Open Access. Powered by Scholars. Published by Universities.®
Physical Sciences and Mathematics Commons™
Open Access. Powered by Scholars. Published by Universities.®
- Institution
Articles 1 - 5 of 5
Full-Text Articles in Physical Sciences and Mathematics
Effect Of Spontaneous Gas Expansion And Mobilization On The Aqueous-Phase Concentrations Above A Dense Non-Aqueous Phase Liquid Pool., Kevin G. Mumford, James Smith, Sarah E. Dickson
Effect Of Spontaneous Gas Expansion And Mobilization On The Aqueous-Phase Concentrations Above A Dense Non-Aqueous Phase Liquid Pool., Kevin G. Mumford, James Smith, Sarah E. Dickson
Sarah E Dickson
This paper presents a framework to quantify the overall variability of the model estimations of Total Polychlorinated Biphenyls (Total PCBs) concentrations in the Niagara River on the basis of the uncertainty of few model parameters and the natural variability embedded in some of the model input variables. The results of the uncertainty analysis are used to understand the importance of stochastic model components and their effect on the overall reliability of the model output and to evaluate multiple sources of uncertainty that might need to be further studied. The uncertainty analysis is performed using a newly developed point estimate method, …
New Observations Of Gas-Phase Expansion Above A Dense Non-Aqueous Phase Liquid Pool, Kevin G. Mumford, James E. Smith, Sarah E. Dickson
New Observations Of Gas-Phase Expansion Above A Dense Non-Aqueous Phase Liquid Pool, Kevin G. Mumford, James E. Smith, Sarah E. Dickson
Sarah E Dickson
The partitioning of volatile dense nonaqueous phase liquid (DNAPL) compounds to a discontinuous gas phase results in the repeated expansion, fragmentation, and vertical mobilization of gas clusters. This process has the potential to significantly affect the dissolution of DNAPL source zones and the characterization of DNAPL-contaminated sites, but has not been included in common conceptual models. This study presents new observations of discontinuous gas-phase growth above a 1,1,1-trichloroethane pool in a two-dimensional flow cell packed with 1.1-mm diameter sand. In contrast to the behavior observed in coarse glass beads, these visualization results show that the gas phase evolves as a …
Expansion Of The Discontinuous Gas Phase And Its Effect On Mass Flux From A Non-Aqueous Phase Liquid (Napl) Pool, Kevin G. Mumford, James E. Smith, Sarah E. Dickson
Expansion Of The Discontinuous Gas Phase And Its Effect On Mass Flux From A Non-Aqueous Phase Liquid (Napl) Pool, Kevin G. Mumford, James E. Smith, Sarah E. Dickson
Sarah E Dickson
The partitioning of non-aqueous phase liquid (NAPL) compounds to a discontinuous gas phase results in the repeated spontaneous expansion, snap-off, and vertical mobilization of the gas phase. This mechanism has the potential to significantly affect the mass transfer processes that control the dissolution of NAPL pools by increasing the vertical transport of NAPL mass and increasing the total mass transfer rate from the surface of the pool. The extent to which this mechanism affects mass transfer from a NAPL pool depends on the rate of expansion and the mass of NAPL compound in the gas phase. This study used well-controlled …
Slow Gas Expansion In Saturated Natural Porous Media By Gas Injection And Partitioning With Non-Aqueous Phase Liquids, Kevin G. Mumford, Sarah E. Dickson, James E. Smith
Slow Gas Expansion In Saturated Natural Porous Media By Gas Injection And Partitioning With Non-Aqueous Phase Liquids, Kevin G. Mumford, Sarah E. Dickson, James E. Smith
Sarah E Dickson
The partitioning of volatile non-aqueous phase liquid (NAPL) compounds to a discontinuous gas phase can result in the expansion of that gas phase, and the resulting gas flow can significantly affect the mass transfer from NAPL source zones. This recently reported gas flow generated by the spontaneous expansion of a discontinuous gas phase has not been extensively characterized in the literature. This study measured the expansion rate of a single gas cluster in a 1.1 mm sand above a pool of trans-1,2-dichloroethene (tDCE) in small-scale flow cell experiments. To characterize the gas flow, gas injection experiments in three sizes of …
Spontaneous Expansion And Mobilization Of Gas Above Dnapl, Kevin G. Mumford
Spontaneous Expansion And Mobilization Of Gas Above Dnapl, Kevin G. Mumford
Sarah E Dickson
No abstract provided.