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Full-Text Articles in Physical Sciences and Mathematics
Isotopic Insights Into Water Of Condensation, Cross-Formation Water Flow, And Natural Hydrocarbon Migration In Sedimentary Basins, Lisa J. Molofsky
Isotopic Insights Into Water Of Condensation, Cross-Formation Water Flow, And Natural Hydrocarbon Migration In Sedimentary Basins, Lisa J. Molofsky
Open Access Theses & Dissertations
This dissertation applies geochemical tools to track the movement, transformation, and behavior of water and gases in hydrocarbon-bearing sedimentary basins. During petroleum exploration and production, hydrocarbons are generated at the surface along with other fluids naturally present in the formation, such as formation water. In addition, where hydraulic fracturing is used to stimulate shale gas and oil production, a percentage of the injected fracturing fluid also returns to the surface. Understanding the origin and movement of these water sources, as well as targeted and non-targeted hydrocarbon gases is critical to evaluating reservoir performance and properly managing fluids at the surface. …
A New Method For Ultra-Low Sulfate Extraction And A Pilot Study In Arid Soils, Marisela Montelongo
A New Method For Ultra-Low Sulfate Extraction And A Pilot Study In Arid Soils, Marisela Montelongo
Open Access Theses & Dissertations
Sulfur in soils is a crucial nutrient for all organisms including plants. Sulfate (SO42-), a water soluable anion, is a good source of this important element. Because of the importance of sulfur for agriculture, the use of sulfate has been well studied in temperate climate zones, and it is generally accepted that microbes play a critical role in controlling the availability of sulfate. Organically bound sulfur, such as sulfate esters and carbon-bonded sulfur, compounds that are generated and decomposed by microbes, are essential sulfur sources for plants under these conditions. For arid environments, knowledge of sulfate turnover in soils by …
Evaluation Of Cryptic Sulfur Cycling In Marine Sediments, Michael Ngari Mathuri
Evaluation Of Cryptic Sulfur Cycling In Marine Sediments, Michael Ngari Mathuri
Open Access Theses & Dissertations
Despite the importance of marine sediments as a carbon sink and many efforts to integrate microbiological with geochemical and geological data, the understanding of microbial organic carbon mineralization processes in marine sediments remains incomplete. There is growing evidence for the existence of an unrecognized oxidative sulfur cycling (cryptic sulfur cycling) above, within and below of the main sulfate reduction zone. For example, sulfate exists in supposedly sulfate-free methanogenic marine sediments from the Aarhus Bay and Black Sea. This implies that sulfur cycling is an ongoing process in the deep biosphere. Quantification of cryptic sulfur cycling is a major challenge because …
Application Of Copper And Zinc Isotopes To Fingerprint Metal Sources And Identify Attenuation Mechanisms In The Abandoned Waldorf Mine Area, Clear Creek County, Colorado, Suzan Aranda Luna
Application Of Copper And Zinc Isotopes To Fingerprint Metal Sources And Identify Attenuation Mechanisms In The Abandoned Waldorf Mine Area, Clear Creek County, Colorado, Suzan Aranda Luna
Open Access Theses & Dissertations
Acid rock drainage (ARD) is caused by the oxidative weathering of sulfide minerals. Sulfur is oxidized by dissolved oxygen or Fe(III) and sulfate ions, metals, and protons are released into the environment. Hence, the pH of nearby water and soils often decreases in response to ARD while metal concentrations increase. Because a large part of the Rocky Mountains of Colorado are highly mineralized (i.e., the Colorado Mineral Belt), ARD is a serious problem in this region. Moreover, the many abandoned mining areas in the Rocky Mountains that include waste rock piles, tailings impoundments, and surface disturbances add to the problem …