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Full-Text Articles in Physical Sciences and Mathematics

Dynamic Simulation Of Oxygen Reduction Reaction In Pt/C Electrode For Proton Exchange Membrane Fuel Cells, Li Shang, Zhou Fen, Chen Lei, Pan Mu Apr 2016

Dynamic Simulation Of Oxygen Reduction Reaction In Pt/C Electrode For Proton Exchange Membrane Fuel Cells, Li Shang, Zhou Fen, Chen Lei, Pan Mu

Journal of Electrochemistry

It is an urgent need to reduce the Pt loading in electrode for practical fuel cell applications worldwide. Herein, we theoretically investigate the oxygen distribution, generated current, and minimum Pt loading of Pt/C electrode for practical applications based on kinetic model of oxygen reduction reaction. The results indicate that with increasing electrode effective thickness to 40 mm, serious concentration polarization is expected for Pt/C electrode. To generate a power density of 1.4 W•cm-2 (2.1A•cm-2 @0.67 V) for fuel cell, the cathode catalyst layer thickness in PEMFC should be as thin as 3 mm. The minimum Pt loading will …


Multi-Scaled Carbon Supported Platinum As A Stable Electrocatalyst For Oxygen Reduction Reaction, Yu-Ping Li, Lu-Hua Jiang, Su-Li Wang, Gong-Quan Sun Apr 2016

Multi-Scaled Carbon Supported Platinum As A Stable Electrocatalyst For Oxygen Reduction Reaction, Yu-Ping Li, Lu-Hua Jiang, Su-Li Wang, Gong-Quan Sun

Journal of Electrochemistry

The stability of carbon supports is essential for electrocatalysts of fuel cells. Herein, the mesoporous carbon with the high graphitic degree (highly graphitic mesoporous carbon, HGMC) was synthesized by using resorcinol as the carbon precursor, SiO2 as the templates and urea as the reducing agent. The as-prepared HGMC was characterized by XRD, Raman spectroscopy, TEM, N2 adsorption. The stability of HGMC was evaluated by mimicking the start-up/shut-down conditions of fuel cells in a three-electrode system referring to the NREL standard. The obtained HGMC is of moderate surface area (187.4 m2•g-1) and is chemically stable under potentiodynamic …


Economic Assessment Of A Hybrid Turboexpander-Fuel Cell Gas Energy Extraction Plant, Ahmad Darabi, Ahmad Shariati, Reza Ghanaee, Ali Soleimani Jan 2016

Economic Assessment Of A Hybrid Turboexpander-Fuel Cell Gas Energy Extraction Plant, Ahmad Darabi, Ahmad Shariati, Reza Ghanaee, Ali Soleimani

Turkish Journal of Electrical Engineering and Computer Sciences

In this paper, a hybrid turboexpander-fuel cell (TE-FC) is investigated for extraction of electrical energy from high pressure gas in which the fuel cells are used for preheating the gas. Combination of expanders and fuel cells will reduce the fuel consumption and greenhouse gas emission. This study reveals that there are some circumstances in which the use of fuel cells in conjunction with a turboexpander is not recommended from an economic point of view. This paper seeks the region in which utilization of fuel cells along with a turboexpander presents maximum economic profit. Using the strategy provided in this paper …


Modeling, Control, And Power Management For A Grid-Integrated Photo Voltaic, Fuel Cell, And Wind Hybrid System, Ezhilarasan Ganesan, Subhranhsu Sekhar Dash, Chinmaya Samanta Jan 2016

Modeling, Control, And Power Management For A Grid-Integrated Photo Voltaic, Fuel Cell, And Wind Hybrid System, Ezhilarasan Ganesan, Subhranhsu Sekhar Dash, Chinmaya Samanta

Turkish Journal of Electrical Engineering and Computer Sciences

Power management in a grid-integrated power system consisting of distributed renewable energy sources is necessitated by ever-increasing energy consumption, the high cost of production, the limited resource of fossil fuel, and the worsening global environment. Wind and solar power generation are two of the most promising renewable power generation technologies. The growth of wind and photovoltaic (PV) power generation systems has exceeded the most optimistic levels of expectations. Fuel cells (FCs) also have great potential to be green power sources of the future because of the many merits they have, such as high efficiency and zero or low emission of …