (T-RGO900) with a relatively high Brunauer-Emmett-Teller (BET) surface area (314 m²·g^-1) and a high electrical conductivity (2421 S·m^-1) shows a low specific capacitance of 56 F·g^-1. In comparison, the T-RGO obtained …

One-Step Synthesis Of Pani/Nihcf Hybrid Film Using Unipolar Pulse Electrodeposition And Its Electrocatalytic Reduction Performance For H2O2 Detection, Sen-Liang Liao, Xiu-Min Li, Xiao-Gang Hao, Yan-Hong Wang, Chun-Feng Xue, Yong-Hong Wang

Journal of Electrochemistry

Organic–inorganic hybrid films composed of polyaniline/nickel hexacyanoferrate (PANI/NiHCF) were fabricated on platinum substrates using unipolar pulse one-step electrodeposition. The deposition mechanism of hybrid film was proposed: Due to high potential of unipolar pulse electrodeposition, which avoided the reduction of Fe(CN)₆^3-, the films with high electrocatalytic property and “insoluble” form of NiHCF were achieved. The morphology and composition of PANI/NiHCF hybrid film were characterized by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and Fourier transform infrared spectroscopy (FT-IR). The effect of pulse potential on the electrochemical performance of hybrid film was investigated in detail. Results showed that …

Platinum Hollow Nanospheres With Different Sizes: Controllable Synthesis And Electrocatalytic Oxidation Toward Methanol, Xuan Lin, Mei-Qin Cheng, Zhong-Jin Shang, Ting Xiong, Xian-Tu Zhang, Wei Tian, Jian-Yun Lin, Qi-Ling Zhong, Bin Ren

Journal of Electrochemistry

The selenium (Se) templates and hollow platinum (Pthollow) nanospheres with different sizes were controllably synthesized by adjusting the concentration of sodium dodecyl sulphonate (SDSN) (CSDSN, μmol·L-1) which was used as a surfactant. Accordingly, the Pthollow nanospheres modified glassy carbon (GC) electrode (Pthollow/GC) was prepared. The morphology and composition of Pthollow nanospheres were characterized by scanning electron microscopy (SEM), transmission electron microscope (TEM), energy dispersive X-ray spectroscopy (EDX), high resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED) and X-ray diffraction (XRD) techniques. The electrocatalytic activities of Pthollow/GC and electrodeposited Pt nanoparticles modified glassy carbon electrode (Ptnano/GC) toward methanol oxidation …

Density Functional Theory Study On The Structures Of Solvent-Ion In The Electrolyte Of Lithium Ion Battery, Li-Dan Xing, Ru Yang, Xian-Wen Tang, Wen-Na Huang, Qi-Feng Liu, Qi-Peng Yu, Wei-Shan Li

Journal of Electrochemistry

In this work, the possible structures of solvent-ion complex, resulting from the electrostatic interaction in the propylene carbonate (PC) base electrolyte of lithium ion battery, have been investigated using the density functional theory. The calculated results show that the structure of solvent-ion complex depends on the solvent number. In the PC base electrolyte, maximum number of PC solvents that coexist in the Li⁺-solvent sheath is four. Additionally, the salt anion exists in a complex with the positively charged alkyl group of PC rather than in a free state. The calculated results give a good explanation to the reported …

Synthesis Of Irreversible Incompletely Specified Multi-Output Functions To Reversible Eosops Circuits With Pse Gates, Robert Adrian Fiszer

Dissertations and Theses

As quantum computers edge closer to viability, it becomes necessary to create logic synthesis and minimization algorithms that take into account the particular aspects of quantum computers that differentiate them from classical computers. Since quantum computers can be functionally described as reversible computers with superposition and entanglement, both advances in reversible synthesis and increased utilization of superposition and entanglement in quantum algorithms will increase the power of quantum computing.

One necessary component of any practical quantum computer is the computation of irreversible functions. However, very little work has been done on algorithms that synthesize and minimize irreversible functions into a …

Development Of A Lab-On-A-Chip Device For Rapid Nanotoxicity Assessment In Vitro, Pratikkumar Shah

FIU Electronic Theses and Dissertations

Increasing useof nanomaterials in consumer products and biomedical applications creates the possibilities of intentional/unintentional exposure to humans and the environment. Beyond the physiological limit, the nanomaterialexposure to humans can induce toxicity. It is difficult to define toxicity of nanoparticles on humans as it varies by nanomaterialcomposition, size, surface properties and the target organ/cell line. Traditional tests for nanomaterialtoxicity assessment are mostly based on bulk-colorimetric assays. In many studies, nanomaterials have found to interfere with assay-dye to produce false results and usually require several hours or days to collect results. Therefore, there is a clear need for alternative tools that can …

College Of Engineering Senior Design Competition Fall 2014, University Of Nevada, Las Vegas

Fred and Harriet Cox Senior Design Competition Projects

Part of every UNLV engineering student’s academic experience, the senior design project stimulates engineering innovation and entrepreneurship. Each student in their senior year chooses, plans, designs, and prototypes a product in this required element of the curriculum. A capstone to the student’s educational career, the senior design project encourages the student to use everything learned in the engineering program to create a practical, real world solution to an engineering challenge. The senior design competition helps focus the senior students in increasing the quality and potential for commercial application for their design projects. Judges from local industry evaluate the projects on …

Vehicle Base Station, Emad William Saad, John L. Vian, Matthew A. Vavrina, Jared A. Nisbett, Donald C. Wunsch

Electrical and Computer Engineering Faculty Research & Creative Works

A system to load and unload material from a vehicle comprises a vehicle base station and an assembly to autonomously load and unload material from the vehicle.

Elucidating Fundamental Mechanisms In Focused Electron- And Ion-Beam Induced Synthesis, Carlos M. Gonzalez

Doctoral Dissertations

A focused electron beam deposition process (FEBID) coupled with in-situ infrared pulsed laser assist (LA-EBID) has been implemented for higher purity tungsten nanowires using W(CO)₆ [tungsten hexacarbonyl] as parent precursor gas. Nanowires made of Co from Co₂(CO)₈ [dicobalt octacarbonyl] and Pt from MeCpPtIVMe₃ [trimethyl methylcyclopentadienyl platinum] have also been realized by using inert focused ion beams of helium and helium and neon, respectively. In all cases, higher electrical conductivities, higher purities and larger grain sizes have been obtained when compared with preceding traditional additive edit techniques. These new approaches will make possible successful nanoscale direct-write …

Security Issues In Data Warehouse, Saiqa Aleem, Luiz Fernando Capretz, Faheem Ahmed Dr.

Electrical and Computer Engineering Publications

Data Warehouse (DWH) provides storage for huge amounts of historical data from heterogeneous operational sources in the form of multidimensional views, thus supplying sensitive and useful information which help decision-makers to improve the organization’s business processes. A data warehouse environment must ensure that data collected and stored in one big repository are not vulnerable. A review of security approaches specifically for data warehouse environment and issues concerning each type of security approach have been provided in this paper.

Simulation, And Overload And Stability Analysis Of Continuous Time Sigma Delta Modulator, Kyung Kang

UNLV Theses, Dissertations, Professional Papers, and Capstones

The ever increasing demand for faster and more powerful digital applications requires high speed, high resolution ADCs. Currently, sigma delta modulators ADCs are extensively used in broadband telecommunication systems because they are an effective solution for high data-rate wireless communication systems that require low power consumption, high speed, high resolution, and large signal bandwidths.

Because mixed-signal integrated circuits such as Continuous Time sigma delta modulators contain both analog and digital circuits, mixed signal circuits are not as simple to model and simulate as all discrete or all analog systems. In this dissertation, the delta transform is used to simulate CT …

Split-Step Approach To Electromagnetic Propagation Through Atmospheric Turbulence Using The Modified Von Karman Spectrum And Planar Apertures, Monish Ranjan Chatterjee, Fathi H.A. Mohamed

Electrical and Computer Engineering Faculty Publications

The impact of atmospheric phase turbulence on Gaussian beam propagation along propagation paths of varying lengths is examined using multiple random phase screens. The work is motivated by research involving generation and encryption of acousto-optic chaos, and the interest in examining propagation of such chaotic waves through atmospheric turbulence. A phase screen technique is used to simulate perturbations to the refractive index of the medium through the propagation path. A power spectral density based on the modified von Karman spectrum model for turbulence is used to describe the random phase behavior of the medium.

In recent work, results for the …

Performance Analysis Of A Hybrid Raman Optical Parametric Amplifier In The O- And E-Bands For Cwdm Pons, Sasanthi Peiris, Nicolas Madamopoulos, Neophytos A. Antoniades, Dwight Richards, Roger Dorsinville

Publications and Research

We describe a hybrid Raman-optical parametric amplifier (HROPA) operating at the O- and E-bands and designed for coarse wavelength division multiplexed (CWDM) passive optical networks (PONs). We present the mathematical model and simulation results for the optimization of this HROPA design. Our analysis shows that separating the two amplification processes allows for optimization of each one separately, e.g., proper selection of pump optical powers and wavelengths to achieve maximum gain bandwidth and low gain ripple. Furthermore, we show that the proper design of optical filters incorporated in the HROPA architecture can suppress idlers generated during the OPA process, as well …

Earth Abundant Thin Film Technology For Next Generation Photovoltaic Modules, Githin Alapatt

All Dissertations

With a cumulative generation capacity of over 100 GW, Photovoltaics (PV) technology is uniquely poised to become increasingly popular in the coming decades. Although, several breakthroughs have propelled PV technology, it accounts for only less than 1% of the energy produced worldwide. This aspect of the PV technology is primarily due to the somewhat high cost per watt, which is dependent on the efficiency of the PV cells as well as the cost of manufacturing and installing them. Currently, the efficiency of the PV conversion process is limited to about 25% for commercial terrestrial cells; improving this efficiency can increase …

Improved Performance Of Analog And Digital Acousto-Optic Modulation With Feedback Under Profiled Beam Propagation For Secure Communication Using Chaos, Fares S. Almehmadi, Monish Ranjan Chatterjee

Electrical and Computer Engineering Faculty Publications

Using intensity feedback, the closed-loop behavior of an acousto-optic hybrid device under profiled beam propagation has been recently shown to exhibit wider chaotic bands potentially leading to an increase in both the dynamic range and sensitivity to key parameters that characterize the encryption. In this work, a detailed examination is carried out vis-à-vis the robustness of the encryption/decryption process relative to parameter mismatch for both analog and pulse code modulation signals, and bit error rate (BER) curves are used to examine the impact of additive white noise.

The simulations with profiled input beams are shown to produce a stronger encryption …

A Comprehensive Assessment Methodology Based On Life Cycle Analysis For On-Board Photovoltaic Solar Modules In Vehicles, Mahmoud Abdelhamid

All Dissertations

This dissertation presents a novel comprehensive assessment methodology for using on-board photovoltaic (PV) solar technologies in vehicle applications. A well-to-wheels life cycle analysis based on a unique energy, greenhouse gas (GHG) emission, and economic perspective is carried out in the context of meeting corporate average fuel economy (CAFE) standards through 2025 along with providing an alternative energy path for the purpose of sustainable transportation. The study includes 14 different vehicles, 3 different travel patterns, in 12 U.S. states and 16 nations using 19 different cost analysis scenarios for determining the challenges and benefits of using on-board photovoltaic (PV) solar technologies …

Photoelectric Characterization Of Bacteriorhodopsin Reconstituted In Lipid Bilayer Membrane, Joel Kamwa

Graduate Theses and Dissertations

The objective of this work was to conduct basic research in biologically inspired energy conversion solutions. A photosynthetic protein (Bacteriorhodopsin) was reconstituted in a bi-layer membrane. Then, when a laser beam was shined on the membrane, the photon energy was used by the protein to pump protons across the membrane. The translocation of protons across the membrane was measured as photocurrent. For this purpose, a system was built to characterize the lipid bilayer membranes and to measure the photocurrent. The lipid bilayer membrane was characterized by its capacitance and resistance. A picoampere photocurrent was observed when Bacteriorhodopsin protein was present …

The Role Of Quantum Dot Size On The Performance Of Intermediate Band Solar Cells, Najla Alnami

Graduate Theses and Dissertations

The goal of this thesis is to understand possible mechanisms for the reported decrease of the open circuit voltage and solar cell efficiency in quantum dot (QD) intermediate band solar cells (IBSCs). More specifically, the effect of indium arsenide (InAs) QD height on the open circuit voltage and solar cell efficiency was studied in a systematic way. To explore this effect in QD solar cells, several solar cells (SCs) were grown with varying InAs QD heights. All experimental characteristics of the QD solar cells were compared to a reference structure without QDs. All samples were grown by Molecular Beam Epitaxy …

Life Cycle Assessment Projection Of Photovoltaic Cells: A Case Study On Energy Demand Of Quantum Wire Based Photovoltaic Technology Research, Shilpi Mukherjee

Graduate Theses and Dissertations

With increasing clean-energy demand, photovoltaic (PV) technologies have gained attention as potential long-term alternative to fossil fuel energy. However, PV research and manufacture still utilize fossil fuel-powered grid electricity. With continuous enhancement of solar conversion efficiency, it is imperative to assess whether overall life cycle efficiency is also being enhanced. Many new-material PV technologies are still in their research phase, and life cycle analyses of these technologies have not yet been performed. For best results, grid dependency must be minimized for PV research, and this can be accomplished by an analytical instrument called Life Cycle Assessment (LCA).

LCA is the …

Design And Implementation Of An Instruction Set Architecture And An Instruction Execution Unit For The Rez9 Coprocessor System, Daniel Spencer Anderson

UNLV Theses, Dissertations, Professional Papers, and Capstones

While the use of RNS has provided groundbreaking theory and progress in this field, the applications still lack viable testing platforms to test and verify the theory. This Thesis outlines the processing of developing an instruction set architecture (ISA) and an instruction execution unit (IEU) to help make the first residue based general processor a viable testing platform to address the mentioned problems.

Consider a 32-bit ripple adder. The delay on this device will be 32N where N is the delay for each adder to complete its operation. The delay of this process is due to the need to propagate …

Introducing The Newton-Poisson-Brillouin Model In The Quest For Plasmons In Metallic Carbon Nanotubes, Richard P. Zannoni

Doctoral Dissertations

A new method is presented to model carbon nanotubes (CNT) of micron length. The Newton-Poisson-Brillouin (NPB) model uses Newtonian physics to model the interaction of a population of thermally excited quasi-particles. The NPB model is self-consistent with Poisson’s equation, and the quasi-particles are confined to the CNT’s band structure. In this work, we explore the parameter space of the model.

Low Cost Infrared And Near Infrared Sensors For Uavs, Samuel T. Aden, James P. Bialas, Zachary Champion, Eugene Levin, Jessica L. Mccarty

Michigan Tech Research Institute Publications

Thermal remote sensing has a wide range of applications, though the extent of its use is inhibited by cost. Robotic and computer components are now widely available to consumers on a scale that makes thermal data a readily accessible resource. In this project, thermal imagery collected via a lightweight remote sensing Unmanned Aerial Vehicle (UAV) was used to create a surface temperature map for the purpose of providing wildland firefighting crews with a cost-effective and time-saving resource. The UAV system proved to be flexible, allowing for customized sensor packages to be designed that could include visible or infrared cameras, GPS, …

A New Transfer Impedance Based System Equivalent Model For Voltage Stability Analysis, Yang Wang, Caisheng Wang, Feng Lin, Wenyuan Li, Le Yi Wang, Junhui Zhao

Electrical & Computer Engineering and Computer Science Faculty Publications

This paper presents a new transfer impedance based system equivalent model (TISEM) for voltage stability analysis. The TISEM can be used not only to identify the weakest nodes (buses) and system voltage stability, but also to calculate the amount of real and reactive power transferred from the generator nodes to the vulnerable node causing voltage instability. As a result, a full-scale view of voltage stability of the whole system can be presented in front of system operators. This useful information can help operators take proper actions to avoid voltage collapse. The feasibility and effectiveness of the TISEM are further validated …

Designing A Bayer Filter With Smooth Hue Transition Interpolation Using The Xilinx System Generator, Zhiqiang Li, Peter Revesz

CSE Conference and Workshop Papers

This paper describes the design of a Bayer filter with smooth hue transition using the System Generator for DSP. We describe and compare experimentally two different designs, one based on a MATLAB implementation and the other based on a modification of the Bayer filter using bilinear interpolation.

A Game-Theoretic Analysis Of The Nuclear Non-Proliferation Treaty, Peter Revesz

CSE Conference and Workshop Papers

Although nuclear non-proliferation is an almost universal human desire, in practice, the negotiated treaties appear unable to prevent the steady growth of the number of states that have nuclear weapons. We propose a computational model for understanding the complex issues behind nuclear arms negotiations, the motivations of various states to enter a nuclear weapons program and the ways to diffuse crisis situations.

Estimating The Flight Path Of Moving Objects Based On Acceleration Data, Peter Revesz

CSE Conference and Workshop Papers

Inertial navigation is the problem of estimating the flight path of a moving object based on only acceleration measurements. This paper describes and compares two approaches for inertial navigation. Both approaches estimate the flight path of the moving object using cubic spline interpolation, but they find the coefficients of the cubic spline pieces by different methods. The first approach uses a tridiagonal matrix, while the second approach uses recurrence equations. They also require different boundary conditions. While both approaches work in O(n) time where n is the number of given acceleration measurements, the recurrence equation-based method can be easier updated …

Cubic Spline Interpolation By Solving A Recurrence Equation Instead Of A Tridiagonal Matrix, Peter Revesz

CSE Conference and Workshop Papers

The cubic spline interpolation method is proba- bly the most widely-used polynomial interpolation method for functions of one variable. However, the cubic spline method requires solving a tridiagonal matrix-vector equation with an O(n) computational time complexity where n is the number of data measurements. Even an O(n) time complexity may be too much in some time-ciritical applications, such as continuously estimating and updating the flight paths of moving objects. This paper shows that under certain boundary conditions the tridiagonal matrix solving step of the cubic spline method could be entirely eliminated and instead the coefficients of the unknown cubic polynomials …