Physical Sciences and Mathematics Commons^™

Supporting Dataset For The Influence Of Tile-Water On Groundwater Nitrate Concentrations Within A Saturated Riparian Buffer Zone, Aminat Tosin Abdulsalam, Eric Wade Peterson

Faculty Publications-- Geography, Geology, and the Environment

In the U.S. Midwest, where fertile soils with high water retention are prevalent, the installation of tile drainage networks have become a common practice to drain excess soil water, which enhances plant growth and increases crop productivity. However, tile drainage networks coupled with the use of inorganic fertilizers have significant implications on water quality, contributing to eutrophication, leading to harmful algal blooms, and resulting in hypoxic conditions in surface water bodies. To mitigate excess nutrient exports to surface water bodies, edge-of-field practices have been introduced. One such practice is the saturated riparian buffer (SRB), which utilizes a diversion system to …

Modeling Overdraft-Driven Nitrate Transport In Shallow Wells For Mitigation And Scenario Planning, Jonathan Cronk

Department of Biological Systems Engineering: Dissertations and Theses

In Nebraska, average nitrate concentrations in groundwater have doubled since 1974, making water quality management more important than ever. As droughts, heat waves, and floods become more common climate events, understanding their impacts will be necessary to make informed management decisions. Emerging literature describes that drought correlates to an increase in the concentration of nitrate-N at domestic and irrigation wells, however the relative contributions of the mechanisms thought to be responsible is currently unknown.

This research assessed the impact of recharge and pumping rate changes as two mechanisms affecting nitrate-N concentration during drought, assessed the relationship between well depth and …

Importance Of Snowmelt On Soil Nitrate Leaching To Groundwater – A Model Study, Sahila Beegum, Arindam Malakar, Chittaranjan Ray, Daniel D. Snow

Nebraska Water Center: Faculty Publications

The movement of nitrate to surface water bodies during snow accumulation and melting has been extensively studied, but there are only limited studies on the influence of snow processes on nitrate leaching to groundwater. The present study investigated the impact of snow processes on nitrate leaching to groundwater based on a simulation modeling approach using HYDRUS-1D. HYDRUS-1D model has a temperature threshold-based snow model in addition to water, solute, and heat simulation components. The snow component in HYDRUS-1D was previously not applied to snow simulation studies since the method does not consider a detailed physical and process-based representation of snow …

Labile Carbon And Soil Texture Control Nitrogen Transformation In Deep Vadose Zone, Lidong Li, Jordan Shields, Daniel D. Snow, Michael Kaiser, Arindam Malakar

Daugherty Water for Food Global Institute: Faculty Publications

Understanding transient nitrogen (N) storage and transformation in the deep vadose zone is critical for controlling groundwater contamination by nitrate. The occurrence of organic and inorganic forms of carbon (C) and nitrogen and their importance in the deep vadose zone is not well characterized due to difficulty in sampling and the limited number of studies. We sampled and characterized these pools beneath 27 croplands with different vadose zone thicknesses (6–45 m).We measured nitrate and ammonium in different depths for the 27 sites to evaluate inorganic N storage. We measured total Kjeldahl nitrogen (TKN), hot-water extractable organic carbon (EOC), soil organic …

Ooi Biogeochemical Sensor Data: Best Practices And User Guide. Version 1.0.0., Hilary I. Palevsky, Sophie Clayton, Dariia Atamanchuk, Roman Battisti, Jennifer Batryn, Annie Bourbonnais, Ellen M. Briggs, Filipa Carvalho, Alison P. Chase, Rachel Eveleth, Rob Fatland, Kristen E. Fogaren, Jonathan Peter Fram, Susan E. Hartman, Isabela Le Bras, Cara C.M. Manning, Joseph A. Needoba, Merrie Beth Neely, Hilde Oliver, Andrew C. Reed, Jennie E. Rheuban, Christina Schallenberg, Michael F. Vardaro, Ian Walsh, Christopher Wingard

OES Faculty Publications

The OOI Biogeochemical Sensor Data Best Practices and User Guide is intended to provide current and prospective users of data generated by biogeochemical sensors deployed on the Ocean Observatories Initiative (OOI) arrays with the information and guidance needed for them to ensure that the data is science-ready. This guide is aimed at researchers with an interest or some experience in ocean biogeochemical processes. We expect that users of this guide will have some background in oceanography, however we do not assume any prior experience working with biogeochemical sensors or their data. While initially envisioned as a “cookbook” for end users …

Source Apportionment And Health Risk Assessment Of Nitrate In Foothill Aquifers Of Western Ghats, South India, Banajarani Panda, S. Chidambaram, Daniel D. Snow, Arindam Malakar, Dhiraj Kr Singh, L. Ramanathan

Nebraska Water Center: Faculty Publications

The present research reports the level of nitrate (NO₃^-), associated health risks and possible sources of contamination in groundwater from south India. Many samples (32%) are above or approaching the recommended level of NO₃^- for safe drinking water. The correlation analysis indicates different sources of NO₃^- contamination in different regions rather than a common origin. The isotopic measurements provide information about potential nitrogen sources contributing NO₃^- to the groundwater. Based on isotope analysis, the sources of NO₃^- in the groundwater of this region are likely to be from (a) …

Occurrence And Potential Transformation Pathways Of Nitrogen Species In The Intermediate Vadose Zone, Jordan Shields

School of Natural Resources: Dissertations, Theses, and Student Research

Nebraska is a large agricultural producing state with a heavy reliance on groundwater resources and nitrogen fertilizer application to maintain output. Poor management, such as excessive fertilizer application, improper timing, and over irrigation can lead to contamination of groundwater. Nitrate is the leading groundwater contaminant in Nebraska and chronic consumption at medium to high concentrations leads to adverse health effects. Nitrate, a highly soluble anion, is present in the root zone in numerous forms and undergoes biogeochemical transformations before being leached through the profile. In order to predict the timing and quantity of nitrate contamination in groundwater, researchers study the …

Supporting Data - Recycling Of Nitrate And Organic Matter By Plants In The Vadose Zone Of A Saturated Riparian Buffer, Patience Bosompemaa, Eric Wade Peterson, William Perry, Wondwosen M. Seyoum

Faculty Publications-- Geography, Geology, and the Environment

Data from the analysis of nitrate as nitrogen in the soil and soil pore water within the vadose zone of a saturated riparian buffer (SRB). Additional properties measured include: Organic matter (as %), bulk density, moisture content, and porosity. Soil samples were collected pre-growing season (n=57) and post-growing season from two plots (n=29): vegetated plots and barren plots. Statistical comparison of among the treatments, Pre-growing season, plot with plants, and barren plot, and among the different depths, 30 cm, 60 cm, and 90 cm identified significantly different soil NO₃^--N concentrations. Plots with plants experienced a reduction in …

Supporting Data – Floating Gardens, Chicago River, April 29, 2018 To November 19, 2019, Eric Wade Peterson, Phil Nicodemus, Emmett Andrew Spooner

Faculty Publications-- Geography, Geology, and the Environment

Between April 29, 2018 to November 19, 2019, water samples were collected upstream and downstream of a floating garden installed along the Chicago River. At each location, samples were collected at the surface and at 0.3 m below the surface. In-situ measurements of Dissolved Oxygen, Specific Conductance, and Temperature were recorded with a YSI 85. Anion samples were analyzed using a Ion Chromatograph for fluoride (F^-), chloride (Cl^-), nitrate as nitrogen (NO₃-N), phosphate (PO₄^-3), and sulfate (SO₄^-2). The available dataset provides the recorded field parameters and the analyzed …

Nitrate Dynamics And Source Within Nested Watersheds Of An Agricultural Stream, Nebraska, Usa, Galen Richards

School of Natural Resources: Dissertations, Theses, and Student Research

Nitrate concentrations have been increasing throughout the globe, primarily due to heightened agricultural activity. Nitrate concentrations in Bazile Creek, located in Northeastern Nebraska, have been steadily rising since the early 2000s. Groundwater nitrate concentrations within the Bazile Creek watershed are high (> 10 mg/L nitrate-N), and there is strong connectivity between groundwater and surface water systems. This study aimed to better understand temporal nitrate concentration variability within the watershed through sampling tributaries and the main channel during baseflow conditions. Nitrate source was also investigated though the use of dual δ¹⁵N and δ¹⁸O nitrate isotopes, with samples …

Environmental Fate And Microbial Effects Of Monensin, Lincomycin, And Sulfamethazine Residues In Soil, Matteo D'Alessio, Lisa M. Durso, Daniel N. Miller, Brian Woodbury, Chittaranjan Ray, Daniel D. Snow

Nebraska Water Center: Faculty Publications

The impact of commonly-used livestock antibiotics on soil nitrogen transformations under varying redox conditions is largely unknown. Soil column incubations were conducted using three livestock antibiotics (monensin, lincomycin and sulfamethazine) to better understand the fate of the antibiotics, their effect on nitrogen transformation, and their impact on soil microbial communities under aerobic, anoxic, and denitrifying conditions. While monensin was not recovered in the effluent, lincomycin and sulfamethazine concentrations decreased slightly during transport through the columns. Sorption, and to a limited extent degradation, are likely to be the primary processes leading to antibiotic attenuation during leaching. Antibiotics also affected microbial respiration …

Isotopic And Geochemical Analysis Of Nitrate Contaminated Groundwater In Edgar, Nebraska, Nathan Roddy

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

High nitrate concentrations in the groundwater beneath Edgar, Nebraska have been measured for well over a decade, exceeding the EPA’s MCL of 10 mg-N/L. Investigating the isotopic signature of nitrate and groundwater have determined the likely source(s) of contamination. Apparent seasonal changes exists in nitrate concentration, isotope ratios, and geochemistry, suggesting that sources and flow paths change as a result of irrigation. Samples collected in December and May had very similar nitrate concentrations (average value of 13.7 mg-N/L) and isotopic ratios (δ¹⁵N 4.46‰ and δ¹⁸O-NO₃ 20.21‰), suggesting synthetic nitrate fertilizers are the major source of …

The Impact Of Land Use On Nitrate-N Movement And Storage In The Vadose Zone Of The Hastings’ Whpa, Craig Adams

School of Natural Resources: Dissertations, Theses, and Student Research

Nebraska has one of the largest agricultural economies in the United States and relies heavily on irrigation and fertilizer application to maintain crop yields. Over-irrigation and continuous application of nitrogen (N) in many areas has led to accumulation of nitrate-N in soils and sediments throughout the state’s vadose zone. Because nitrate-N is both persistent and mobile, groundwater concentrations in many areas of Nebraska and other agriculturally intensive states are increasing. Nitrate-N contamination of public and private drinking water supplies that utilize groundwater are of particular concern. Vadose zone sampling is an important method for rapidly assessing the effect of changing …

Characterization Of Groundwater And Surface Water Geochemistry In An Agricultural Setting At Eku Meadowbrook Farm, Madison County, Kentucky, Reid E. Buskirk, Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Agricultural activities often contaminate watersheds with excess nutrients leading to poor water quality and eutrophication. Eastern Kentucky University (EKU) Meadowbrook Farm raises crops and livestock, which contribute dissolved nutrients to the neighboring Muddy Creek watershed. Consequently, the Farm is developing methods to sequester phosphorous and limit nutrient contamination.

Before phosphorous sequestration methods can be tested, Farm surface water and groundwater geochemistry must be better understood to determine hydrological pathways for nutrients. We use naturally-occurring dissolved cations, pH, oxidation-reduction potential (ORP), specific conductivity (SC), dissolved oxygen (DO%), total hardness, and alkalinity as chemical tracers to parse the contribution of dissolved ions …

Nutrient Export From A Proximal Intermittent Stream Draining Eku Meadowbrook Farm, Madison County, Kentucky, James Scott Winter, Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Agricultural activities contribute significant amounts of nutrients that contaminate surface and subsurface water. Eastern Kentucky University (EKU) Meadowbrook Farm (Madison County, Kentucky) seeks to decrease its export of nutrients to Muddy Creek using sequestration techniques. The first step in the overall process is to determine nutrient export at present, before sequestration efforts take place. Here we estimate the export of phosphate, nitrate, and ammonium during Tropical Storm Cindy (July 22 to 24, 2017) from a proximal, intermittent stream, named the BRC. This stream drains a representative portion the Farm, receiving water from a dairy complex, pasture, and cropland.

To estimate …

Nutrient Contamination From Non-Point Sources: Dissolved Nitrate And Ammonium In Surface And Subsurface Waters At Eku Meadowbrook Farm, Madison County, Kentucky, Reid E. Buskirk, Hunter R. Evans, Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Agricultural activities often contaminate watersheds with excess nutrients leading to poor water quality and eutrophication. We assayed dissolved nutrient levels in surface and subsurface waters of Eastern Kentucky University’s Meadowbrook Farm in order to assess levels of dissolved nutrients leaving its farmland and draining into the Muddy Creek watershed. The Farm raises both crops and livestock so that nutrient sources include fertilizer and manure. We sampled springs, runoff, and subsurface pipe drainage as well as Muddy Creek on six days from May to August 2016 under a variety of weather conditions. Using established, standard colorimetric methods, we measured nitrate (NO …

Geochemical Characteristics And Storm Dynamics Of Surface Waters And Groundwater At Eastern Kentucky University’S Meadowbrook Farm, Madison County, Kentucky, Reid E. Buskirk, Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Agricultural activities often contaminate watersheds with excess nutrients leading to poor water quality and eutrophication. Eastern Kentucky University’s Meadowbrook Farm raises crops and livestock, contributing dissolved nutrients to the neighboring Muddy Creek watershed. Consequently, the Farm is developing methods to sequester and limit nutrient contamination.

Before phosphorous sequestration methods can be tested, the geochemistry of surface water and groundwater on the Farm need to be better understood to determine hydrological pathways. We use naturally-occurring, dissolved cations as tracers to identify the contribution of different water sources and interpret storm events.

Water samples taken from springs (groundwater), surface water, and storm …

Nitrate Leaching From Sand And Pumice Geomedia Amended With Pyrogenic Carbon Materials, Jihoon Kang, Marissa Davila, Sergio Mireles, Jungseok Ho

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

There is increasing interest in using pyrogenic carbon as an adsorbent for aqueous contaminants in stormwater. The objective of this study was to investigate pyrogenic carbon materials as an amendment to geomedia to reduce nitrate leaching. Batch adsorption and column experiments were conducted to evaluate the performance of a commercial activated carbon and two biochars incorporated (5% by weight) into sand and pumice columns. The batch adsorption with 50 mg L−1 of nitrate solution showed that only activated carbon resulted in a substantial adsorption for nitrate up to 41%. Tested biochars were not effective in removing aqueous nitrate and even …

Nutrient Contamination From Non-Point Sources: Dissolved Nitrate And Ammonium In Surface And Subsurface Waters At Eku Meadowbrook Farm, Madison County, Kentucky, Reid E. Buskirk, Hunter R. Evans, Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Agricultural activities often contaminate watersheds with excess nutrients leading to poor water quality and eutrophication. We assayed dissolved nutrient levels in surface and subsurface waters of Eastern Kentucky University’s Meadowbrook Farm in order to assess levels of dissolved nutrients leaving its farmland and draining into the Muddy Creek watershed. The Farm raises both crops and livestock so that nutrient sources include fertilizer and manure. We sampled springs, runoff, and subsurface pipe drainage as well as Muddy Creek on six days from May to August 2016 under a variety of weather conditions. Using established, standard colorimetric methods, we measured nitrate (NO …

Agriculture Causes Nitrate Fertilization Of Remote Alpine Lakes, Elizabeth J. Hundey, Sam S.D. Russell, Fred Longstaffe, Katrina A. Moser

Earth Sciences Publications

Humans have altered Earth’s nitrogen cycle so dramatically that reactive nitrogen (Nr) has doubled. This has increased Nr in aquatic ecosystems, which can lead to reduced water quality and ecosystem health. Apportioning sources of Nr to specific ecosystems, however, continues to be challenging, despite this knowledge being critical for mitigation and protection of water resources. Here we use D¹⁷O, d¹⁸O and d¹⁵N from Uinta Mountain (Utah, USA) snow, inflow and lake nitrate in combination with a Bayesian-based stable isotope mixing model, to show that at least 70% of nitrates in aquatic systems are anthropogenic …

Hydrochemical Investigation Of A Transient Parafluvial Zone Under Drought Conditions, Platte River, Nebraska, Audrey R. Boerner

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

Shallow groundwater (0.5 m -1.2 m deep) beneath a vegetated and non-vegetated fluvial island was observed in the lower Platte River, Nebraska, USA during exceptional summer drought. Over the course of three months, sub-hourly measurements of hydraulic head, and weekly measurements of redox indicators, δ²H, δ¹⁸O, and dissolved gases were analyzed together with nitrogen and carbon species from an array of shallow piezometers in the river bed and islands. These data were compared with the same parameters collected from a 15 m-deep riparian borehole. Vertical hydraulic gradients in the island piezometers indicated the vertical component to …

Modeling Vulnerability Of Groundwater To Pollution Under Future Scenarios Of Climate Change And Biofuels-Related Land Use Change: A Case Study In North Dakota, Usa, Ruopu Li, James W. Merchant

School of Natural Resources: Faculty Publications

Modeling groundwater vulnerability to pollution is critical for implementing programs to protect groundwater quality.Most groundwater vulnerability modeling has been based on current hydrogeology and land use condi- tions. However, groundwater vulnerability is strongly dependent on factors such as depth-to-water, recharge and land use conditions thatmay change in response to future changes in climate and/or socio-economic condi- tions. In this research, a modeling framework, which employs three sets of models linked within a geographic information system (GIS) environment, was used to evaluate groundwater pollution risks under future climate and land use changes in North Dakota. The results showed that areas with …

Temporal And Spatial Variations Of Ions, Isotopes And Agricultural Contaminants In Surface Waters And Groundwater Of Nebraska's Rainwater Basin Wetland Region, Sarah E. Foster

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

The wetlands of south-central Nebraska’s Rainwater Basin region are considered of international importance as a habitat for millions of migratory birds, but are being endangered by agricultural practices. The Rainwater Basin extends across 17 counties and covers 4,000 square miles. The purpose of this study was to assemble baseline chemical data for several representative wetlands across the Rainwater Basin region, and determine the use of these chemical data for investigating groundwater recharge.

Eight representative wetlands were chosen across the Rainwater Basin to monitor surface and groundwater chemistry. At each site, a shallow well and deep well were installed and sampled …

Slides: The Use Of Terrestrial Cyanobacteria For The Rehabilitation Of Arid Soils: Not Just Another Good Idea, Timothy Flynn

Best Practices for Community and Environmental Protection (October 14)

Presenter: Dr. Timothy Flynn, Primordial Solutions Inc.

42 slides

Ground-Water Quality In Kentucky: Nitrate-Nitrogen, Philip G. Conrad, Daniel I. Carey, James S. Webb, James S. Dinger, Matthew J. Mccourt

Information Circular--KGS

No abstract provided.

Concentrations And Isotope Ratios Of Dissolved Inorganic Carbon In Denitrifying Environments, C. Nascimento, Eliot A. Atekwana, R. V. Krishnamurthy

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

We measured the concentration and isotope ratio of dissolved inorganic carbon (DIC) in groundwater associated with denitrification (C_org + NO₃^- = CO₂ + N₂) in an agriculturally impacted site in southwestern Michigan. Samples with the lowest nitrate levels also had low dissolved oxygen content and were more depleted in δ¹³C than background groundwater. All the samples had DIC concentrations in excess of titratable alkalinity. The magnitude of this DIC in excess of alkalinity correlated with a decreasing δ¹³C attesting to the presence of CO₂ derived from organic carbon. Carbon …

Evaluation Of The Crop Growth Component Of The Root Zone Water Quality Model For Corn In Ohio, Sue E. Nokes, Feliks M. Landa, Jon D. Hanson

Biosystems and Agricultural Engineering Faculty Publications

The Root Zone Water Quality Model (RZWQM) is a computer model developed to simulate water, chemical, and biological processes in the root zone of agricultural management systems. As of this writing RZWQM is in the beta-testing phase of development. This article reports on a parameterization and evaluation study performed in Ohio on field corn for the crop growth component of RZWQM. The generic crop growth model in RZWQM had not previously been parameterized or tested on field corn. This article reports the results of such a study. One year of data was used to calibrate RZWQM, and two additional years …

A Comparison Of No And N20 Production By The Autophic Nitrifier Nitrosomonas Europaea And The Heterotrophic Nitrifier Alcaligenes Faecalis, Iris C. Anderson, Mark Poth, Julie Homstead, David J. Burdige

OES Faculty Publications

Soil microorganisms are important sources of the nitrogen trace gases NO and N₂O for the atmosphere. Present evidence suggests that autotrophic nitrifiers such as Nitrosomonas europaea are the primary producers of NO and N₂O in aerobic soils, whereas denitrifiers such as Pseudomonas spp. or Alcaligenes spp. are responsible for most of the NO and N₂O emissions from anaerobic soils. It has been shown that Alcaligenes faecalis, a bacterium common in both soil and water, is capable of concomitant heterotrophic nitrification and denitrification. This study was undertaken to determine whether heterotrophic nitrification might be …

Effects Of Tillage And Grass Filter Strips On Surface Runoff Of Water, Nitrate, Sediment, And Atrazine, C. E. Madison, Robert L. Blevins, Wilbur Frye

Soil Science News and Views

The contamination of streams and other natural bodies of water through agricultural runoff has become a very important environmental issue. Surface water runoff can contain heavy loads of sediment and/or agricultural chemicals, such as nitrogen and atrazine. Conservation tillage methods with vegetative filter strips downslope from cropped fields help· to combat this problem. Conservation tillage has proven effective in decreasing erosion by decreasing exposure of the soil surface to rainfall. Vegetative filter strips provide an area where sediment and agricultural chemicals from cropland can be deposited before the runoff reaches a body of water.

Managing Soil Content Of Nitrate Nitrogen, Kenneth L. Wells

Soil Science News and Views

The concerns about leaching of fertilizer nitrogen (N} into groundwater which were raised in the late 1960's were largely silenced during the 1970's as our agricultural economy was massively expanded. But since the early 80's they have been raised again to the point that national legislation (the Clean Water Act) was put into place to bring purity of the nation's water supplies into compliance with EPA-established standards. Beyond the apprehension largely about nitrate (NO₃) levels in groundwater, the groundwater issue today also includes concerns about pesticides. At the current time, the public is apprehensive about drinking water and …