Physical Sciences and Mathematics Commons^™

Primary Research Of Reversible Proton Exchange Membrane Regenerative Fuel Cells, Zhigang Shao, Baolian Yi, Ming Han

Journal of Electrochemistry

In this paper, we report the results of our studies on regenerative proton exchange membrane fuel cell(RPEMRFC) catalysts, electrode preparation and their performances. The Pt catalyst for the oxygen electrode was replaced by 60 w%Pt+40 w%IrO 2 which reduces polarization by 0.2 V in a polymer protone exchange membrane fuel cell. The cycle performance of RPEMRFC was found to be manly effected by the stability of the diffiusion layer of bifunctional oxygen electrode.

The Latest World Wide Progress In Solid Oxide Fuel Cell, Jiang Yi

Journal of Electrochemistry

Solid oxide fuel cell(SOFC) is a novel, green electricity generation technology, which has been showing rapid development since 1980's. In light of its high efficiency, environmental friendly, fuel adaptability and long term stability, the Research, Development and Demonstration(RD&D) of this hype of full cell have been emphasized in a large number of developed countries. Based on the information communicated at the latest symposium on SOFC held last year in Aachen(Germany) and the knowledge gained through years of research in this field, a comprehensive review on the latest development of the tubular, this planar SOFC as well as on a number …

A Preliminary Study Of The Synthesis Of Tin Based Amorphous Material And Its Behavior On Lithium Intercalation, Li Liu, Hanxi Yang, Jutang Sun, Xingping Ai

Journal of Electrochemistry

An amorphous lithium inserting anode material based on Tin oxide glass was synthesized by salification in solution and its properties on lithium intercalation was investigated by X ray diffraction(XRD), microelectrode voltammetry and charge discharge measurements. The results have shown that this kind of material has considerable electrochemical reversibility toward lithium intercalation deintercalation. The available discharge capacity of the material reaches 430 mA·h/g with charge_discharge efficiency over 90%, showing a great potential for practical use.

Drect Electro_Oxidation Synthesis Of D Arabinose On Spectroscopic Graphite Electrode, Hei Wei, Huang Ying

Journal of Electrochemistry

D Arabinose synthesized by direct electro_oxidative decarboxylation of D gluconate on graphite electrode from aqueous solutions. The effects of D gluconate concentration, electrolysis potential, temperature and electrolyte composition on the current efficiency and product yield of electrosynthsis are discussed. The laboratory scale electrosynthesis was achieved with flow through cell.The optimum technology conditions for electrosynthesis were obtained with orthogonal design method.Both galvanostatic and potentionstatic conditions have been exploited, the later was found to be more effective.

Study On Electrosynthesis Of Butyl Butyrate At Conducting Oxide Anode Support On Titanium, Junxiang He, Jincheng Zhou

Journal of Electrochemistry

Synthesis of butyl butyrate by direct electroxidation of n butyl alcohol and the electrochemical behaviors of several selected conducting oxide electrodes (Pb/PbO 2、Ti/PbO 2、i/SnO 2 +Sb 2O 3 /PbO 2 and Ti/SnO 2+Sb 2O 3+PdO x/PbO 2) have been investigated. The results demonstrated that the intermediate layers of SnO 2、Sb 2O 3 and PdO x could significantly decrease the interfacial resistance of the electrodes,and that the Ti/SnO 2+Sb 2O 3+PdO x/PbO 2 electrode possessed better electrocatelytic performance than others.

Studies Of Spinal Li 1+X Mn 2-X O 4 Rechargeable Lithium Ion Battery, Xiaomei Wu, Qinghe Yang, Zhongkao Jin, Haoqing Wu, Xiangfu Zong

Journal of Electrochemistry

The spinel Li intercalation compound Li 1+ x Mn 2- x O 4(0< x <1) was prepared by using techniques of cyclic voltammetry. The electrochemical parameters of Li 1+ x Mn 2- x O 4 electrode vary as either the starting materials or the synthesis temperature changes. It was found that the initial capacity and reversible behaviors of the Li 1+ x Mn 2- x O 4 electrode depends on the amount of the excess Li, represented as x in Li 1+ x Mn 2- x O 4. The reversible of Li intercalation process for Li 1+ x Mn 2- x O 4 electrode was demonstrate by cyclic voltammograms.

Self-Enhancement Of Dynamic Gratings In Photogalvanic Crystals, Nickolai Kukhtarev, Sergei F. Lyuksyutov, Preben Buchhave, Tatiana Kukhtareva, K. Sayano, Partha P. Banerjee

Electrical and Computer Engineering Faculty Publications

We have developed a compact closed-form solution of the band transport model for high-contrast gratings in photogalvanic crystals. Our solution predicts the effect of the photoconductivity and the electric field grating enhancement due to the photogalvanic effect. We predict a pronounced dependence of the steady-state photogalvanic current on the contrast of the interference pattern and an increase of holographic storage time due to the enhancement of the photoconductivity grating contrast. In the high contrast limit and a large photogalvanic effect the refractive index grating will be shifted from the position of the intensity modulation pattern, contrary to the usually adopted …

Validation Of Waimss Incident Duration Estimation Model, Wei Wu, Pushkin Kachroo, Kaan Ozbay

Electrical & Computer Engineering Faculty Research

This paper presents an effort to validate the traffic incident duration estimation model of WAIMSS (wide area incident management support system). Duration estimation model of WAIMSS predicts the incident duration based on an estimation tree which was calibrated using incident data collected in Northern Virginia. Due to the limited sample size, a full scale test of the distribution, mean and variance of incident duration was performed only for the root node of the estimation tree, white only mean tests were executed at all other nodes whenever a data subset was available. Further studies were also conducted on the model error …

Wide-Area Incident Management System On The Internet, Kaan Ozbay, Pushkin Kachroo

Electrical & Computer Engineering Faculty Research

The incident management process consists of four sequential steps-incident detection, response, clearance and recovery. Each of these components comprises of a number of operations and coordinated decision-making between the agencies involved. The provision of computer based support tools for the personnel involved will help develop appropriate strategies and increase efficiency and expediency. Existing systems are developed on various traditional computing platforms. However, with the advent of World Wide Web and Internet based programming tools such as Java, it is now possible to develop platform independent decision support tools for the incident management agencies. Any agency will be able to use …

Automatic Target Cueing Of Hyperspectral Image Data, Terry A. Wilson

Theses and Dissertations

Modern imaging sensors produce vast amounts data, overwhelming human analysts. One such sensor is the Airborne Visible and Infrared Imaging Spectrometer (AVIRIS) hyperspectral sensor. The AVIRIS sensor simultaneously collects data in 224 spectral bands that range from 0.4µm to 2.5µm in approximately 10nm increments, producing 224 images, each representing a single spectral band. Autonomous systems are required that can fuse "important" spectral bands and then classify regions of interest if all of this data is to be exploited. This dissertation presents a comprehensive solution that consists of a new physiologically motivated fusion algorithm and a novel Bayes optimal self-architecting classifier …

Direct Electrochemical Reaction Of Cytochrome C At The Poly (Ethylene Oxide) Film Modified Gold Electrodes, Xiaogang Qu, Gongquan Sun

Journal of Electrochemistry

In this paper, the direct electrochemical reaction of cytochrome c was sudied at the poly (ethylene oxide) film modified gold electrodes. It was found the PEO is a good promoter for the electrochemical reaction of cytochrome c, and the reversibility of reaction of cytochrome c was found to depend on the molecular weight of PEO and the morphology of the PEO films.

Modification Of Carbon Anode Materials Of Lithium Ion Secondary Battery, Yuping Wan Chunrong Wu, Changyin Jiang, Jiangiun Li

Journal of Electrochemistry

In this paper, the latest research work on modification of carbon anode materials of lithium ion secondary battery is reviewed. Modification methods include: incorporation of nonmetal elements such as boron, silicon, nitrogen, phosphorus and sulfur, metal elements such as potassium, aluminum, gallium and transitional metal elements such as vanadium, nickel, cobalt, copper and iron and surface treatment such as oxidation and formation of surface layer. Since these methods can affect the carbon materials' electronics state, crystal structure and surface structure, the electrochemical properties of the carbon materials could probably be improved. Besides, mechanisms for lithium storage in carbonaceous materials are …

External Transducing Measurement Of The Internal Pressure In Sealed Battery By Resistance Strain Gauge, Hanxi Yang, Ronghui Hu, Xinping Ai, Congzhi Yang, Shengxian Li

Journal of Electrochemistry

A novel method to monitor dynamically the internal pressure of sealed battery with no damage of the battery by using of resistance strain measurement technique is presented. This technique employs the resistence strain gauges in touch of the battery case and to detect the minimal change in the battery deformation due to the increasing internal pressure, electrode expantion or intrenal temperature rise. Application of the technique for the study of the effects of the battery processing factors on the battery performance is described taking Ni MH battery as example.

Lithiun Insertion In Carbon Nanotubes, Guotao Wu, Chunsheng Wang, Zhongfu Qi, Wenzhu Li

Journal of Electrochemistry

Carbon nanotubes were produced by chemical vapour deposition(CVD) of acetylene under hydrogen gas.The reversible specific capacity of carbon nanotubes is up to 700 mAh/g, much higher than the theoretical specific capacity of graphite(372 mAh/g).After twenty charge/discharge cycles,the discharge capacity of carbon nanotube anode still maintains 65.3% of its original discharge capacity . Besides, the charge/discharge efficiency of carbon nanotube in the first charge/discharge cycle was found to improve from 42.6% up to 55.9% by coating carbon nanotubes with copper.

Electrooxidation Of Benzene To Benzoquinone In A Packed Bed Reactor, Xinsheng Zhang, Ping Ding, Yingchun Dai, Weikang Yuan

Journal of Electrochemistry

A packed electrode reactor was used to oxidize to benzoquinone. Anode bed of the reactor has a size of 10～30 mm×450 mm×50 mm(thickness×length×width),and was packed porous lead alloy. A dispersion of benzene in 1 mol/L aqueous sulfuric acid was passed through the reactor. Current efficiency for benzoquinone generation is 62.9% at optimal operating condition: velocity of electrolyte flow, 0.19 ms -1 ;current, 10 A; thickness of anode bed, 10 mm, and percentage of benzene, 24%.

Studies On The Electrode Kinetics Of Electrooxidation Of Mn 2+, Wanli Hu, Tong Su, Wei Guo, Ding Zhou

Journal of Electrochemistry

The mechanism of electrooxidation of MnSO 4 on Pb Sb As alloy anode was investigated by using rotating disc electrode technique. The results shown that the conditional standard potential of Mn(Ⅲ)/Mn(Ⅱ)in 40% H 2SO 4 is 0.886 4 V.The rate controlling step of electrode process is mixed controlled by charge transfer and diffusion.

Study Of Proton Exchange Membrane Fuel Cells(Pemfc), Shanhai Ge, Baolian Yi, Hongfen Xu, Ming Han, Zhigang Shao

Journal of Electrochemistry

The electrode kinetic parameters for proton exchange membrane fuel cells(PEMFC) were investigated by measuring the relations of cell potential and current density. An experimental stack of PEMFC which can be operated at E cell =0.7V, I =0.55A/cm 2 steadily is presented, and the effects of electrode structure and operation conditions such as temperature, pressure, humidification, flow rate on the performance of PEMFC are discussed.

Photoelectrochemical Studies On Nanoporous Tio 2/Pan Film Electrode, Minsheng Liu, Yanzhong Hao, Xuebin Qiao, Maizhi Yang, Shengmin Cai

Journal of Electrochemistry

The photon to electricity conversion process of nanoporous TiO 2/PAn film electrode was studied in electrolytes with and without redox couple by using the photocurrent action spectra and potential dependence of photocurrent. It is concluded that the nanoporous TiO 2/PAn film electrode has a structure of duplex n type semiconductor layers. The band gap of PAn film is 2.88eV.The TiO 2 nanoporous film electrode modified by PAn can extend the range of optical absorption into visible and infrared region and effectively increase the photocurrent in the visible and infrared region. The photocurrent threshold shifts to>600nm and conversion efficiency of …

Experimental Investigations Of Wavelength And Angular Errors In Holographic Gratings With Non-Bragg-Matched Read Beams, Monish Ranjan Chatterjee, Vivek Ray

Electrical and Computer Engineering Faculty Publications

Perfect Bragg matching is generally desirable for accurate optical interconnections with holographic gratings. In reality, however, gratings may be illuminated by READ beams with non-Bragg-matched angles, or wavelengths, or both. In such cases, the scattered beams are generally misdirected, and may suffer loss of efficiency and possibly more serious errors such as crosstalk noise or missed connections. A conventional wave-vector triad method of analyzing the scattered beam errors leads readily to near-Bragg estimates of the output angular misalignment. However, the READ wave-vector triads appear to indicate a possible wavelength shift in the output beam even with a Bragg-matched READ wavelength, …

Fuzzy Logic Applied To System Control To Enhance Commercial Appliance Performance, Glenn Moffett

Doctoral Dissertations

The purpose of this research is to determine the usefulness of fuzzy logic and fuzzy control when applied to a commercial appliance. Fuzzy logic is a structured, model-free estimator that approximates a function through linguistic input/output associations. Fuzzy rule-based systems apply these methods to solve many types of "real-world" problems, especially where a system is difficult to model, is controlled by a human operator or expert, or where ambiguity or vagueness is common.

This dissertation presents fuzzy sets, fuzzy systems, and fuzzy control, with an example conveying the use of fuzzy control of a consumer product and an overview of …

The Cluster Multipole Algorithm For Far-Field Computations, Rakesh R. Patel

Electrical & Computer Engineering Theses & Dissertations

Computer simulations of N-body systems are beneficial to study the overall behavior of a number of physical systems in fields such as astrophysics, molecular dynamics, and computational fluid dynamics. A new approach for computer simulations of N-body systems is proposed in this research. The new algorithm is called the Cluster Multipole Algorithm (CMA). The goals of the new algorithm are to improve the applicability to non-point sources and to provide more control on the accuracy over current algorithms. The algorithm is targeted to applications that do not require rebuilding the data structure about the system every time step due to …

Representations, Approximations, And Algorithms For Mathematical Speech Processing, Laura R. Suzuki

Theses and Dissertations

Representing speech signals such that specific characteristics of speech are included is essential in many Air Force and DoD signal processing applications. A mathematical construct called a frame is presented which captures the important time-varying characteristic of speech. Roughly speaking, frames generalize the idea of an orthogonal basis in a Hilbert space, Specific spaces applicable to speech are L₂(R) and the Hardy spaces H_p(D) for p> 1 where D is the unit disk in the complex plane. Results are given for representations in the Hardy spaces involving Carleson's inequalities (and its extensions), …

Trigonometric Transforms For Image Reconstruction, Thomas M. Foltz

Theses and Dissertations

This dissertation demonstrates how the symmetric convolution-multiplication property of discrete trigonometric transforms can be applied to traditional problems in image reconstruction with slightly better performance than Fourier techniques and increased savings in computational complexity for symmetric point spread functions. The fact that the discrete Fourier transform a circulant matrix provides an alternate way to derive the symmetric convolution-multiplication property for discrete trigonometric transforms. Derived in this manner, the symmetric convolution-multiplication property extends easily to multiple dimensions and generalizes to multidimensional asymmetric sequences. The symmetric convolution-multiplication property allows for linear filtering of degraded images via point-by-point multiplication in the transform domain …

New Esrelectrochemical Cell Designs For Coaxial Microwave Cavity, Lin Lu Juntao Zhuang

Journal of Electrochemistry

New cell designs for simultaneous electrochemical(EC) and electron spin resonance (ESR) measurements are reported for coaxial microwave cavity. Adjustable shieldings are introduced so that the working electrode can be much shorter than the full height of the cavity. Besides the traditional helical electrode, the working electrode can be cylinders made from metal plates, metallic meshes or even composite materials. The counter electrode can be placed either inside or outside the cavity. These features make the new designs more flexible than that previously reported. With a nonperforated cylindrical electrode, this cell can be used to determine the standard potential and the …

Studies Of Surface Alloy As High Efficient Electrocatalyst For Glyoxylic Acid Synthesis, Shengpei Chen, Shengqing Xia, Shigang Sun

Journal of Electrochemistry

No abstract provided.

Studies On The Transport Properties Of Zn~2+ In The Zn/V_2o_5 Secondary Battery With Aqueous Medium, Jiahong Zhou, Kuanhong Xue, Guping Pan

Journal of Electrochemistry

The transport properties and the reaction mechanism of Zn~2+ in the cathode material of Zn/V_2O_5 secondary battery with aqueous medium were studied by use of intermittent titration experiments and X-Ray diffraction analysis. The relations of some kinetic parameters to the discharge depth were discussed. The results of the experiments show that the cathodic discharge reaction is an intercalation process.

Electrode Process Of Lithium Ions On Aluminum Electrode In Molten Licl-Kcl, Shuzhen Duan, Congsheng Guan, Qingrong Shi, Xindong Wang

Journal of Electrochemistry

The Deposition mechanism of Lithium on aluminium electrode was studied by using linear sweep voltammetry and potential step method. The formation of α-solid solution was controlled by the diffusion of lithium within the aluminium substance. The formation of β-LiAl alloy was limited by the rate of forming the alloy at the legining, and by diffiusion of lithium through the β- LiAl alloy layer was limited by the rate of forming the alloy at the begining, and by the diffusion of lithium through the β-LiAl alloy later. Neucleation polarization for the formation of β-LiAl alloy was observed. This polarization is an …

Electrochemical Preparation Of Rare Earth Functional Materials And Application Of Rare Earth To Electrochemistry, Qiqin Tong Yexiang Yang

Journal of Electrochemistry

The new progress and related mechanism of the electrochemical preparation of rare earth materials(magnets, magnetooptic materials, battery materials, luminescent devices, semiconductors, superconductors) and the application of rare earth to the electrochemical areas(e.g. electroplating,corrosion,electrosynthses) have introduced.

InSitu Raman Spectroscopic Study Of The Oxidation And Reduction Of Ag Electrode In Na_2so_4 Solution, Chen Y X, Huang K Q, Tian Z Q

Journal of Electrochemistry

Insitu Raman spectroscopy combined with cyclic voltammogram measurements was used to investigate formation of oxygen species at Ag electrode surfaces during the oxidation and reduction process in 0.1 mol/L Na_2SO_4 solution. The time dependent Raman spectra show that at potentials positive of 0.2 V, adsorption of oxygen atom occurs, while at the potentials positive of 0.4 V, some oxygen atoms migrate into subsurface of the Ag electrode and the other form strongly bound oxygen on the surface through chemical bond. At the same potentials, part of the silver atoms are oxidized and form Ag_2SO_4. During the negative potential ex cursion, …

Thermal Lattice Boltzmann Simulations Of Variable Prandtl Number Turbulent Flows, Min Soe, George Vahala, Pavol Pavlo, Linda L. Vahala, Hudong Chen

Electrical & Computer Engineering Faculty Publications

Thermal lattice Boltzmann (TLBE) models that utilize the single relaxation time scalar Bhatnagar, Gross, and Krook collision operator have an invariant Prandtl number. For flows with arbitrary Prandtl number, a matrix collision operator is introduced. The relaxation parameters are generalized so that the transport coefficients become density independent. TLBE simulations are presented for two-dimensional free decaying turbulence induced by a strongly perturbed double velocity shear layer for various Prandtl numbers.